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Real-world networks often have power-law degrees and scale-free properties such as ultra-small distances and ultra-fast information spreading. We provide evidence of a third universal property: three-point correlations that suppress the creation of triangles and signal the presence of hierarchy. We quantify this property in terms of $\bar c(k)$, the probability that two neighbors of a degree-$k$ node are neighbors themselves. We investigate how the clustering spectrum $k\mapsto\bar c(k)$ scales with $k$ and discover a {\it universal curve} that consists of three $k$-ranges where $\bar c(k)$ remains flat, starts declining, and eventually settles on a power law $\bar c(k)\sim k^{-\alpha}$ with $\alpha$ depending on the power law of the degree distribution. We test these results against ten contemporary real-world networks and explain analytically why the universal curve properties only reveal themselves in large networks.