论文信息 - The Temperature Dependence of the Diamagnetic Shielding Correction for Proton NMR in Water

The Temperature Dependence of the Diamagnetic Shielding Correction for Proton NMR in Water

The fractional frequency shift in the nmr signal from protons in a spherically-shaped pure water sample has been measured directly as -10.36(30) × 10-9 °C-1 over the range 5 °C to 45 °C. A revised value of 25.69(14) × 10-6 is suggested for the proton diamagnetic shielding correction in water at 25 °C, leading to μ'p(25 °C)/μB = 0.001 520 993 136(17).

B W Petley | B. Petley | R. W. Donaldson | R W Donaldson

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