Influence of Mixing Sequence and Superplasticiser Dosage on the Rheological Response of Cement Pastes at Different Temperatures

An experimental methodology to study the rheological response of superplasticised cement pastes subjected to temperatures ranging from 5 to 45°C is presented. The content of a polycarboxylate-based superplasticiser (PC) and moment of its addition to the mix (direct or delayed) are investigated. A loop of shear rate ramps is applied to each sample in order to obtain information about apparent viscosities and yield stresses, as well as a measure of their thixotropic behaviour. Results from the experimental campaigns indicate PC saturation dosages depend only slightly on temperature. The evolution of yield stress and thixotropy with temperature shows inverted trends under some conditions.

[1]  Moncef L. Nehdi,et al.  Estimating rheological properties of cement pastes using various rheological models for different test geometry, gap and surface friction , 2004 .

[2]  Hamlin M. Jennings,et al.  The influence of mixing on the rheology of fresh cement paste , 1999 .

[3]  Phillip Frank Gower Banfill,et al.  The rheology of fresh concrete , 1983 .

[4]  I. Aiad,et al.  Effect of delaying addition of some concrete admixtures on the rheological properties of cement pastes , 2002 .

[5]  I. Aiad Influence of time addition of superplasticizers on the rheological properties of fresh cement pastes , 2003 .

[6]  A. Paolini,et al.  Optimum time for adding superplasticizer to Portland cement pastes , 1985 .

[7]  Nicolas Roussel,et al.  Steady and transient flow behaviour of fresh cement pastes , 2005 .

[8]  Kamal H. Khayat,et al.  Analytical models for estimating yield stress of high-performance pseudoplastic grout , 2001 .

[9]  A. Potanin Thixotropy and rheopexy of aggregated dispersions with wetting polymer , 2004 .

[10]  Leslie J. Struble,et al.  Microstructure and Flow Behavior of Fresh Cement Paste , 2005 .

[11]  Daisuke Sawaki,et al.  Influence of kind and added timing of organic admixture on the composition, structure and property of fresh cement paste , 1995 .

[12]  Y. Renardy,et al.  Experimental observation and matching numerical simulation for the deformation and breakup of immiscible drops in oscillatory shear , 2002 .

[13]  J. Lewis Colloidal Processing of Ceramics , 2004 .

[14]  C. Jolicoeur,et al.  The Influence of Temperature on the Rheological Properties of Superplasticized Cement Pastes , 1997, SP-173: Fifth CANMET/ACI International Conference on Superplasticizers and Other Chemical Admixtures in Concrete.

[15]  M. Collepardi Admixtures: Enhancing Concrete Performance , 2005 .

[16]  Christopher W. Macosko,et al.  Rheology: Principles, Measurements, and Applications , 1994 .

[17]  Robert J. Flatt,et al.  A simplified view on chemical effects perturbing the action of superplasticizers , 2001 .

[18]  A. Griesser Cement-superplasticizer interactions at ambient temperatures , 2002 .

[19]  Philippe Coussot,et al.  Viscosity bifurcation in thixotropic, yielding fluids , 2002 .

[20]  Robert Le Roy,et al.  The Marsh Cone: A Test Or a Rheological Apparatus? , 2005 .