The reaction probabilities of ClONO2 and N2O5 on 40 to 75% sulfuric acid solutions

A wetted-wall flow tube was used to measure the reaction probabilities,γ, of ClONO 2 and N 2 O 5 on sulfuric acid surfaces. The reaction probabilities were determined from first-order wall loss rate coefficients measured over sulfuric acid slowly flowing down the inside wall of the flow tube. Sulfuric acid content was varied from 40 to 75% by weight

[1]  D. R. Hanson,et al.  The reaction probabilities of ClONO2 and N2O5 on polar stratospheric cloud materials , 1991 .

[2]  M. Zahniser,et al.  Uptake of dinitrogen pentoxide and nitric acid by aqueous sulfuric acid droplets , 1991 .

[3]  M. Zahniser,et al.  Uptake of N2O5 and HNO3 by Aqueous Sulfuric Acid Droplets. , 2010 .

[4]  M. Zahniser,et al.  Temperature Dependence of the Uptake Coefficients of HNO3, HCl, and N2O5 by Water Droplets , 1990 .

[5]  W. Brune,et al.  Heterogeneous chemistry on liquid sulfate aerosols - A comparison of in situ measurements with zero-dimensional model calculations , 1990 .

[6]  M. Zahniser,et al.  Uptake of HCl molecules by aqueous sulfuric acid droplets as a function of acid concentration , 1990 .

[7]  M. Zahniser,et al.  Temperature dependence of the uptake coefficients of nitric acid, hydrochloric acid and nitrogen oxide (N2O5) by water droplets , 1990 .

[8]  S. Solomon,et al.  Ozone destruction through heterogeneous chemistry following the eruption of El Chichón , 1989 .

[9]  M. Mozurkewich,et al.  Reaction probability of N2O5 on aqueous aerosols , 1988 .

[10]  David M. Golden,et al.  Heterogeneous interactions of chlorine nitrate, hydrogen chloride, and nitric acid with sulfuric acid surfaces at stratospheric temperatures , 1988 .

[11]  M. Ko,et al.  Antarctic chlorine chemistry: Possible global implications , 1988 .

[12]  Stanley C. Solomon,et al.  The mystery of the Antarctic Ozone “Hole” , 1988 .

[13]  A. McDaniel,et al.  Absolute infrared absorption cross sections for ClONO2 at 296 and 223 K , 1987 .

[14]  L. F. Keyser.  High-pressure flow kinetics - A study of the OH + HCl reaction from 2 to 100 torr , 1984 .

[15]  H. M. Steele,et al.  Effects of temperature and humidity on the growth and optical properties of sulphuric acid—water droplets in the stratosphere , 1981 .

[16]  Carleton J. Howard,et al.  Kinetic measurements using flow tubes , 1979 .

[17]  D. Albritton,et al.  Rate constants for the reactions of O2+, NO2+, NO+, H3O+, CO3−, NO2−, and halide ions with N2O5 at 300 K , 1978 .

[18]  R. L. Brown.  Tubular Flow Reactors With First-Order Kinetics. , 1978, Journal of research of the National Bureau of Standards.

[19]  F. Fehsenfeld,et al.  Gas phase ion chemistry of HNO3 , 1975 .

[20]  P. V. Danckwerts.  Absorption by simultaneous diffusion and chemical reaction into particles of various shapes and into falling drops , 1951 .