Design of a luminescence pattern via altering the crystal structure and doping ions to create warm white LEDs.

Presently considerable interest in phosphor-converted warm LEDs which meet the stringent requirements of general illumination is stimulated. Here we report warm white LEDs made by altering the crystal structure and doping ions, which can govern the luminescence pattern to modulate the correlated color temperature and color-rendering index.

[1]  Fuqiang Huang,et al.  Red, green and blue emissions coexistence in white-light-emitting Ca11(SiO4)4(BO3)2:Ce3+,Eu2+,Eu3+ phosphor , 2013 .

[2]  Z. Xia,et al.  Preparation and luminescence properties of Ce3+ and Ce3+/Tb(3+)-activated Y4Si2O7N2 phosphors. , 2013, Dalton transactions.

[3]  Yongchao Jia,et al.  Utilizing Tb3+ as an energy transfer bridge to connect Eu(2+)-Sm3+ luminescent centers: realization of efficient Sm3+ red emission under near-UV excitation. , 2013, Chemical communications.

[4]  Jun Lin,et al.  Tunable luminescence and energy transfer properties of Ca5(PO4)2SiO4:Ce3+/Tb3+/Mn2+ phosphors , 2013 .

[5]  Yongchao Jia,et al.  Tunable color of Ce3+/Tb3+/Mn(2+)-coactivated CaScAlSiO6 via energy transfer: a single-component red/white-emitting phosphor. , 2013, Inorganic chemistry.

[6]  Yeju Huang,et al.  A novel orange-yellow-emitting Ba3Lu(PO4)3:Eu2+,Mn2+ phosphor with energy transfer for UV-excited white LEDs. , 2013, Dalton transactions.

[7]  F. Liu,et al.  New yellow Ba0.93Eu0.07Al2O4 phosphor for warm-white light-emitting diodes through single-emitting-center conversion , 2013, Light: Science & Applications.

[8]  Wei-Ren Liu,et al.  Crystal structure of blue–white–yellow color-tunable Ca4Si2O7F2:Eu2+,Mn2+ phosphor and investigation of color tunability through energy transfer for single-phase white-light near-ultraviolet LEDs , 2012 .

[9]  C. Yeh,et al.  A study on the luminescence and energy transfer of single-phase and color-tunable KCaY(PO4)2:Eu2+,Mn2+ phosphor for application in white-light LEDs. , 2012, Inorganic chemistry.

[10]  Jun Lin,et al.  Luminescence and energy transfer properties of Ca8Gd2(PO4)6O2:A (A = Ce3+/Eu2+/Tb3+/Dy3+/Mn2+) phosphors , 2012 .

[11]  Xiaojun Wang,et al.  Tunable full-color-emitting Ca3Sc2Si3O12:Ce3+, Mn2+ phosphor via charge compensation and energy transfer. , 2011, Chemical communications.

[12]  H. Höppe,et al.  Recent developments in the field of inorganic phosphors. , 2009, Angewandte Chemie.

[13]  Zhihao Yuan,et al.  Tunable single-doped single-host full-color-emitting LaAlO(3):Eu phosphor via valence state-controlled means. , 2009, Chemical communications.

[14]  R. Xie,et al.  Silicon-based oxynitride and nitride phosphors for white LEDs—A review , 2007 .

[15]  Teng‐Ming Chen,et al.  Luminescence and energy transfer of Eu- and Mn-coactivated CaAl2Si2O8 as a potential phosphor for white-light UVLED , 2005 .

[16]  P. Dorenbos Energy of the first 4f7→4f65d transition of Eu2+ in inorganic compounds , 2003 .

[17]  P. Schmidt,et al.  Inorganic Luminescent Materials: 100 Years of Research and Application , 2003 .

[18]  G. Blasse,et al.  Energy transfer between inequivalent Eu2+ ions , 1986 .

[19]  M. M. Broer,et al.  Resonant Fluorescence Line Narrowing in La 1 − x P 5 O 14 : Nd x 3 + , 1982 .