Present and future thermoelectric materials toward wearable energy harvesting

Abstract Thermoelectric (TE) devices emerge as an important renewable energy source with great potential to take advancement of the widely-abundant and normally-wasted thermal energy, which are expected to provide sufficient energy for long-term operations, avoiding the inconvenient battery replacement or frequent recharging. Recently, the wearable energy conversion devices to provide electricity for portable electronics have attracted increasing attention with the available of novel low-power portable equipment. This paper reviews recent developments of TE materials toward flexible or wearable energy harvesting based on film- and fiber-based materials. The potential of film- and fiber-based TE materials have been discussed for the next generation of sustainable energy supply toward wearable energy harvesting owing to their low-weight, high flexibility, and reliability. Remaining challenges and perspectives of flexible devices are also examined to suggest for practical application toward wearable energy harvesting.

[1]  Elena Nicolescu Veety,et al.  Wearable thermoelectric generators for human body heat harvesting , 2016 .

[2]  Muhammad M. Hussain,et al.  Strain‐Induced Rolled Thin Films for Lightweight Tubular Thermoelectric Generators , 2018 .

[3]  Yue Wu,et al.  Inkjet Printing of Single‐Crystalline Bi2Te3 Thermoelectric Nanowire Networks , 2017 .

[4]  Hanfu Wang,et al.  A thin film thermoelectric device fabricated by a self-aligned shadow mask method , 2017 .

[5]  Sam F. Y. Li,et al.  Solution layer-by-layer uniform thin film dip coating of nickel hydroxide and metal incorporated nickel hydroxide and its improved electrochromic performance , 2018, Solar Energy Materials and Solar Cells.

[6]  B. Cho,et al.  Enhancement of reproducibility and reliability in a high-performance flexible thermoelectric generator using screen-printed materials , 2018 .

[7]  Jingkun Xu,et al.  Functionalized Poly(3,4-ethylenedioxy bithiophene) Films for Tuning Electrochromic and Thermoelectric Properties. , 2017, The journal of physical chemistry. B.

[8]  Zhenjie Sun,et al.  Two-dimensional black phosphorus: A new star in energy applications and the barrier to stability , 2019, Applied Materials Today.

[9]  Y. Fu,et al.  Transparent flexible thermoelectric material based on non-toxic earth-abundant p-type copper iodide thin film , 2017, Nature Communications.

[10]  Jong Soo Ko,et al.  Flexible thermoelectric generator with polydimethyl siloxane in thermoelectric material and substrate , 2016 .

[11]  Yongan Huang,et al.  Energy Harvesters for Wearable and Stretchable Electronics: From Flexibility to Stretchability , 2016, Advanced materials.

[12]  M. Dresselhaus,et al.  High-Thermoelectric Performance of Nanostructured Bismuth Antimony Telluride Bulk Alloys , 2008, Science.

[13]  D. R. Strachan,et al.  Increased power factors of organic–inorganic nanocomposite thermoelectric materials and the role of energy filtering , 2017 .

[14]  N. Toshima Recent progress of organic and hybrid thermoelectric materials , 2017 .

[15]  Jungdae Kim,et al.  A Review of SnSe: Growth and Thermoelectric Properties , 2018 .

[16]  Fei Hu,et al.  Highly Conductive Hydrogel Polymer Fibers toward Promising Wearable Thermoelectric Energy Harvesting. , 2018, ACS applied materials & interfaces.

[17]  V. Nyamori,et al.  Graphene for Thermoelectric Applications: Prospects and Challenges , 2018 .

[18]  K. Zhang,et al.  Engineered doping of organic semiconductors for enhanced thermoelectric efficiency. , 2013, Nature materials.

[19]  Thermoelectric properties of single-wall carbon nanotube films: Effects of diameter and wet environment , 2016 .

[20]  Yong Du,et al.  Flexible thermoelectric materials and devices , 2018, Applied Materials Today.

