论文信息 - On the Thermodynamics of Non‐Electrolyte Solutions and Its Technical Applications III. Systems with Associated Components

On the Thermodynamics of Non‐Electrolyte Solutions and Its Technical Applications III. Systems with Associated Components

The influence of continuous association of one component on the free energy of a non‐electrolyte solution is derived from a few assumptions. The result is in accord with available data for hydrocarbon‐alcohol solutions. Systems of two associating components and the general interpretation of the free energy of non‐electrolyte solutions are briefly discussed.

O. Redlich | A. Kister

[1] G. Scatchard,et al. Vapor-Liquid Equilibrium. VI. Benzene-Methanol Mixtures1 , 1946 .

[2] P. Flory. Statistical Mechanics of Linear Association Equilibria , 1946 .

[3] J. Mayer,et al. The Region of Critical Solution of Binary Liquids, Evidence for an Anomalous First‐Order Transition in the System Triethyl Amine‐Water , 1941 .

[4] G. Scatchard,et al. Vapor–Liquid Equilibrium. III. Benzene–Cyclohexane Mixtures. , 1939 .

[5] E. N. Lassettre. The Interpretation of Freezing Point Lowering Data in Terms of Polymerization , 1937 .

[6] J. B. Ferguson,et al. The System Ethyl Alcohol–n-Heptane at 30°C. , 1932 .

[7] G. Scatchard,et al. Equilibria in Non-electrolyte Solutions in Relation to the Vapor Pressures and Densities of the Components. , 1931 .

[8] J. B. Ferguson. The System Methyl Alcohol-n-Hexane at 45 Degrees , 1931 .

[9] S. C. Lee. Partial Pressure Isotherms II. , 1930 .

[10] C. P. Smyth,et al. MOLECULAR ORIENTATION AND THE PARTIAL VAPOR PRESSURES OF BINARY LIQUID MIXTURES. II. SYSTEMS CONTAINING AN ALCOHOL , 1929 .

[11] D. Tyrer. XCIV.—The volume of a solute in solution. Part II. The influences of molecular association, solvate formation and ionisation , 1911 .

[12] R. Lattey. CXCI.—The vapour pressures of triethylamine, of 2 : 4 : 6-trimethylpyridine, and of their mixtures with water , 2022 .