Measurements of air-broadened and nitrogen-broadened Lorentz width coefficients and pressure shift coefficients in the nu(4) and nu(2) bands of (12)CH(4).

Air-broadened and N(2)-broadened halfwidth and pressure shift coefficients of 294 transitions in the nu(4) and nu(2) bands of (12)CH(4) have been measured from laboratory absorption spectra recorded at room temperature with the Fourier transform spectrometer in the McMath solar telescope facility of the National Solar Observatory. Total pressures of up to 551 Torr were employed with absorption paths of 5-150 cm, CH(4) volume mixing ratios of 2.6% or less, and resolutions of 0.005 and 0.01 cm(-1). A nonlinear least-squares spectral fitting technique has been utilized in the analysis of the twenty-five measured spectra. Lines up to J' = 18 in the nu(4) band and J' = 15 in the nu(2) band have been analyzed.

[1]  Robert A. Toth,et al.  Molecular line parameters for the atmospheric trace molecule spectroscopy experiment. , 1987, Applied optics.

[2]  A Goldman,et al.  The HITRAN database: 1986 edition. , 1987, Applied optics.

[3]  J. Reid,et al.  Linewidths and linestrengths in the ν2 band of HTO as measured with a tunable diode laser , 1987 .

[4]  W. B. Johnston,et al.  Self-broadened widths and absolute strengths of 12CH4 lines in the 1310–1370 cm-1 region , 1986 .

[5]  V. Malathy Devi,et al.  Measurements of (C-12)H4 nu-4 band halfwidths using a tunable diode laser system and a Fourier transform spectrometer , 1985 .

[6]  J. H. Shaw,et al.  Sources of systematic errors in line intensities. , 1985, Applied optics.

[7]  Robert A. Toth,et al.  Comparison of the frequencies of NH 3 , CO 2 , H 2 O, N 2 O, CO, and CH 4 as infrared calibration standards , 1985 .

[8]  P L Varghese,et al.  Collisional narrowing effects on spectral line shapes measured at high resolution. , 1984, Applied optics.

[9]  K. Fox Symmetry‐dependent broadening parameters for methane , 1984 .

[10]  R. Davies,et al.  Theoretical calculations of N2-broadened halfwidths of H2O using quantum Fourier transform theory. , 1983, Applied optics.

[11]  C. Rinsland,et al.  Absolute intensity measurements of the (11 1 0) II ← 00 0 0 band of 12 C 16 O 2 at 5.2 μm , 1983 .

[12]  Francisco P. J. Valero,et al.  Thermal infrared lines of methane broadened by nitrogen at low temperatures , 1983 .

[13]  V. Malathy Devi,et al.  Strengths and lorentz broadening coefficients for spectral lines in the ν3 and ν2 + ν4 bands of 12CH4 and 13CH4 , 1983 .

[14]  V. M. Devi,et al.  Tunable diode laser measurements of intensities and Lorentz broadening coefficients of lines in the ν2 band of 12CH4 , 1983 .

[15]  A. S. Pine,et al.  Collisional narrowing of HF fundamental band spectral lines by neon and argon , 1980 .

[16]  R. Davies,et al.  Theoretical calculations of H2O linewidths and pressure shifts: Comparison of the Anderson theory with quantum many-body theory for N2 and air-broadened lines , 1978 .

[17]  A. Chédin,et al.  ν4 Band of methane (12CH4 and 13CH4). Line parameters and evaluation of Jovian atmospheric transmission at 7.7 μm , 1978 .

[18]  A. S. Pine,et al.  High-resolution methane ν 3 -band spectra using a stabilized tunable difference-frequency laser system* , 1976 .

[19]  P. Varanasi,et al.  Collision-broadened linewidths of tetrahedral molecules—II. Computations for CH4 lines broadened by N2, O2, He, Ne and Ar , 1975 .

[20]  P. Varanasi Collision-broadened line widths of tetrahedral molecules—I. Theoretical formulation , 1974 .

[21]  A. Calawa,et al.  Tunable diode laser measurements of water vapour absorption line parameters , 1974 .

[22]  Kenneth Fox,et al.  Calculated linewidths for CH4 broadened by N2 and O2 , 1974 .

[23]  A. Calawa,et al.  Tunable laser measurements of water vapor transitions in the vicinity of 5 μm , 1973 .

[24]  R. S. Eng,et al.  Collisional narrowing of infrared water‐vapor transitions , 1972 .

[25]  A. Calawa,et al.  Tunable Infrared Laser Spectroscopy of Atmospheric Water Vapor , 1972, Science.

[26]  P. Varanasi,et al.  Experimental and theoretical studies on collision-broadened lines in the v4-fundamental of methane , 1972 .

[27]  P. Varanasi Collision-broadened half-widths and shapes of methane lines , 1971 .

[28]  G. Yamamoto,et al.  Rotational line width of methane , 1971 .

[29]  P. Varanasi,et al.  Calculation of Collision‐Broadened Linewidths in the Infrared Bands of Methane , 1971 .

[30]  J. Margolis Self-broadened half-widths and pressure shifts for the R-branch J-manifolds of the 3v3 methane band , 1971 .

[31]  R. L. Barger,et al.  Pressure shift and broadening of methane line at 3.39 mu studied by laser-saturated molecular absorption. , 1969 .