New prospects and frontiers of nanodiamond clusters

The review is devoted to nanodiamond as a member of new nanocarbon allotropes. The past results related to the main features of detonation technology for producing nanodiamond are highlighted. Effects of technology on the structure of nanodiamond particles as well as functionalization of nanodiamond surface to chemical properties are discussed. The real structure of single nanodiamond particles has been critically reviewed and its aggregation problem emphasized. Several applications of nanodiamonds mainly as precursors for CVD diamond film growth, for forming new magnetic nanomaterials and field electron emitters are reviewed. As a result, the availability of nanodiamonds as attractive building blocks for nanotechnology is concluded.

[1]  V. Danilenko Nanocarbon Phase Diagram and Conditions for Detonation Nanodiamond Formation , 2005 .

[2]  S. A. Grudinkin,et al.  Diamond films: Initial CVD growth stage using nanodiamonds as nucleation centers , 2002 .

[3]  A. Vul,et al.  Nanodiamonds intercalated with metals: structure and diamond-graphite phase transitions , 2004 .

[4]  V. Kuznetsov,et al.  Onion-like carbon and diamond nanoparticles for optical limiting , 2002 .

[5]  E. Orlova,et al.  Preparation of Wear-Resistant Chromium Coatings Using Different Types of Nanodiamonds , 2003 .

[6]  Direct observation of isolated ultrananodimensional diamond clusters using atomic force microscopy , 2006 .

[7]  P. Brogueira,et al.  Transport and photoluminescence of hydrogenated amorphous silicon–carbon alloys , 1995 .

[8]  A. Vul,et al.  Magnetic Properties of Hydrogen‐Terminated Surface Layer of Diamond Nanoparticles , 2006 .

[9]  A. Vul,et al.  Nuclear magnetic resonance study of ultrananocrystalline diamonds , 2006, cond-mat/0701771.

[10]  Optical absorption of amorphous carbon doped with copper , 1996 .

[11]  A. Vul Characterization and Physical Properties of UNCD Particles , 2006 .

[12]  On MSSM charged Higgs-boson production in association with an electroweak W boson at electron–positron colliders , 2006, hep-ph/0610079.

[13]  I. Uvarova,et al.  Nanostructured materials and coatings for biomedical and sensor applications , 2003 .

[14]  V. Dolmatov,et al.  Currently available methods of industrial nanodiamond synthesis , 2004 .

[15]  S. A. Grudinkin,et al.  Raman scattering, AFM and nanoindentation characterisation of diamond films obtained by hot filament CVD , 2004 .

[16]  M. Yoshikawa,et al.  Structure and electronic properties of graphite nanoparticles , 1998 .

[17]  O. Shenderova,et al.  15 Nanodiamond Designing the Bio-Platform , 2006, Ultrananocrystalline Diamond.

[18]  Giulia Galli,et al.  Quantum confinement and fullerenelike surface reconstructions in nanodiamonds. , 2003, Physical review letters.

[19]  A. Vul,et al.  Magnetic Resonance Study of Nanodiamonds , 2005 .

[20]  A. Vul,et al.  Optical properties of layers of ultradisperse diamond obtained from an aqueous suspension , 1997 .

[21]  H. Makita,et al.  Low Temperature Fabrication of Diamond Films with Nanocrystal Seeding , 1995 .

[22]  E. Gusev Defects in high-κ gate dielectric stacks : nano-electronic semiconductor devices , 2006 .

[23]  K. Pandey New dimerized-chain model for the reconstruction of the diamond (111)-(2 × 1) surface , 1982 .

[24]  V. Konov,et al.  Diamond/sp2-bonded carbon structures: quantum well field electron emission? , 2001 .

[25]  Kiyotaka Asakura,et al.  Photochemical Transformation of Molecular Crystals into Devices , 2006 .

[26]  M. Ozawa,et al.  Unusually tight aggregation in detonation nanodiamond: Identification and disintegration , 2005 .

[27]  P. Badziag,et al.  Nanometre-sized diamonds are more stable than graphite , 1990, Nature.

[28]  Gamarnik Energetical preference of diamond nanoparticles. , 1996, Physical review. B, Condensed matter.

[29]  S. A. Grudinkin,et al.  Nanodiamond Injection into the Gas-Phase During CVD Diamond Film Growth , 2005 .

[30]  K. Ten,et al.  The Formation Kinetics of Detonation Nanodiamonds , 2005 .

[31]  V. Afanas’ev,et al.  Ultradisperse diamond cluster aggregation studied by atomic force microscopy , 2000 .

[32]  A. Vul,et al.  The structure of diamond nanoclusters , 1999 .

[33]  T. Alam Solid-state 13C magic angle spinning NMR spectroscopy characterization of particle size structural variations in synthetic nanodiamonds , 2004 .

[34]  A. Barnard From nanodiamond to nanowires. , 2005 .

[35]  V. Yu. Davydov,et al.  Diamond-graphite phase transition in ultradisperse-diamond clusters , 1997 .

[36]  Orlando Auciello,et al.  Electron field emission for ultrananocrystalline diamond films , 2001 .

[37]  D. Kania,et al.  Diamond : electronic properties and applications , 1995 .