[21]  Jingkun Xu,et al.  Poly(3,4-ethylenedioxythiophene) as promising organic thermoelectric materials: A mini-review , 2012 .

[22]  Nelson E. Coates,et al.  Thermoelectric power factor optimization in PEDOT:PSS tellurium nanowire hybrid composites. , 2013, Physical chemistry chemical physics : PCCP.

[23]  Gangjian Tan,et al.  Rationally Designing High-Performance Bulk Thermoelectric Materials. , 2016, Chemical reviews.

[24]  H. Hng,et al.  Mechanically Durable and Flexible Thermoelectric Films from PEDOT:PSS/PVA/Bi0.5Sb1.5Te3 Nanocomposites , 2017 .

[25]  M. Kanatzidis,et al.  Broad temperature plateau for thermoelectric figure of merit ZT>2 in phase-separated PbTe0.7S0.3 , 2014, Nature Communications.

[26]  Zhong Lin Wang,et al.  Toward Wearable Self-Charging Power Systems: The Integration of Energy-Harvesting and Storage Devices. , 2018, Small.

[27]  Matthew S. Dargusch,et al.  High Performance Thermoelectric Materials: Progress and Their Applications , 2018 .

[28]  Weiguo Hu,et al.  Wearable Self‐Charging Power Textile Based on Flexible Yarn Supercapacitors and Fabric Nanogenerators , 2016, Advanced materials.

[29]  Jingkun Xu,et al.  Effective treatment methods on PEDOT:PSS to enhance its thermoelectric performance , 2017 .

[30]  Heng Wang,et al.  Convergence of electronic bands for high performance bulk thermoelectrics , 2011, Nature.

[31]  Kevin C. See,et al.  Water-processable polymer-nanocrystal hybrids for thermoelectrics. , 2010, Nano letters.

[32]  Eun Seon Cho,et al.  Bottom-up design of de novo thermoelectric hybrid materials using chalcogenide resurfacing , 2017 .

[33]  Song Jin,et al.  Enhancement of the thermoelectric properties in nanoscale and nanostructured materials , 2011 .

[34]  Kenji Koga,et al.  Flexible n-type thermoelectric materials by organic intercalation of layered transition metal dichalcogenide TiS2. , 2015, Nature materials.

[35]  Ling Chen,et al.  High Thermoelectric Performance of In 4 Se 3 ‐ Based Materials and the In fl uencing Factors Published as part of the Accounts of Chemical Research special issue “ Advancing Chemistry through Intermetallic Compounds ” , 2018 .

[36]  Jingkun Xu,et al.  Effects of solvents on thermoelectric performance of PANi/PEDOT/PSS composite films , 2017, Journal of Polymer Research.

[37]  Jingkun Xu,et al.  Fabrication of freestanding tellurium nanofilm and its thermoelectric performance , 2018 .

[38]  Li Shi,et al.  Two-Dimensional Phonon Transport in Supported Graphene , 2010, Science.

[39]  Investigating enhanced thermoelectric performance of graphene-based nano-structures. , 2018, Nanoscale.

[40]  C. Soukoulis,et al.  Chemical intuition for high thermoelectric performance in monolayer black phosphorus, α-arsenene and aW-antimonene , 2018 .

[41]  S. Cho,et al.  Engineered nanocarbon mixing for enhancing the thermoelectric properties of a telluride-PEDOT:PSS nanocomposite , 2017 .

[42]  Lu Yin,et al.  High-Performance Screen-Printed Thermoelectric Films on Fabrics , 2017, Scientific Reports.

[43]  H. Hng,et al.  Fabrication of flexible thermoelectric thin film devices by inkjet printing. , 2014, Small.

[44]  G. Shi,et al.  Ultrahigh‐Conductivity Polymer Hydrogels with Arbitrary Structures , 2017, Advanced materials.

[45]  M. R. A. Bhuiyan,et al.  A review on bismuth telluride (Bi2Te3) nanostructure for thermoelectric applications , 2018 .

