Growth and device processing of hexagonal boron nitride epilayers for thermal neutron and deep ultraviolet detectors

Solid-state neutron detectors with high performance are highly sought after for the detection of fissile materials. However, direct-conversion neutron detectors based on semiconductors with a measureable efficiency have not been realized. We report here the first successful demonstration of a direct-conversion semiconductor neutron detector with an overall detection efficiency for thermal neutrons of 4% and a charge collection efficiency as high as 83%. The detector is based on a 2.7 μm thick 10B-enriched hexagonal boron nitride (h-BN) epitaxial layer. The results represent a significant step towards the realization of practical neutron detectors based on h-BN epilayers. Neutron detectors based on h-BN are expected to possess all the advantages of semiconductor devices including wafer-scale processing, compact size, light weight, and ability to integrate with other functional devices.

[1]  Jing Li,et al.  Hexagonal boron nitride thin film thermal neutron detectors with high energy resolution of the reaction products , 2015 .

[2]  R. Dupuis,et al.  Modulated precursor flow epitaxial growth of AlN layers on native AlN substrates by metal-organic chemical vapor deposition , 2008 .

[3]  Huge excitonic effects in layered hexagonal boron nitride. , 2005, Physical review letters.

[4]  Yaron Danon,et al.  Self-powered micro-structured solid state neutron detector with very low leakage current and high efficiency , 2012 .

[5]  Takashi Taniguchi,et al.  Far-ultraviolet plane-emission handheld device based on hexagonal boron nitride , 2009 .

[6]  Josef Uher,et al.  Efficiency of composite boron nitride neutron detectors in comparison with helium-3 detectors , 2007 .

[7]  O. Osberghaus,et al.  ISOTOPE ABUNDANCES OF BORON A MASS-SPECTROMETRIC INVESTIGATION OF PRODUCTS OBTAINED FROM BF$sub 3$ AND BCl$sub 3$ THROUGH BOMBARDMENT WITH ELECTRONS , 1950 .

[8]  Hongxing Jiang,et al.  Two-dimensional excitons in three-dimensional hexagonal boron nitride , 2013 .

[9]  Rajendra Dahal,et al.  Epitaxial growth and demonstration of hexagonal BN/AlGaN p-n junctions for deep ultraviolet photonics , 2012 .

[10]  R C Martin,et al.  Production, distribution and applications of californium-252 neutron sources. , 1999, Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine.

[11]  Justin Clinton,et al.  Optimization and Characterization of a Novel Self Powered Solid State Neutron Detector , 2011 .

[12]  Jing Li,et al.  Dry etching techniques for active devices based on hexagonal boron nitride epilayers , 2013 .

[13]  Takashi Taniguchi,et al.  Direct-bandgap properties and evidence for ultraviolet lasing of hexagonal boron nitride single crystal , 2004, Nature materials.

[14]  Rajendra Dahal,et al.  Hexagonal boron nitride epitaxial layers as neutron detector materials , 2011 .

[15]  A. Many,et al.  High-field effects in photoconducting cadmium sulphide , 1965 .

[16]  K. Kumakura,et al.  Layered boron nitride as a release layer for mechanical transfer of GaN-based devices , 2012, Nature.

[17]  M. Asif Khan,et al.  Low pressure metalorganic chemical vapor deposition of AIN over sapphire substrates , 1992 .

[18]  P. Wallace The Band Theory of Graphite , 1947 .

[19]  G. Semenoff,et al.  Condensed-Matter Simulation of a Three-Dimensional Anomaly , 1984 .

[20]  Rajendra Dahal,et al.  Epitaxially grown semiconducting hexagonal boron nitride as a deep ultraviolet photonic material , 2011 .

[21]  Jing Li,et al.  The origin of deep-level impurity transitions in hexagonal boron nitride , 2015 .

[22]  Rebecca J. Nikolic,et al.  Comparison of CF4 and SF6 based plasmas for ECR etching of isotopically enriched 10boron films , 2009 .

[23]  Kenji Watanabe,et al.  Deep Ultraviolet Light-Emitting Hexagonal Boron Nitride Synthesized at Atmospheric Pressure , 2007, Science.

[24]  R. J. Shul,et al.  GAN : PROCESSING, DEFECTS, AND DEVICES , 1999 .

[25]  Jing Li,et al.  Fabrication and characterization of solid-state thermal neutron detectors based on hexagonal boron nitride epilayers , 2014 .

[26]  SUPARNA DUTTASINHA,et al.  Van der Waals heterostructures , 2013, Nature.

[27]  Hongxing Jiang,et al.  Hexagonal boron nitride for deep ultraviolet photonic devices , 2014 .

[28]  Yael Nemirovsky,et al.  Study of the charge collection efficiency of CdZnTe radiation detectors , 1996 .