[38]  Alexander N. Obraztsov,et al.  Role of the curvature of atomic layers in electron field emission from graphitic nanostructured carbon , 1999 .

[39]  G. Mcguire,et al.  Types of Nanocrystalline Diamond , 2006 .

[40]  A. Vul,et al.  Ultradisperse-Diamond Nanoclusters. Fractal Structure and Diamond–Graphite Phase Transition , 1999 .

[41]  J. Ristein,et al.  Surface science of diamond: Familiar and amazing , 2006 .

[42]  G. Kresse,et al.  Atomic and electronic structure of diamond (111) surfaces I. Reconstruction and hydrogen-induced de-reconstruction of the one dangling-bond surface , 1996 .

[43]  Andre Stesmans,et al.  Structure and defects of detonation synthesis nanodiamond , 2000 .

[44]  T. Enoki,et al.  Electrophoretic Deposition of nanosized diamond particles , 2001 .

[45]  V. G. Golubev,et al.  Optical properties of diamond films grown by MPCVD method with alternating nanodiamond injection , 2005, SPIE OPTO-Ireland.

[46]  A. Vul,et al.  Defects and impurities in nanodiamonds: EPR, NMR and TEM study , 2002 .

[47]  Yury Gogotsi,et al.  Control of sp2/sp3 carbon ratio and surface chemistry of nanodiamond powders by selective oxidation in air. , 2006, Journal of the American Chemical Society.

[48]  A. Vul,et al.  Magnetic and high resolution TEM studies of nanographite derived from nanodiamond , 2006 .

[49]  A. Vul,et al.  Intercalation of ultrafine-dispersed diamond in aqueous suspensions , 2004 .

[50]  G. Galli,et al.  Structural and Electronic Properties of Isolated Nanodiamonds: A Theoretical Perspective , 2005 .

[51]  Pate,et al.  Photoelectric emission from negative-electron-affinity diamond (111) surfaces: Exciton breakup versus conduction-band emission. , 1995, Physical review. B, Condensed matter.

[52]  A. Vul,et al.  Fractal structure of ultradisperse-diamond clusters , 1998 .

[53]  S. Gordeev,et al.  Paramagnetic properties of nanodiamond , 2001 .

[54]  D. Kania,et al.  Dynamics of Free Carriers in Diamond , 1995 .

[55]  A. Vul,et al.  Thermoelectric Effect in Field Electron Emission from Nanocarbon , 2005 .

[56]  D. Dandy,et al.  Studies on nucleation process in diamond CVD: an overview of recent developments , 1995 .

[57]  A. Vul,et al.  Optical properties of nanodiamond layers , 2001 .

[58]  A. Vul,et al.  The mechanism of autoelectron emission in carbon nanostructures , 2003 .

[59]  Dieter M. Gruen,et al.  Diamond Films: Recent Developments , 1998 .

[60]  N. Mel’nik,et al.  Purification and Functionalization of Nanodiamond , 2005 .

[61]  S. Russo,et al.  Ab initio modelling of the stability of nanocrystalline diamond morphologies , 2003 .

[62]  E. Moroz,et al.  STUDY OF ULTRADISPERSED DIAMOND POWDERS OBTAINED USING EXPLOSION ENERGY , 1991 .

[63]  T. Enoki,et al.  17 – Unconventional Magnetic Properties of Nanographite , 2006 .

[64]  D. Gruen,et al.  Synthesis, properties, and applications of ultrananocrystalline diamond , 2005 .

[65]  J. D. Johnson,et al.  Diamonds in detonation soot , 1988, Nature.

[66]  V. Kuznetsov,et al.  Synthesis and Properties of Nanostructured Carbon Materials: Nanodiamond, Onion-Like Carbon and Carbon Nanotubes , 2003 .

[67]  E. Kohn,et al.  Electronic Properties and Applications of Ultrananocrystalline Diamond , 2005 .

[68]  A. M. Rao,et al.  Heat-treatment effect on the nanosized graphite π-electron system during diamond to graphite conversion , 2000 .

[69]  Kai Xu,et al.  FTIR study of ultradispersed diamond powder synthesized by explosive detonation , 1995 .

[70]  E. Ōsawa Disintegration and Purification of Crude Aggregates of Detonation Nanodiamond , 2005 .

[71]  Electron emission properties of detonation nanodiamonds , 2004 .

[72]  A. Vul,et al.  MAGNETIC DEFECTS IN PRISTINE AND HYDROGENTERMINATED NANODIAMONDS , 2006 .

[73]  W. Kang,et al.  Applying CVD Diamond and Particulate Nanodiamond , 2005 .

[74]  Yury Gogotsi,et al.  Effect of sintering on structure of nanodiamond , 2005 .

[75]  S. A. Grudinkin,et al.  Growth of diamond films on crystalline silicon by hot-filament chemical vapor deposition , 2002 .

[76]  Zhang,et al.  Negative-electron-affinity effects on the diamond (100) surface. , 1994, Physical review. B, Condensed matter.

[77]  V. Dolmatov Synthesis and Post-Synthesis Treatment of Detonation Nanodiamonds , 2006 .