The radar response of vegetated environments, and forested areas in particular, are usually modeled using a very simple structure made of a random volume, representing a cloud of vegetation particles, lying over a semi-infinite medium with a rough interface, associated with the underlying ground. This Random Volume over Ground model can efficiently handle double-bounce scattering mechanisms, or arbitrary volume reflectivity profiles. This paper proposes to analyze a specific component of the Random Volume over Ground simplified scattering model, which concerns the double-bounce interaction between the ground and the volume. This specific contribution is not considered by classical characterization techniques and is studied in this work using a controlled experiment involving a Synthetic Aperture Radar operated in a Polarimetric and Tomographic configuration in order to image in 3D a controlled miniaturized scene composed of volume lying over a ground. It is shown that ground/volume double-bounce scattering, which remains focused at the ground level even in 3D imaging mode, and has polarimetric patterns that differ largely from those usually expected from double-bounce reflections, with volume-like features, such as a strong cross-polarized reflectivity or decorrelation between co-polarized channels. Moreover, it is shown that the full rank polarimetric patterns of the ground-volume mechanism are tightly linked to the reflectivity of the volume and may mask the ground response. As a consequence, isolating the ground response using 3D imaging does not permit to avoid a generally very strong distortion of the soil response by the double-bounce reflection, and the estimation of different geophysical parameters of the ground, such as its humidity or roughness are significantly altered.