IDOAS: A new monitoring technique to study the 2D distribution of volcanic gas emissions

Imaging Differential Optical Absorption Spectroscopy (IDOAS) is an optical remote-sensing method using scattered sunlight as light source. It combines a “pushbroom” imaging spectrometer with the DOAS technique and thus allows imaging two-dimensional trace gas distributions, e.g., in volcanic plumes. The highly sensitive and specific detection of many trace gases simultaneously (specific molecules, not just elements, e.g. SO2, BrO, NO2, O3, HCHO, etc.) is possible, and the temporal and spatial variation of these gases can be measured. The IDOAS system presented here enables the taking of two-dimensional images of trace gas distributions in a volcanic plume with a spatial resolution of 100 pixels horizontally × 64 pixels vertically, each with a field of view of 0.087° in horizontal and 0.208° in vertical directions. Therefore, IDOAS provides useful information about the chemical composition and chemical variability in a volcanic plume and allows studying plume dispersal and chemical transformations. The technique was applied to map the SO2 distribution in the plume of Mt. Etna volcano for the first time in October 2003.

[1]  M. T. Coffey,et al.  Observations of the impact of volcanic activity on stratospheric chemistry , 1996 .

[2]  Tamsin A. Mather,et al.  Walking traverse and scanning DOAS measurements of volcanic gas emission rates , 2002 .

[3]  Toshiya Mori,et al.  Infrared spectral radiometer: A new tool for remote measurement of SO2 of volcanic gas , 1993 .

[4]  C. Oppenheimer,et al.  Diurnal changes in volcanic plume chemistry observed by lunar and solar occultation spectroscopy , 2001 .

[5]  J. Grainger,et al.  Anomalous Fraunhofer Line Profiles , 1962, Nature.

[6]  Dietrich Althausen,et al.  Retrieval of Aerosol Profiles using Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) , 2003 .

[7]  M. McCormick,et al.  Atmospheric effects of the Mt Pinatubo eruption , 1995, Nature.

[8]  C. Federico,et al.  Anomalous magmatic degassing prior to the 5th April 2003 paroxysm on Stromboli , 2004 .

[9]  A. Vandaele,et al.  SO2 Absorption Cross-section Measurement in the UV using a Fourier Transform Spectrometer , 1994 .

[10]  C. Oppenheimer,et al.  Remote sensing of CO2 and H2O emission rates from Masaya volcano, Nicaragua , 2000 .

[11]  M. Sigrist Air monitoring by spectroscopic techniques , 1994 .

[12]  G. Rottman,et al.  How active was solar cycle 22 , 1993 .

[13]  A. McGonigle,et al.  A miniaturised ultraviolet spectrometer for remote sensing of SO2 fluxes: a new tool for volcano surveillance , 2003 .

[14]  U. Platt,et al.  Ground-based imaging differential optical absorption spectroscopy of atmospheric gases. , 2004, Applied optics.

[15]  M. Millán,et al.  Study of the Barringer refractor plate correlation spectrometers as a remote sensing instrument , 1970 .

[16]  Clive Oppenheimer,et al.  Remote measurements of volcanic gas compositions by solar occultation spectroscopy , 1998, Nature.

[17]  R. Turco,et al.  Self-limiting physical and chemical effects in volcanic eruption clouds , 1989 .

[18]  U. Platt,et al.  Detection of bromine monoxide in a volcanic plume , 2003, Nature.

[19]  C. Oppenheimer,et al.  SO2∶HCl ratios in the plumes from Mt. Etna and Vulcano determined by Fourier Transform Spectroscopy , 1995 .

[20]  Ulrich Platt,et al.  Differential optical absorption spectroscopy (DOAS) , 1994 .

[21]  H. Bovensmann,et al.  Balloon-borne limb profiling of UV/vis skylight radiances, O 3 , NO 2 , and BrO: technical set-up and validation of the method , 2004 .

[22]  A. Robock Volcanic eruptions and climate , 2000 .