Dendrimer waveguide based high-efficiency terahertz source

Dendrimer is a workhorse nanomaterial for a number of important photonic devices. The electro-optic (EO) properties of a chromophore doped and poled dendrimer film exhibits higher electro-optic coefficient r33 . Measured refractive index shows significant difference between poled and unpoled dendrimer film. The r33 value was determined to be ~130 pm/V at 633 nm that dropped to ~90 pm/V at 1553 nm. Dendrimer waveguide can be used to design several important photonic devices. EO dendrimer is used to generate terahertz radiation via electro-optic route. Here electro-optic rectification and difference frequency generation has been demonstrated. Significantly higher terahertz power can be generated by the higher χ(2) dendrimer emitter of the present investigation.

[1]  D. Tomalia Birth of a new macromolecular architecture: dendrimers as quantized building blocks for nanoscale synthetic polymer chemistry , 2005 .

[2]  Larry R. Dalton,et al.  Highly efficient and thermally stable organic/polymeric electro-optic materials by dendritic approach , 2001, SPIE Optics + Photonics.

[3]  Mark Cronin-Golomb,et al.  Cascaded nonlinear difference-frequency generation of enhanced terahertz wave production. , 2004, Optics letters.

[4]  L. Michael Hayden,et al.  New materials for optical rectification and electrooptic sampling of ultrashort pulses in the terahertz regime , 2003 .

[5]  Peter Meissner,et al.  Coherent Generation and Detection of Continuous Terahertz Waves Using Two Photomixers Driven by Laser Diodes , 2004, Infrared and Millimeter Waves, Conference Digest of the 2004 Joint 29th International Conference on 2004 and 12th International Conference on Terahertz Electronics, 2004..

[6]  Robert Blum,et al.  High-electric-field poling of nonlinear optical polymers , 1998 .

[7]  C. Liu,et al.  Power scalable compact THz system based on an ultrafast Yb-doped fiber amplifier. , 2006, Optics express.

[8]  J. Sherwood,et al.  Terahertz pulse generation in an organic crystal by optical rectification and resonant excitation of molecular charge transfer , 2002 .

[9]  Yujie J. Ding,et al.  Guest–host polyetherketone polymer for applications in integrated-optical devices: characterization , 2002 .

[10]  Stephen T. Kowel,et al.  Second-harmonic generation and absorption studies of polymer-dye films oriented by corona-onset poling at elevated temperatures , 1989 .

[11]  L. Hayden,et al.  Generation and detection of terahertz radiation with multilayered electro-optic polymer films. , 2002, Optics letters.

[12]  M. Scalora,et al.  Collinear terahertz generation in photonic crystal structures via difference-frequency generation , 2006 .

[13]  Frank K. Tittel,et al.  Tunable, fiber coupled spectrometer based on difference-frequency generation in periodically poled lithium niobate , 2001 .

[14]  Nasser N Peyghambarian,et al.  Polarization-insensitive transition between sol-gel waveguide and electrooptic polymer and intensity modulation for all-optical networks , 2003 .

[15]  D. Remiens,et al.  Electro-optic characterization of (Pb, La)TiO3 thin films using prism-coupling technique , 1999 .

[16]  Xiang Zhang,et al.  Electro-optic transceivers for terahertz-wave applications , 2001 .

[17]  S. Wada,et al.  Difference-frequency terahertz-wave generation from 4-dimethylamino-N-methyl-4-stilbazolium-tosylate by use of an electronically tuned Ti:sapphire laser. , 1999, Optics letters.

[18]  Francesco Michelotti,et al.  Study of the orientational relaxation dynamics in a nonlinear optical copolymer by means of a pole and probe technique , 1996 .

[20]  C. Joshi,et al.  High-power terahertz radiation source based on difference frequency mixing of CO/sub 2/ laser lines , 2005, (CLEO). Conference on Lasers and Electro-Optics, 2005..

[21]  C. C. Teng,et al.  Simple reflection technique for measuring the electro‐optic coefficient of poled polymers , 1990 .

[22]  W. Herman,et al.  Chielectric relaxation: chromophore dynamics in an azo-dye-doped polymer , 1998 .

[23]  Wei Shi,et al.  Single-frequency terahertz source pumped by Q-switched fiber lasers based on difference-frequency generation in GaSe crystal. , 2007, Optics letters.

[24]  Francois Kajzar,et al.  Nonlinear optical properties of poled polymers , 1991, Optics & Photonics.

[25]  D. Gordon,et al.  Tunable, high peak power terahertz radiation from optical rectification of a short modulated laser pulse. , 2006, Optics express.

[26]  Timothy J. Carrig,et al.  Scaling of terahertz radiation via optical rectification in electro‐optic crystals , 1995 .

[27]  J. Schildkraut Limitations to the determination of the optical properties of a thin film by combined ellipsometric and surface plasmon resonance measurements. , 1988, Applied optics.