High sensitivity and good selectivity of ultralong MoO3 nanobelts for trimethylamine gas

Abstract In the present work, ultralong MoO3 nanobelts are prepared by a facile hydrothermal method, which are flexible with an average length of 200 μm and width of 200–400 nm. Gas sensor based on ultralong MoO3 nanobelts shows a remarkable gas sensing properties towards trimethylamine (TMA) from 100 °C to 380 °C with a humidity level of about 55%. The optimum operating temperature is 240 °C with a response of 582 to 50 ppm TMA in static mode. The selectivity test among various reducing gases shows that the sensor has a quite good response towards TMA if compared with others gases, such as ethanol, ammonia, toluene, methanol and acetone. The probable gas sensing mechanism of the prepared MoO3 nanobelts is discussed as well. The results indicate that this kind of sensor has a promising application in TMA detection.

[1]  Y. Mortazavi,et al.  Highly sensitive and selective ethanol sensor based on Sm2O3-loaded flower-like ZnO nanostructure , 2014 .

[2]  Wen Chen,et al.  Enhancement of ethanol gas sensing response based on ordered V2O5 nanowire microyarns , 2015 .

[3]  L. Mai,et al.  Lithiated MoO3 Nanobelts with Greatly Improved Performance for Lithium Batteries , 2007 .

[4]  Sheikh A. Akbar,et al.  Gas Sensors Based on One Dimensional Nanostructured Metal-Oxides: A Review , 2012, Sensors.

[5]  J. Słoczyński Kinetics and Mechanism of Molybdenum (VI) Oxide Reduction , 1995 .

[6]  Changwen Hu,et al.  Thermal oxidation synthesis hollow MoO3 microspheres and their applications in lithium storage and gas-sensing , 2013 .

[7]  Yun Chan Kang,et al.  Ultraselective and ultrasensitive detection of trimethylamine using MoO3 nanoplates prepared by ultrasonic spray pyrolysis , 2014 .

[8]  Xuejun Zheng,et al.  Fabrication of flower-like ZnO nanosheet and nanorod-assembled hierarchical structures and their enhanced performance in gas sensors , 2014 .

[9]  P. Gouma,et al.  Comparison of sol–gel and ion beam deposited MoO3 thin film gas sensors for selective ammonia detection , 2003 .

[10]  Wojtek Wlodarski,et al.  Comparison of single and binary oxide MoO3, TiO2 and WO3 sol–gel gas sensors , 2002 .

[11]  P. Forzatti,et al.  Characterization and reactivity of MoO3/SiO2 catalysts in the selective catalytic oxidation of ammonia to N2 , 2000 .

[12]  M. Yin,et al.  Preparation of ZnO hollow spheres with different surface roughness and their enhanced gas sensing property , 2014 .

[13]  Chan Woong Na,et al.  Highly sensitive and selective trimethylamine sensor using one-dimensional ZnO–Cr2O3 hetero-nanostructures , 2012, Nanotechnology.

[14]  N. Bârsan,et al.  Metal oxide-based gas sensor research: How to? , 2007 .

[15]  Ying Wang,et al.  Synthesis of Crystalline/Amorphous Core/Shell MoO3 Composites through a Controlled Dehydration Route and Their Enhanced Ethanol Sensing Properties , 2014 .

[16]  A. Cabrera,et al.  In situ-Raman studies on thermally induced structural changes of porous MoO3 prepared in vapor phase under He and H2 , 2012 .

[17]  V. Pillai,et al.  Hydrogen and ethanol sensing properties of molybdenum oxide nanorods based thin films: Effect of electrode metallization and humid ambience , 2013 .

[18]  Zhihua Wang,et al.  Fine-tuning the structure of cubic indium oxide and their ethanol-sensing properties , 2014 .

[19]  Wojtek Wlodarski,et al.  Gas sensing properties of thermally evaporated lamellar MoO3 , 2010 .

[20]  F. Iacomi,et al.  Selectivity between methanol and ethanol gas of La–Pb–Fe–O perovskite synthesized by novel method , 2013 .

[21]  Jing Sun,et al.  Single-crystalline MoO3 nanoplates: topochemical synthesis and enhanced ethanol-sensing performance , 2011 .

[22]  Wojtek Wlodarski,et al.  Two dimensional α-MoO3 nanoflakes obtained using solvent-assisted grinding and sonication method: Application for H2 gas sensing , 2014 .

