Hydroacoustic and geochemical traces of marine gas seepage in the North Sea

This PhD thesis consists of a general introduction Chapter I, followed by three stand-alone Chapters II-IV, a general conclusion Chapter V, and supplemental content in the Appendix. Chapter II is the reprint of a published paper that outlines the feasibility of ship-born gas bubble detection with conventional multibeam mapping sonar and its advantages compared to single beam sounders. Chapter III consists of a submitted manuscript describing the use of a prototype in situ multibeam bubble monitoring system (GasQuant) and illustrates the device’s potential to resolve tempo-spatial variation of gas seepage. Due to technical difficulties, the aspired calibration of GasQuant failed and a quantitative analysis of the echo signals could not be accomplished. Even though, gas bubble acoustic inversion theory and principle limitations are discussed in Appendix B. Furthermore we attach a registered patented generic algorithm in Appendix A to e.g. automatically detect rising gas bubbles in sonar data. Chapter IV covers the seepage at a specific seep site in the North Sea combining acoustic and geochemical methods. Thus, the source strength of the respective seep field could be determined and the further fate of methane seepage in the North Sea is discussed. This Chapter is again in the form of a manuscript for a peer reviewed journal and will be submitted shortly. Two peer-reviewed Co-authorship publications abstracts related to this work can additionally be found in the Appendix C and Appendix D.

[1]  Olaf Pfannkuche,et al.  GEOMAR Landers as Long-Term Deep-Sea Observatories , 2003 .

[2]  I. Leifer,et al.  Transient discharges from marine hydrocarbon seeps: spatial and temporal variability , 2004 .

[3]  D. Archer,et al.  Global inventory of methane clathrate: sensitivity to changes in the deep ocean , 2004 .

[4]  O. Schmale Submarine methane seepage in the Paleo Dnepr Area and Sorokin Trough and its influence on the Black Sea methane budget , 2007 .

[5]  A. Vogel,et al.  Modern Optical Techniques in Fluid Mechanics , 1984 .

[6]  A. Moll Regional distribution of primary production in the North Sea simulated by a three-dimensional model , 1998 .

[7]  J. Zimmerman,et al.  Review of the physical oceanography of the North Sea , 1990 .

[8]  Kerry W. Commander,et al.  Off‐resonance contributions to acoustical bubble spectra , 1989 .

[9]  Jens Greinert,et al.  Monitoring temporal variability of bubble release at seeps: The hydroacoustic swath system GasQuant , 2008 .

[10]  Ian Bryden,et al.  CONTRIBUTIONS TO ATMOSPHERIC METHANE BY NATURAL SEEPAGES ON THE UK CONTINENTAL SHELF , 1997 .

[11]  Victor C. Anderson,et al.  Sound Scattering from a Fluid Sphere , 1950 .

[12]  Darrell R. Jackson,et al.  Spatial and temporal variation of acoustic backscatter in the STRESS experiment , 1994 .

[13]  Jason T. Holt,et al.  Modelling the tidal mixing fronts and seasonal stratification of the Northwest European Continental shelf , 2008 .

[14]  I. Leifer,et al.  Oceanic methane layers: the hydrocarbon seep bubble deposition hypothesis , 2002 .

[15]  Paul Wessel,et al.  Interpolation with Splines in Tension: A Green's Function Approach , 1998 .

[16]  A. Judd,et al.  Natural seabed gas seeps as sources of atmospheric methane , 2004 .

[17]  C. Martens,et al.  Biogeochemical cycling in an organic-rich coastal marine basin—I. Methane sediment-water exchange processes , 1980 .

[18]  Ira Leifera,et al.  Measurement of marine hydrocarbon seep flow through fractured rock and unconsolidated sediment , 2005 .

[19]  G. Rehder,et al.  Methane sources, distributions, and fluxes from cold vent sites at Hydrate Ridge, Cascadia Margin , 2005 .

[20]  James A. Finch,et al.  Axial velocity profiles of single bubbles in water/frother solutions , 1996 .

[21]  Anthony P. Lyons,et al.  Predictions of the acoustic scattering response of free‐methane bubbles in muddy sediments , 1996 .

[22]  K. Foote Linearity of fisheries acoustics, with addition theorems , 1983 .

[23]  Gerhard Bohrmann,et al.  Vodyanitskii mud volcano, Sorokin trough, Black Sea: Geological characterization and quantification of gas bubble streams , 2009 .

[24]  Shelly L. Miller,et al.  Particle Image Velocimetry of Human Cough , 2011 .

[25]  R. Battino,et al.  Solubility of Gases in Liquids , 1966 .