[46]  Hua Zhang,et al.  The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets. , 2013, Nature chemistry.

[47]  Jinlian Hu,et al.  A novel design for a wearable thermoelectric generator based on 3D fabric structure , 2017 .

[48]  Xiangfan Xu,et al.  Phonon thermal conduction in novel 2D materials , 2016, Journal of physics. Condensed matter : an Institute of Physics journal.

[49]  M. Kanatzidis,et al.  High-performance bulk thermoelectrics with all-scale hierarchical architectures , 2012, Nature.

[50]  Xiaodong Wang,et al.  Simple Layer-by-Layer Assembly Method for Simultaneously Enhanced Electrical Conductivity and Thermopower of PEDOT:PSS/ce-MoS2 Heterostructure Films , 2018, ACS Applied Energy Materials.

[51]  Jingkun Xu,et al.  The evolution of organic thermoelectric material based on conducting poly(3,4-ethylenedioxythiophene) , 2017 .

[52]  Santanu Chattopadhyay,et al.  Recent advances in CNT/graphene based thermoelectric polymer nanocomposite: A proficient move towards waste energy harvesting , 2016 .

[53]  J. Razal,et al.  One‐Step Wet‐Spinning Process of Poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) Fibers and the Origin of Higher Electrical Conductivity , 2011 .

[54]  Gang Zhang,et al.  Thermoelectric properties of two-dimensional transition metal dichalcogenides , 2017 .

[55]  Quan-hong Yang,et al.  Opening Two‐Dimensional Materials for Energy Conversion and Storage: A Concept , 2017 .

[56]  S. LeBlanc,et al.  Printed thermoelectric materials and devices: Fabrication techniques, advantages, and challenges , 2017 .

[57]  Yong Du,et al.  Flexible Thermoelectric Composite Films of Polypyrrole Nanotubes Coated Paper , 2017 .

[58]  Chen Ming,et al.  Realizing a thermoelectric conversion efficiency of 12% in bismuth telluride/skutterudite segmented modules through full-parameter optimization and energy-loss minimized integration , 2017 .

[59]  Yingjun Liu,et al.  Chemically doped macroscopic graphene fibers with significantly enhanced thermoelectric properties , 2018, Nano Research.

[60]  Renaud Demadrille,et al.  Structure and Dopant Engineering in PEDOT Thin Films: Practical Tools for a Dramatic Conductivity Enhancement , 2016 .

[61]  D. Carroll,et al.  Nanowires as Building Blocks to Fabricate Flexible Thermoelectric Fabric: The Case of Copper Telluride Nanowires. , 2015, ACS applied materials & interfaces.

[62]  Choongho Yu,et al.  Air-stable fabric thermoelectric modules made of N- and P-type carbon nanotubes , 2012 .

[63]  Xiaoping Liao,et al.  Review of Micro Thermoelectric Generator , 2018, Journal of Microelectromechanical Systems.

[64]  Jin Young Oh,et al.  Chemically exfoliated transition metal dichalcogenide nanosheet-based wearable thermoelectric generators , 2016 .

[65]  Weifang Yang,et al.  Fabrications of Polyaniline Films by Pulse Electrodeposition in Acidic Solutions with Different Anions and Their Thermoelectric Performances , 2017, Journal of Electronic Materials.

[66]  Xiaodong Wang,et al.  Highly enhanced thermoelectric performance of WS2 nanosheets upon embedding PEDOT:PSS , 2017 .

[67]  Yue Chen,et al.  3D charge and 2D phonon transports leading to high out-of-plane ZT in n-type SnSe crystals , 2018, Science.

[68]  Kevin C. See,et al.  Effect of Interfacial Properties on Polymer–Nanocrystal Thermoelectric Transport , 2013, Advanced materials.

[69]  Jingkun Xu,et al.  Fabrication of flexible SWCNTs-Te composite films for improving thermoelectric properties , 2017 .

