On the Localization of Persistent Currents Due to Trapped Magnetic Flux at the Stacking Faults of Graphite at Room Temperature

Granular superconductivity at high temperatures in graphite can emerge at certain two-dimensional (2D) stacking faults (SFs) between regions with twisted (around the c-axis) or untwisted crystalline regions with Bernal (ABA…) and/or rhombohedral (ABCABCA…) stacking order. One way to observe experimentally such 2D superconductivity is to measure the frozen magnetic flux produced by a permanent current loop that remains after removing an external magnetic field applied normal to the SFs. Magnetic force microscopy was used to localize and characterize such a permanent current path found in one natural graphite sample out of ∼50 measured graphite samples of different origins. The position of the current path drifts with time and roughly follows a logarithmic time dependence similar to the one for flux creep in type II superconductors. We demonstrate that a ≃10 nm deep scratch on the sample surface at the position of the current path causes a change in its location. A further scratch was enough to irreversibly destroy the remanent state of the sample at room temperature. Our studies clarify some of the reasons for the difficulties of finding a trapped flux in a remanent state at room temperature in graphite samples with SFs.

[1]  Kenji Watanabe,et al.  Superconductivity in rhombohedral trilayer graphene , 2021, Nature.

[2]  M. Stiller,et al.  Influence of surface band bending on a narrow band gap semiconductor: Tunneling atomic force studies of graphite with Bernal and rhombohedral stacking orders , 2021, 2104.02142.

[3]  A. Manzin,et al.  Magnetic Force Microscopy: Comparison and Validation of Different Magnetic Force Microscopy Calibration Schemes (Small 11/2020) , 2020 .

[4]  A. Manzin,et al.  Comparison and Validation of Different Magnetic Force Microscopy Calibration Schemes. , 2020, Small.

[5]  M. Stiller,et al.  Record‐Breaking Magnetoresistance at the Edge of a Microflake of Natural Graphite , 2019, Advanced Engineering Materials.

[6]  F. Guinea,et al.  Twists and the electronic structure of graphitic materials. , 2019, Nano letters.

[7]  P. Esquinazi Ordered Defects: A Roadmap towards room temperature Superconductivity and Magnetic Order , 2019, 1902.07489.

[8]  A. Zakharov,et al.  Flat-Band Electronic Structure and Interlayer Spacing Influence in Rhombohedral Four-Layer Graphene. , 2018, Nano letters.

[9]  G. Volovik Graphite, Graphene, and the Flat Band Superconductivity , 2018, 1803.08799.

[10]  I. Gilmutdinov,et al.  Observation of Persistent Currents in Finely Dispersed Pyrolytic Graphite , 2018 .

[11]  Takashi Taniguchi,et al.  Unconventional superconductivity in magic-angle graphene superlattices , 2018, Nature.

[12]  M. Stiller,et al.  Local Magnetic Measurements of Trapped Flux Through a Permanent Current Path in Graphite , 2018, 1801.08836.

[13]  A. Ouerghi,et al.  Flat electronic bands in long sequences of rhombohedral-stacked graphene , 2017, Physical Review B.

[14]  V. Novosad,et al.  Observation of superconducting vortex clusters in S/F hybrids , 2016, Scientific Reports.

[15]  Q. Xue,et al.  Interface high-temperature superconductivity , 2016, 1610.03576.

[16]  J. Meijer,et al.  Identification of a possible superconducting transition above room temperature in natural graphite crystals , 2016, 1606.09425.

[17]  A. Ouerghi,et al.  Evidence for Flat Bands near the Fermi Level in Epitaxial Rhombohedral Multilayer Graphene. , 2015, ACS nano.

[18]  P. Esquinazi,et al.  Granular superconductivity below 5 K in SPI-II pyrolytic graphite , 2014, 1412.8573.

[19]  Y. Lysogorskiy,et al.  On the superconductivity of graphite interfaces , 2014, 1407.2060.

[20]  Evelyn Tang,et al.  Strain-Induced Helical Flat Band and Interface Superconductivity in Topological Crystalline Insulators , 2014 .

[21]  Evelyn Tang,et al.  Strain-induced partially flat band, helical snake states and interface superconductivity in topological crystalline insulators , 2014, Nature Physics.

[22]  P. Esquinazi,et al.  Size dependence of the Josephson critical behavior in pyrolytic graphite TEM lamellae , 2014, 1401.4959.

[23]  A. Taraphder,et al.  Phase segregation of superconductivity and ferromagnetism at the LaAlO3/SrTiO3 interface , 2013, Journal of physics. Condensed matter : an Institute of Physics journal.

