A Study on the Classification of a Mirror Entry in the European List of Waste: Incineration Bottom Ash from Municipal Solid Waste

In the European Union (EU), waste is classified according to the List of Waste (LoW) and relying on the assessment of 15 hazardous properties (HPs). Incineration bottom ash (IBA) from municipal solid waste is a mirror entry in the LoW, which leads to extremely different management options within the EU. IBA has shown potential for different applications under a circular economy perspective, contributing both to avoiding waste landfilling and the consumption of natural resources, such as sand and gravel. In this context, IBA evaluation and classification play a significant role in understanding which protection measures should be taken. This work aims to present an assessment of the 15 HPs and the consequent classification of IBA using data from the industry. Each HP is assessed based on knowledge of waste, chemical composition considering concentration limits for hazardous substances, and/or through tests (chemical, physical, or biological). According to the criteria followed, 5 out of 6 samples from a Portuguese Waste-to-Energy plant were considered non-hazardous. Only one sample was classified as hazardous due to the assignment of HP 10, which resulted from Pb content (0.36%) above the concentration limit established for this property (0.3%). Nonetheless, although most hazardous entries in the LoW have this classification based on HP 14, the results obtained for the samples of this work seem to indicate IBA from this study is non-ecotoxic. Moreover, it has been suggested that IBA could possibly achieve the End-of-Waste status according to the Waste Framework Directive. For such purpose, clear criteria should be laid down to safely use the material, and testing is a crucial step.

[1]  J. M. Chimenos,et al.  Opportunities and Barriers for Valorizing Waste Incineration Bottom Ash: Iberian Countries as a Case Study , 2021, Applied Sciences.

[2]  T. Tamm,et al.  Towards Sustainable Soil Stabilization in Peatlands: Secondary Raw Materials as an Alternative , 2021, Sustainability.

[3]  M. Grosso,et al.  Metal recovery from incineration bottom ash: State-of-the-art and recent developments. , 2020, Journal of hazardous materials.

[4]  J. M. Chimenos,et al.  Legal situation and current practice of waste incineration bottom ash utilisation in Europe. , 2019, Waste management.

[5]  P. Hennebert HAZARD CLASSIFICATION OF WASTE: REVIEW OF AVAILABLE PRACTICAL METHODS AND TOOLS , 2019, Detritus.

[6]  J. M. Chimenos,et al.  Municipal solid waste incineration bottom ash as alkali-activated cement precursor depending on particle size , 2019 .

[7]  J. Fellner,et al.  Chemical composition and leachability of differently sized material fractions of municipal solid waste incineration bottom ash. , 2019, Waste management.

[8]  Hongwei Luo,et al.  Review of leaching behavior of municipal solid waste incineration (MSWI) ash. , 2019, The Science of the total environment.

[9]  J. de Brito,et al.  Environmental impacts of the use of bottom ashes from municipal solid waste incineration: A review , 2019, Resources, Conservation and Recycling.

[10]  C. Poon,et al.  Limitations and quality upgrading techniques for utilization of MSW incineration bottom ash in engineering applications – A review , 2018, Construction and Building Materials.

[11]  W. Chan,et al.  Cr, Cu, Hg and Ni release from incineration bottom ash during utilization in land reclamation - based on lab-scale batch and column leaching experiments and a modeling study. , 2018, Chemosphere.

[12]  R. Snellings,et al.  The Use of Municipal Solid Waste Incineration Ash in Various Building Materials: A Belgian Point of View , 2018, Materials.

[13]  P. Hennebert Proposal of concentration limits for determining the hazard property HP 14 for waste using ecotoxicological tests. , 2017, Waste management.

[14]  V. Chang,et al.  Review of MSWI bottom ash utilization from perspectives of collective characterization, treatment and existing application , 2017 .

[15]  R. Dhir,et al.  Use of municipal solid waste incineration bottom ashes in alkali-activated materials, ceramics and granular applications: A review. , 2017, Waste management.