[23]  Zhifu Liu,et al.  O2 and CO sensing of Ga2O3 multiple nanowire gas sensors , 2008 .

[24]  Ezra L. Clark,et al.  MoO(3-x) nanowire arrays as stable and high-capacity anodes for lithium ion batteries. , 2012, Nano letters.

[25]  Jie Yu,et al.  Hydrothermal synthesis and gas sensing properties of single-crystalline ultralong ZnO nanowires , 2010 .

[26]  Bingqiang Cao,et al.  Highly sensitive and selective triethylamine-sensing properties of nanosheets directly grown on ceramic tube by forming NiO/ZnO PN heterojunction , 2014 .

[27]  Kang Wang,et al.  Synthesis, characterization and gas sensing properties of flowerlike In2O3 composed of microrods , 2010 .

[28]  B. Jeyaprakash,et al.  Nanostructured α-MoO3 thin film as a highly selective TMA sensor. , 2014, Biosensors & bioelectronics.

[29]  R. P. Tandon,et al.  MoO3-based sensor for NO, NO2 and CH4 detection , 2006 .

[30]  Yun Chan Kang,et al.  Highly selective and sensitive detection of trimethylamine using WO3 hollow spheres prepared by ultrasonic spray pyrolysis , 2013 .

[31]  L. Mai,et al.  Synthesis and gas sensing properties of Fe2O3 nanoparticles activated V2O5 nanotubes , 2010 .

[32]  Peng Song,et al.  Morphology-controllable synthesis, characterization and sensing properties of single-crystal molybdenum trioxide , 2013 .

[33]  X. Lou,et al.  Ultralong α-MoO3 Nanobelts: Synthesis and Effect of Binder Choice on Their Lithium Storage Properties , 2012 .

[34]  Yoshitake Nishi,et al.  Trimethylamine biosensor with flavin-containing monooxygenase type 3 (FMO3) for fish-freshness analysis , 2004 .

[35]  Zheng Lou,et al.  Branch-like hierarchical heterostructure (α-Fe2O3/TiO2): a novel sensing material for trimethylamine gas sensor. , 2013, ACS applied materials & interfaces.

[36]  C. Liu,et al.  Ultrasonic synthesis of MoO3 nanorods and their gas sensing properties , 2012 .

[37]  L. Greenspan Humidity Fixed Points of Binary Saturated Aqueous Solutions , 1977, Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry.

[38]  Zhenan Tang,et al.  Assay of fish freshness using trimethylamine vapor probe based on a sensitive membrane on piezoelectric quartz crystal , 2002 .

[39]  Yujin Chen,et al.  Facile synthesis and enhanced H2S sensing performances of Fe-doped α-MoO3 micro-structures , 2012 .

[40]  S. Sarkar,et al.  Replica of a fishy enzyme: structure-function analogue of trimethylamine-N-oxide reductase. , 2013, Inorganic chemistry.

[41]  F. Shayeganfar,et al.  Electronic properties of self-assembled trimesic acid monolayer on graphene. , 2014, Langmuir : the ACS journal of surfaces and colloids.

[42]  Y. Qian,et al.  Hydrothermal route to single crystalline α-MoO3 nanobelts and hierarchical structures , 2005 .

[43]  A. Bettiol,et al.  Rainbow-like MoO3 Nanobelts Fashioned via AFM Micromachining , 2010 .

[44]  Shiming Liang,et al.  Trimethylamine sensing properties of sensors based on MoO3 microrods , 2010 .

[45]  Zheng Lou,et al.  Nanoparticles-assembled Co3O4 nanorods p-type nanomaterials: One-pot synthesis and toluene-sensing properties , 2014 .

[46]  Xindong Zhang,et al.  Performance improvement of inverted polymer solar cells with different top electrodes by introducing a MoO3 buffer layer , 2008 .

[47]  Jong Heun Lee,et al.  Selective trimethylamine sensors using Cr2O3- decorated SnO2 nanowires , 2014 .

[48]  Donghai Mei,et al.  Density Functional Theory Study of Acetaldehyde Hydrodeoxygenation on MoO3 , 2011 .

[49]  Wei‐De Zhang,et al.  Fabrication of SnO2–ZnO nanocomposite sensor for selective sensing of trimethylamine and the freshness of fishes , 2008 .

[50]  D. Kang,et al.  MoO3 and Cu0.33MoO3 nanorods for unprecedented UV/Visible light photocatalysis. , 2010, Chemical communications.