[70]  Jingkun Xu,et al.  A simple thermoelectric device based on inorganic/organic composite thin film for energy harvesting , 2017 .

[71]  Zhenan Bao,et al.  Mechanically tunable conductive interpenetrating network hydrogels that mimic the elastic moduli of biological tissue , 2018, Nature Communications.

[72]  W. Xu,et al.  Organic Thermoelectric Materials: Emerging Green Energy Materials Converting Heat to Electricity Directly and Efficiently , 2014, Advanced materials.

[73]  Ke Li,et al.  Free-Standing Conducting Polymer Films for High-Performance Energy Devices. , 2016, Angewandte Chemie.

[74]  Y. Sun,et al.  Enhanced thermoelectric performance of phosphorene by strain-induced band convergence , 2014, 1406.5272.

[75]  E. Koukharenko,et al.  Towards thermoelectric nanostructured energy harvester for wearable applications , 2018, Journal of Materials Science: Materials in Electronics.

[76]  G. Liang,et al.  Theoretical study of thermoelectric properties of few-layer MoS2 and WSe2. , 2014, Physical chemistry chemical physics : PCCP.

[77]  Dimuthu Wijethunge,et al.  Simplified human thermoregulatory model for designing wearable thermoelectric devices , 2018 .

[78]  Takashi Taniguchi,et al.  Unconventional superconductivity in magic-angle graphene superlattices , 2018, Nature.

[79]  T. Fujigaya,et al.  Development of n-type cobaltocene-encapsulated carbon nanotubes with remarkable thermoelectric property , 2015, Scientific Reports.

[80]  Max Shtein,et al.  Fiber-based flexible thermoelectric power generator , 2008 .

[81]  B. Cho,et al.  Post ionized defect engineering of the screen-printed Bi2Te2.7Se0.3 thick film for high performance flexible thermoelectric generator , 2017 .

[82]  N. Ravindra,et al.  Thermoelectric Properties of Pristine and Doped Graphene Nanosheets and Graphene Nanoribbons: Part I , 2016 .

[83]  Bill J. Van Heyst,et al.  A review of the state of the science on wearable thermoelectric power generators (TEGs) and their existing challenges , 2017 .

[84]  Solution synthesis of telluride-based nano-barbell structures coated with PEDOT:PSS for spray-printed thermoelectric generators. , 2016, Nanoscale.

[85]  M. Yoon,et al.  Effect of Metal Doping and Vacancies on the Thermal Conductivity of Monolayer Molybdenum Diselenide. , 2018, ACS applied materials & interfaces.

[86]  Y. Cohen,et al.  Strong, Light, Multifunctional Fibers of Carbon Nanotubes with Ultrahigh Conductivity , 2013, Science.

[87]  High thermoelectric performance can be achieved in black phosphorus , 2015, 1508.06834.

[88]  Kwang-Suk Jang,et al.  Enhancement of Thermoelectric Properties of PEDOT:PSS and Tellurium-PEDOT:PSS Hybrid Composites by Simple Chemical Treatment , 2015, Scientific Reports.

[89]  Xiaodong Wang,et al.  An effective dual-solvent treatment for improving the thermoelectric property of PEDOT:PSS with white graphene , 2017, Journal of Materials Science.

[90]  Takeshi Saito,et al.  From materials to device design of a thermoelectric fabric for wearable energy harvesters , 2017 .

[91]  Lianzhou Wang,et al.  Recent Progress on Integrated Energy Conversion and Storage Systems , 2017, Advanced science.

[92]  Xiaodong Wang,et al.  Solution-processed two-dimensional layered heterostructure thin-film with optimized thermoelectric performance. , 2017, Physical chemistry chemical physics : PCCP.

[93]  Wei Huang,et al.  2D Black Phosphorus for Energy Storage and Thermoelectric Applications. , 2017, Small.

[94]  Deyber Arley Vargas Medina,et al.  Hyperporous carbon-coated 3D printed devices , 2019, Applied Materials Today.

