Design and Fabrication of Chitosan for Application of Artificial Photosynthesis

Artificial photosynthesis is a new approach to generate sustainable energy. In order to constrain reaction solution in a solid state structure and increase the reaction efficiency in artificial photosynthesis reactions, we presented two methods to fabricate the chitosan scaffold with interconnected micro channels as construction structure of a novel artificial photosynthesis device. We built 3D chitosan structure with a home-made heterogeneous 3D rapid prototyping machine, and we used lyophilization method to generate the micron-scale pores inside the chitosan scaffold. Chitosan in acetic acid could achieve different viscosities. We found a proper chitosan recipe to construct 3D scaffold by our own rapid prototyping machine. Optional support material sodium bicarbonate was used in printing 3D scaffold for holding the printed structures, and the results images indicate that this method can make the scaffold stronger and more stable.

[1]  Qingwei Zhang,et al.  Micro and Nano Design and Fabrication of a Novel Artificial Photosynthesis Device , 2012 .

[2]  Y. Wong,et al.  Direct writing of chitosan scaffolds using a robotic system , 2005 .

[3]  Junji Sugiyama,et al.  Microstructure and mechanical properties of bacterial cellulose/chitosan porous scaffold , 2010 .

[4]  J. Desbrières,et al.  Viscosity of semiflexible chitosan solutions: influence of concentration, temperature, and role of intermolecular interactions. , 2002, Biomacromolecules.

[5]  S. Madihally,et al.  Porous chitosan scaffolds for tissue engineering. , 1999, Biomaterials.

[6]  T. Moore,et al.  Solar fuels via artificial photosynthesis. , 2009, Accounts of chemical research.

[7]  Makarand V Risbud,et al.  Chitosan: a versatile biopolymer for orthopaedic tissue-engineering. , 2005, Biomaterials.

[8]  Carlo Montemagno,et al.  Artificial photosynthesis in ranaspumin-2 based foam. , 2010, Nano letters.

[9]  Han Tong Loh,et al.  Fabrication of 3D chitosan–hydroxyapatite scaffolds using a robotic dispensing system , 2002 .

[10]  Tao Wang,et al.  Chitosan nanoparticle as protein delivery carrier--systematic examination of fabrication conditions for efficient loading and release. , 2007, Colloids and surfaces. B, Biointerfaces.

[11]  J. Leroux,et al.  Novel injectable neutral solutions of chitosan form biodegradable gels in situ. , 2000, Biomaterials.

[12]  Claude Moreau,et al.  Isomerization of glucose into fructose in the presence of cation-exchanged zeolites and hydrotalcites ☆ , 2000 .

[13]  O. Kwon,et al.  Electrospinning of chitosan dissolved in concentrated acetic acid solution. , 2005, Biomaterials.