[24]  T. Heikkila,et al.  Surface Superconductivity in Rhombohedral Graphite , 2012, 1210.7075.

[25]  P. Esquinazi Invited review: Graphite and its hidden superconductivity , 2013, 1312.4459.

[26]  L. Covaci,et al.  Tight-binding description of intrinsic superconducting correlations in multilayer graphene , 2013, 1302.1073.

[27]  T. Scheike,et al.  Granular superconductivity at room temperature in bulk highly oriented pyrolytic graphite samples , 2013, 1301.4395.

[28]  A. Harju,et al.  High-temperature surface superconductivity in rhombohedral graphite , 2012, 1210.7595.

[29]  M. Liebmann,et al.  Networks of ABA and ABC stacked graphene on mica observed by scanning tunneling microscopy , 2012, 1207.5427.

[30]  P. Mallet,et al.  Unraveling the intrinsic and robust nature of van Hove singularities in twisted bilayer graphene by scanning tunneling microscopy and theoretical analysis. , 2012, Physical review letters.

[31]  T. Scheike,et al.  Can Doping Graphite Trigger Room Temperature Superconductivity? Evidence for Granular High‐Temperature Superconductivity in Water‐Treated Graphite Powder , 2012, Advanced materials.

[32]  P. Esquinazi,et al.  Josephson-coupled superconducting regions embedded at the interfaces of highly oriented pyrolytic graphite , 2012, 1206.2463.

[33]  Q. Guo,et al.  High-resolution TEM observations of isolated rhombohedral crystallites in graphite blocks , 2012 .

[34]  G. E. Volovik,et al.  High-temperature surface superconductivity in topological flat-band systems , 2011, 1103.2033.

[35]  J. Kirtley Fundamental studies of superconductors using scanning magnetic imaging , 2010, 1008.3179.

[36]  J. Gómez‐Herrero,et al.  Upper bound for the magnetic force gradient in graphite. , 2010, Physical review letters.

[37]  D. Rugar,et al.  Controlled manipulation of individual vortices in a superconductor , 2008, 0810.0790.

[38]  A. A. Dubrovskiĭ,et al.  Magnetoresistance hysteresis in granular HTSCs as a manifestation of the magnetic flux trapped by superconducting grains in YBCO + CuO composites , 2007 .

[39]  K. Nenkov,et al.  Fermi-surface rearrangement in Bi bicrystals with twisting superconducting crystallite interfaces , 2007 .

[40]  Y. Kopelevich,et al.  Ferromagnetism and Superconductivity in Carbon-based Systems , 2006, cond-mat/0609497.

[41]  M. Jonson,et al.  Direct evidence for interfacial superconductivity in two-layer semiconducting heterostructures , 2006 .

[42]  N. García,et al.  Electrostatic force microscopy on oriented graphite surfaces: coexistence of insulating and conducting behaviors. , 2006, Physical review letters.

[43]  T. Butz,et al.  Ferromagnetic Spots in Graphite Produced by Proton Irradiation , 2003 .

[44]  T. Butz,et al.  Induced magnetic ordering by proton irradiation in graphite. , 2003, Physical review letters.

[45]  A. I. Fedorenko,et al.  Novel superconducting semiconducting superlattices: dislocation-induced superconductivity? , 2001, Physical review letters.

[46]  Y. Kopelevich,et al.  Ferromagnetic- and Superconducting-Like Behavior of Graphite , 1999, cond-mat/9912413.

[47]  D. Gunter,et al.  Meissner holes in superconductors , 1997 .

[48]  N. Leporda,et al.  Restructuring of the energy spectrum in large-angle bismuth bicrystals , 1995 .

[49]  A. D. Grozav,et al.  Experimental observation of a superconducting phase with T c ≃8.5 K in large-angle bismuth bicrystals , 1992 .

[50]  S. Senoussi,et al.  The contribution of the intergrain currents to the low field hysteresis cycle of granular superconductors and the connection with the micro- and macrostructures , 1991 .

[51]  J. Villégier,et al.  Size dependence of the superconducting critical temperature and fields of Nb/Al multilayers , 1986 .

[52]  L. Bulaevskii,et al.  Localization and superconductivity , 1984 .

[53]  B. T. Kelly,et al.  Physics of Graphite , 1981 .

[54]  K. Antonowich The effect of microwaves on DC current in an Al–carbon–Al sandwich , 1975 .

[55]  K. Antonowicz̵ Possible superconductivity at room temperature , 1974, Nature.