[95]  Venkata Vasiraju,et al.  Nanowire-based thermoelectrics , 2017, Nanotechnology.

[96]  M. Dresselhaus,et al.  Thermoelectric figure of merit of a one-dimensional conductor. , 1993, Physical review. B, Condensed matter.

[97]  J. Shapter,et al.  Advances in carbon nanotube n-type doping: Methods, analysis and applications , 2018 .

[98]  M. Dresselhaus,et al.  Ab initio study of electron-phonon interaction in phosphorene , 2014, 1410.4242.

[99]  Yue Wu,et al.  Flexible nanocrystal-coated glass fibers for high-performance thermoelectric energy harvesting. , 2012, Nano letters.

[100]  Anvar A. Zakhidov,et al.  Woven‐Yarn Thermoelectric Textiles , 2016, Advanced materials.

[101]  C. Adessi,et al.  First Principle Investigation on Thermoelectric Properties of Transition Metal Dichalcogenides: Beyond the Rigid Band Model , 2017 .

[102]  M. Dong,et al.  Modulation the electronic property of 2D monolayer MoS2 by amino acid , 2019, Applied Materials Today.

[103]  L. Dai,et al.  Electronic and Optoelectronic Applications Based on 2D Novel Anisotropic Transition Metal Dichalcogenides , 2017, Advanced science.

[104]  Zhou Li,et al.  Energy Harvesting from the Animal/Human Body for Self-Powered Electronics. , 2017, Annual review of biomedical engineering.

[105]  Shufang Wang,et al.  Multinary diamond-like chalcogenides for promising thermoelectric application* , 2018 .

[106]  Baoling Huang,et al.  Ab initio and molecular dynamics predictions for electron and phonon transport in bismuth telluride , 2008 .

[107]  Jingkun Xu,et al.  Optimizing the thermoelectric properties of PEDOT:PSS films by combining organic co-solvents with inorganic base , 2015, Journal of Materials Science: Materials in Electronics.

[108]  V. Perebeinos,et al.  Thermal Light Emission from Monolayer MoS2 , 2017, Advanced materials.

[109]  Lee, Changhoon,et al.  Control of valley degeneracy in Mo S2 by layer thickness and electric field and its effect on thermoelectric properties , 2016 .

[110]  Daoben Zhu,et al.  Recent advances in organic polymer thermoelectric composites , 2017 .

[111]  Kaufui Wong,et al.  A Review of Additive Manufacturing , 2012 .

[112]  Jingkun Xu,et al.  Highly electrical and thermoelectric properties of a PEDOT:PSS thin-film via direct dilution–filtration , 2015 .

[113]  G. J. Snyder,et al.  Dense dislocation arrays embedded in grain boundaries for high-performance bulk thermoelectrics , 2015, Science.

[114]  J. M. Baik,et al.  Wearable solar thermoelectric generator driven by unprecedentedly high temperature difference , 2017 .

[115]  X. Duan,et al.  A Solution Processable High‐Performance Thermoelectric Copper Selenide Thin Film , 2017, Advanced materials.

[116]  K. Goodson,et al.  Modulation of thermal and thermoelectric transport in individual carbon nanotubes by fullerene encapsulation. , 2017, Nature materials.

[117]  Ge Zhang,et al.  An efficient PEDOT-coated textile for wearable thermoelectric generators and strain sensors , 2019, Journal of Materials Chemistry C.

[118]  A. Maignan,et al.  Transport and thermoelectric properties in Copper intercalated TiS2 chalcogenide , 2011 .

[119]  S. Cho,et al.  High-performance flexible thermoelectric generator by control of electronic structure of directly spun carbon nanotube webs with various molecular dopants , 2017 .

[120]  J. Grunlan,et al.  Carbon‐Nanotube‐Based Thermoelectric Materials and Devices , 2018, Advanced materials.

[121]  Yeonsu Jung,et al.  Flexible and Robust Thermoelectric Generators Based on All-Carbon Nanotube Yarn without Metal Electrodes. , 2017, ACS nano.