[26]  R. Keir,et al.  Methane and methane carbon isotope ratios in the Northeast Atlantic including the Mid-Atlantic Ridge (50°N) , 2005 .

[27]  Bernd Jähne,et al.  Air-Water Gas Transfer , 1995 .

[28]  Gerold Wefer,et al.  Ocean Margin Systems , 2003 .

[29]  O. Schmale,et al.  Methane emission from high‐intensity marine gas seeps in the Black Sea into the atmosphere , 2005 .

[30]  Ira Leifer,et al.  Shallow seabed methane gas could pose coastal hazard , 2006 .

[31]  J. Greinert,et al.  Hydroacoustic experiments to establish a method for the determination of methane bubble fluxes at cold seeps , 2004 .

[32]  J. Hunter,et al.  Fronts in the Irish Sea , 1974, Nature.

[33]  Jan O. Backhaus,et al.  Transport of conservative passive tracers in the North Sea: first results of a circulation and transport model , 1987 .

[34]  M. Hovland,et al.  The geological methane budget at Continental Margins and its influence on climate change , 2002 .

[35]  Giuseppe Etiope,et al.  New Directions: GEM—Geologic Emissions of Methane, the missing source in the atmospheric methane budget☆ , 2004 .

[36]  David M. Karl,et al.  Aerobic production of methane in the sea , 2008 .

[37]  J. Greinert,et al.  1300-m-high rising bubbles from mud volcanoes at 2080m in the Black Sea: Hydroacoustic characteristics and temporal variability , 2006 .

[38]  I. Leifer,et al.  Corrigendum to: Measurement of marine hydrocarbon seep flow through fractured rock and unconsolidated sediment: [Marine and Petroleum Geology 22 (2005), 551–558] , 2006 .

[39]  Kerstin Jerosch,et al.  Methane discharge from a deep-sea submarine mud volcano into the upper water column by gas hydrate-coated methane bubbles , 2006 .

[40]  D. Blake,et al.  Continuing Worldwide Increase in Tropospheric Methane, 1978 to 1987 , 1988, Science.

[41]  D. Valentine,et al.  Water column methane oxidation adjacent to an area of active hydrate dissociation, Eel river Basin , 2001 .

[42]  T. Pohlmann,et al.  The Multiple Sources and Patterns of Methane inNorth Sea Waters , 1998 .

[43]  E. Dlugokencky,et al.  Atmospheric chemistry and greenhouse gases , 2001 .

[44]  Larry A. Mayer,et al.  3D visualization for pelagic fisheries research and assessment , 2002 .

[45]  M. Hovland,et al.  Understanding Geology as the Key to Using Seepage in Exploration: The Spectrum of Seepage Styles , 1996 .

[46]  M. Torres,et al.  Fluid and chemical fluxes in and out of sediments hosting methane hydrate deposits on Hydrate Ridge, OR, I: Hydrological provinces , 2002 .

[47]  T. Stanton Simple approximate formulas for backscattering of sound by spherical and elongated objects , 1988 .

[48]  A. Boetius,et al.  Methane emission and consumption at a North Sea gas seep (Tommeliten area) , 2005 .

[49]  K. Kvenvolden,et al.  Gaia's breath—global methane exhalations , 2005 .

[50]  Peter Lonsdale,et al.  Acoustically detected hydrocarbon plumes rising from 2‐km depths in Guaymas Basin, Gulf of California , 1985 .

[51]  Ira Leifer,et al.  The bubble mechanism for methane transport from the shallow sea bed to the surface: A review and sensitivity study , 2002 .

[52]  A. Anderson,et al.  Acoustics of Gas-Bearing Sediments. , 1974 .

[53]  G. Wegener Methane oxidation and carbon assimilation in marine sediments , 2008 .

[54]  I. Ostrovsky,et al.  Quantifying gas ebullition with echosounder: the role of methane transport by bubbles in a medium‐sized lake , 2008 .

[55]  Michel D'Heur Porosity and hydrocarbon distribution in the North Sea chalk reservoirs , 1984 .

[56]  Ira Leifer,et al.  Optical Measurement of Bubbles: System Design and Application , 2003 .

[57]  B. M. Bary,et al.  Echo-sounding on probable gas bubbles from the bottom of Saanich Inlet, British Columbia , 1965 .

[58]  C. Clay,et al.  Fundamentals of Acoustical Oceanography , 1997 .

[59]  I. Leifer,et al.  Dynamics of the gas flux from shallow gas hydrate deposits: interaction between oily hydrate bubbles and the oceanic environment , 2003 .

[60]  Dietmar Schumacher,et al.  Hydrocarbon Migration and Its Near-Surface Expression , 1996 .

