Line mixing effects in the self- and N(2)-broadened Q-branch of the nu(2) + nu(3) band of N(2)O.

Line mixing effects are observed in the self- and N(2)-broadened Q-branch of the nu(2) + nu(3) band of N(2)O at 2798.2 cm(-1). The spectra were recorded at 295 K using a Fourier spectrometer. Experimental results are compared with computations performed taking into account off-diagonal elements of the relaxation matrix.

[1]  A. Pine,et al.  Q‐branch line mixing in N2O: Effects of l‐type doubling , 1988 .

[2]  C. Boulet,et al.  Collisionally induced population transfer effect in infrared absorption spectra. I. A line‐by‐line coupling theory from resonances to the far wings , 1988 .

[3]  C. Boulet,et al.  IOS and ECS line coupling calculation for the CO–He system: Influence on the vibration–rotation band shapes , 1987 .

[4]  G. Millot,et al.  Study of rotational relaxation fitting laws from calculations of SRS N2 Q-branch , 1987 .

[5]  B. Gentry,et al.  Line mixing in a N2‐broadened CO2 Q branch observed with a tunable diode laser , 1987 .

[6]  D. Robert,et al.  Line coupling in the temperature and frequency dependences of absorption in the microwindows of the 4.3 μm CO2 band , 1986 .

[7]  G. Millot,et al.  Rotational collisional line broadening at high temperatures in the N2 fundamental Q-branch studied with stimulated Raman spectroscopy , 1986 .

[8]  B. Gentry,et al.  Rotational collisional narrowing in an infrared CO2 Q branch studied with a tunable-diode laser , 1986 .

[9]  R. Farrow,et al.  Calculation of collisionally narrowed coherent anti-Stokes Raman spectroscopy spectra. , 1985, Optics letters.

[10]  P. Dahoo,et al.  Self-broadening parameters in the ν3 band of 14N2 16O , 1985 .

[11]  N. Lacome,et al.  N2- and O2-broadening parameters in the ν3 band of 14N2 16O , 1985 .

[12]  G. Guelachvili,et al.  Fourier transform measurement of self-, N(2)-, and O(2)-broadening of N(2)O lines: temperature dependence of linewidths. , 1984, Applied optics.

[13]  V. M. Devi,et al.  Analysis of high resolution fourier transform and diode laser spectra of the ν9 band of ethane , 1983 .

[14]  G. J. Rosasco,et al.  Line interference effects in the vibrational Q-branch spectra of N2 and CO , 1983 .

[15]  L. Bonamy,et al.  Overlapping effects and motional narrowing in molecular band shapes: Application to the Q branch of HDa) , 1977 .

[16]  K. Lam Application of pressure broadening theory to the calculation of atmospheric oxygen and water vapor microwave absorption , 1977 .

[17]  A. Ben-Reuven,et al.  Line Mixing by Collisions in the Far‐Infrared Spectrum of Ammonia , 1969 .

[18]  U. Fano Pressure Broadening as a Prototype of Relaxation , 1963 .