UV gated Raman spectroscopy for standoff detection of explosives

Abstract Real-time detection and identification of explosives at a standoff distance is a major issue in efforts to develop defense against so-called improvised explosive devices (IED). It is recognized that the only method, which is potentially capable to standoff detection of minimal amounts of explosives is laser-based spectroscopy. LDS technique belongs to trace detection, namely to its micro-particles variety. It is based on commonly held belief that surface contamination was very difficult to avoid and could be exploited for standoff detection. We have applied gated Raman spectroscopy for detection of main explosive materials, both factory and homemade. We developed and tested a Raman system for the field remote detection and identification of minimal amounts of explosives on relevant surfaces at a distance of up to 30 m.

[1]  Salman Rosenwaks,et al.  The use of rovibrationally excited NO photofragments as trace nitrocompounds indicators , 2000 .

[2]  S. Asher,et al.  Raman spectroscopy of a coal liquid shows that fluorescence interference is minimized with ultraviolet excitation. , 1984, Science.

[3]  Salman Rosenwaks,et al.  NO and PO photofragments as trace analyte indicators of nitrocompounds and organophosphonates , 2000 .

[4]  R. Onguéné,et al.  BOOK OF ABSTRACTS , 2008 .

[5]  Ian R. Lewis,et al.  Raman spectroscopic studies of explosive materials: towards a fieldable explosives detector , 1995 .

[6]  P. Matousek,et al.  Resonance Raman spectroscopy of highly fluorescing lignin containing chemical pulps: Suppression of fluorescence with an optical Kerr gate , 2004 .

[7]  Andrew G. Glen,et al.  APPL , 2001 .

[8]  Andrew I. Whitehouse,et al.  Test of a stand-off laser-induced breakdown spectroscopy sensor for the detection of explosive residues on solid surfaces , 2006 .

[9]  Richard E. Whipple,et al.  Standoff Detection of High Explosive Materials at 50 Meters in Ambient Light Conditions Using a Small Raman Instrument , 2005, Applied spectroscopy.

[10]  R Lavi,et al.  Photodissociation followed by laser-induced fluorescence at atmospheric pressure and 24 degrees C: a unique scheme for remote detection of explosives. , 2001, Applied optics.

[11]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[12]  Salman Rosenwaks,et al.  Emission following laser-induced breakdown spectroscopy of organic compounds in ambient air. , 2003, Applied optics.

[13]  K. H. Fung,et al.  Stand-off Detection of Chemicals by UV Raman Spectroscopy , 2000 .