[61]  R. D. Adams,et al.  Seasonal changes in the circulation of the northern North Sea , 1992 .

[62]  J. Houghton,et al.  Climate change 2001 : the scientific basis , 2001 .

[63]  R. Bidigare,et al.  Gulf of Mexico hydrocarbon seep communities , 1989 .

[64]  D. Schimel Microbial production and consumption of greenhouse gases: Methane, nitrogen oxides, and halomethanes , 1993 .

[65]  Garth van der Kamp,et al.  Theory for the effects of free gas in subsea formations on tidal pore pressure variations and seafloor displacements , 1998 .

[66]  M. Hutnak Seabed Fluid Flow , 2007 .

[67]  Ira Leifer,et al.  A Study on the Temperature Variation of Rise Velocity for Large Clean Bubbles , 2000 .

[68]  G. Panteleev,et al.  The distribution of methane on the Siberian Arctic shelves: Implications for the marine methane cycle , 2005 .

[69]  T. Pohlmann Calculating the annual cycle of the vertical eddy viscosity in the North Sea with a three-dimensional baroclinic shelf sea circulation model , 1996 .

[70]  G. Rehder,et al.  Methane and pCO2 in the Kuroshio and the South China Sea during maximum summer surface temperatures , 2001 .

[71]  T. Wever,et al.  Potential environmental control of free shallow gas in the seafloor of Eckernförde Bay, Germany , 2006 .

[72]  I. Leifer,et al.  Turbine tent measurements of marine hydrocarbon seeps on subhourly timescales , 2005 .

[73]  J. Greinert,et al.  Geological and morphological setting of 2778 methane seeps in the Dnepr paleo-delta, northwestern Black Sea , 2006 .

[74]  Derek C. Quigley,et al.  The world's most spectacular marine hydrocarbon seeps (Coal Oil Point, Santa Barbara Channel, California): Quantification of emissions , 1999 .

[75]  Ira Leifer,et al.  Natural marine seepage blowout: Contribution to atmospheric methane , 2006 .

[76]  Herman Medwin,et al.  Acoustical determinations of bubble‐size spectra , 1977 .

[77]  I. Ostrovsky Methane bubbles in Lake Kinneret: Quantification and temporal and spatial heterogeneity , 2003 .

[78]  M. Hovland,et al.  On the self-sealing nature of marine seeps , 2002 .

[79]  M. Minnaert XVI.On musical air-bubbles and the sounds of running water , 1933 .

[80]  I. Leifer,et al.  Temporal variation in natural methane seep rate due to tides, Coal Oil Point area, California , 2001 .

[81]  F. Keppler,et al.  Methane emissions from terrestrial plants under aerobic conditions , 2006, Nature.

[82]  D. Jackson,et al.  Sonar evidence for methane ebullition in Eckernförde Bay , 1998 .

[83]  B. Calder,et al.  Automatic processing of high‐rate, high‐density multibeam echosounder data , 2003 .

[84]  M. Hovland,et al.  Characteristics of two natural gas seepages in the North Sea , 1985 .

[85]  G. Haar The Acoustic Bubble , 1996 .

[86]  R. Keir,et al.  Methane in the northern Atlantic controlled by microbial oxidation and atmospheric history , 1999 .

[87]  I. Levin,et al.  Methane concentration in aerated soils in West-Germany , 1988 .

[88]  N. P. Fofonoff,et al.  Algorithms for Computation of Fundamental Properties of Seawater. Endorsed by Unesco/SCOR/ICES/IAPSO Joint Panel on Oceanographic Tables and Standards and SCOR Working Group 51. Unesco Technical Papers in Marine Science, No. 44. , 1983 .

[89]  Derek M. Cunnold,et al.  Renewed growth of atmospheric methane , 2008 .

[90]  B. Schroot,et al.  Surface and subsurface expressions of gas seepage to the seabed – examples from the Southern North Sea , 2005 .

[91]  C. Devin,et al.  SURVEY OF THERMAL, RADIATION, AND VISCOUS DAMPING OF PULSATING AIR BUBBLES IN WATER , 1959 .

[92]  E. Suess,et al.  An improved head-space analysis method for methane in seawater , 1994 .

[93]  J. Greinert,et al.  Fate of rising methane bubbles in stratified waters: How much methane reaches the atmosphere? , 2006 .

[94]  K. Brown,et al.  Monitoring periodic and episodic flow events at Monterey Bay seeps using a new optical flow meter , 2007 .

[95]  B. Tilbrook,et al.  Production and transport of methane in oceanic particulate organic matter , 1994, Nature.