[122]  Zhitao Zhang,et al.  Conjugated Polymers for Flexible Energy Harvesting and Storage , 2018, Advanced materials.

[123]  Tao Hua,et al.  Fiber‐Based Thermoelectric Generators: Materials, Device Structures, Fabrication, Characterization, and Applications , 2018 .

[124]  Shu-Shen Lyu,et al.  WSe2 nanoribbons: new high-performance thermoelectric materials. , 2016, Physical chemistry chemical physics : PCCP.

[125]  R. Venkatasubramanian,et al.  Thin-film thermoelectric devices with high room-temperature figures of merit , 2001, Nature.

[126]  Ashutosh Kumar Singh,et al.  Conductive polymers for thermoelectric power generation , 2018 .

[127]  Baoyang Lu,et al.  Thermoelectric Performance of Poly(3,4-ethylenedioxythiophene): Poly(styrenesulfonate) , 2008 .

[128]  Baoyang Lu,et al.  Electrochemical Treatment for Effectively Tuning Thermoelectric Properties of Free-Standing Poly(3-methylthiophene) Films. , 2016, Chemphyschem : a European journal of chemical physics and physical chemistry.

[129]  Byung Jin Cho,et al.  Structural design of a flexible thermoelectric power generator for wearable applications , 2018 .

[130]  Jingkun Xu,et al.  High performance of PEDOT:PSS/SiC-NWs hybrid thermoelectric thin film for energy harvesting , 2018 .

[131]  Naokatsu Yamamoto,et al.  Electrical power generation from a knitted wire panel using the thermoelectric effect , 2002 .

[132]  S. Sarma,et al.  Electronic transport in two-dimensional graphene , 2010, 1003.4731.

[133]  Xu Du,et al.  Approaching ballistic transport in suspended graphene. , 2008, Nature nanotechnology.

[134]  W. Su,et al.  Strategies for optimizing the thermoelectricity of PbTe alloys , 2018 .

[135]  G. J. Snyder,et al.  Impact of Ni content on the thermoelectric properties of half-Heusler TiNiSn , 2018 .

[136]  Jingkun Xu,et al.  High-performance hybrid organic thermoelectric SWNTs/PEDOT:PSS thin-films for energy harvesting , 2017 .

[137]  Nan Zhang,et al.  High-performance and compact-designed flexible thermoelectric modules enabled by a reticulate carbon nanotube architecture , 2017, Nature Communications.

[138]  Zhifeng Ren,et al.  Flexible Electronics: Stretchable Electrodes and Their Future , 2018, Advanced Functional Materials.

[139]  Jun Zou,et al.  A review on heat and mechanical energy harvesting from human – Principles, prototypes and perspectives , 2018 .

[140]  SeongHwan Cho,et al.  Self-Powered Wearable Electrocardiography Using a Wearable Thermoelectric Power Generator , 2018 .

[141]  Jingkun Xu,et al.  Effects of additives and post‐treatment on the thermoelectric performance of vapor‐phase polymerized PEDOT films , 2017 .

[142]  Lei Zhai,et al.  Two-dimensional transition metal dichalcogenide hybrid materials for energy applications , 2018 .

[143]  Jingkun Xu,et al.  Liquid Exfoliated Graphene as Dopant for Improving the Thermoelectric Power Factor of Conductive PEDOT:PSS Nanofilm with Hydrazine Treatment. , 2015, ACS applied materials & interfaces.

[144]  H. Hng,et al.  Designing hybrid architectures for advanced thermoelectric materials , 2017 .

[145]  Hyang Hee Choi,et al.  All organic-based solar cell and thermoelectric generator hybrid device system using highly conductive PEDOT:PSS film as organic thermoelectric generator , 2016 .

[146]  Trisha L. Andrew,et al.  Towards seamlessly-integrated textile electronics: methods to coat fabrics and fibers with conducting polymers for electronic applications. , 2017, Chemical communications.