[16]  C. Vandecasteele,et al.  Recycling of MSWI Bottom Ash: A Review of Chemical Barriers, Engineering Applications and Treatment Technologies , 2017 .

[17]  Ciarán J. Lynn,et al.  Municipal incinerated bottom ash (MIBA) characteristics and potential for use in road pavements , 2017 .

[18]  D. Bendz,et al.  Evaluation of frameworks for ecotoxicological hazard classification of waste. , 2016, Waste management.

[19]  Yabo Wang,et al.  Conversion of municipal solid waste incineration bottom ash to sorbent material for pollutants removal from water , 2016 .

[20]  B. Steenari,et al.  Leaching optimization of municipal solid waste incineration ash for resource recovery: A case study of Cu, Zn, Pb and Cd. , 2016, Waste management.

[21]  E Toraldo,et al.  A road pavement full-scale test track containing stabilized bottom ashes , 2015, Environmental technology.

[22]  Aimin Li,et al.  Development of a sintering process for recycling oil shale fly ash and municipal solid waste incineration bottom ash into glass ceramic composite. , 2015, Waste management.

[23]  Mikko Hupa,et al.  Thermal treatment of solid residues from WtE units: a review. , 2015, Waste management.

[24]  H. A. van der Sloot,et al.  Hazard property classification of waste according to the recent propositions of the EC using different methods. , 2014, Waste management.

[25]  Pascal Pandard,et al.  Proposal for a “Harmonized” strategy for the assessment of the HP 14 property , 2013, Integrated environmental assessment and management.

[26]  Ivano Vassura,et al.  The recycling of MSWI bottom ash in silicate based ceramic , 2010 .

[27]  A. P. Bayuseno,et al.  Understanding the chemical and mineralogical properties of the inorganic portion of MSWI bottom ash. , 2010, Waste management.

[28]  G. Mckay,et al.  Use of incineration MSW Ash: A Review , 2010 .

[29]  J. M. Chimenos,et al.  Combined use of MSWI bottom ash and fly ash as aggregate in concrete formulation: environmental and mechanical considerations. , 2009, Journal of hazardous materials.

[30]  J. Römbke,et al.  Ecotoxicological characterisation of 12 incineration ashes using 6 laboratory tests. , 2009, Waste management.

[31]  Jiri Hyks,et al.  Leaching from MSWI bottom ash: evaluation of non-equilibrium in column percolation experiments. , 2009, Waste management.

[32]  B. Wilke,et al.  Ecotoxicological characterization of hazardous wastes. , 2008, Ecotoxicology and environmental safety.

[33]  L Morselli,et al.  Reuse of incinerator bottom and fly ashes to obtain glassy materials. , 2008, Journal of hazardous materials.

[34]  J. Devillers,et al.  Selecting a battery of bioassays for ecotoxicological characterization of wastes. , 2006, The Science of the total environment.

[35]  M. H. Fernandes,et al.  Development and properties of a glass made from MSWI bottom ash , 2006 .

[36]  Paolo Pozzi,et al.  Recycling industrial waste in brick manufacture. Part 1 , 2005 .

[37]  Carlton C. Wiles,et al.  Municipal Solid Waste Combustion Ash: State-of-the-Knowledge , 1996, Municipal Solid Wastes.

[38]  T. Astrup,et al.  Treatment and Reuse of Incineration Bottom Ash , 2016 .

[39]  Incinerator Bottom Ash RECOVERY OF METALS FROM WASTE INCINERATOR BOTTOM ASH , 2015 .

[40]  Ole Hjelmar,et al.  Hazard property classification of high temperature waste materials , 2013 .

[41]  M. H. Fernandes,et al.  Characterization of MSWI bottom ashes towards utilization as glass raw material. , 2008, Waste management.

[42]  C. Seguí,et al.  Characterization of bottom ash in municipal solid waste incinerators for its use in road base. , 2004, Waste management.