Spent lead-acid battery recycling in China - A review and sustainable analyses on mass flow of lead.

Lead is classified to be one of the top heavy metal pollutants in China. The corresponding environmental issues especially during the management of spent lead-acid battery have already caused significant public awareness and concern. This research gives a brief overview on the recycling situation based on an investigation of the lead industry in China and also the development of technologies for spent lead-acid batteries. The main principles and research focuses of different technologies including pyrometallurgy, hydrometallurgy and greener technologies are summarized and compared. Subsequently, the circulability of lead based on the entire life cycle analyses of lead-acid battery is calculated. By considering different recycling schemes, the recycling situation of spent lead-acid battery in China can be understood semi-quantitatively. According to this research, 30% of the primary lead production can be shut down that the lead production can still ensure consecutive life cycle operation of lead-acid battery, if proper management of the spent lead-acid battery is implemented according to current lead industry situation in China. This research provides a methodology on the view of lead circulability in the whole life cycle of a specific product and is aiming to contribute more quantitative guidelines for efficient organization of lead industry in China.

[1]  Ting Wen,et al.  Selected-control hydrothermal growths of α- and β-PbO crystals and orientated pressure-induced phase transition , 2013 .

[2]  K. Ramus,et al.  Lead/acid battery recycling and the new Isasmelt process , 1993 .

[3]  Keqiang Qiu,et al.  Recovery of lead from lead paste in spent lead acid battery by hydrometallurgical desulfurization and vacuum thermal reduction. , 2015, Waste management.

[4]  Jilt Sietsma,et al.  Toward Sustainability for Recovery of Critical Metals from Electronic Waste: The Hydrochemistry Processes , 2017 .

[5]  A. Spicer,et al.  Third-party demanufacturing as a solution for extended producer responsibility , 2004 .

[6]  Cheng Ma,et al.  Leaching of lead slag component by sodium chloride and diluted nitric acid and synthesis of ultrafine lead oxide powders , 2015 .

[7]  Yi Liu,et al.  Solvothermal synthesis of α-PbO from lead dioxide and its electrochemical performance as a positive electrode material , 2013 .

[8]  R. David Prengaman,et al.  Recovering Lead from Batteries , 1995 .

[9]  Naoko Tojo,et al.  Extended Producer Responsibility , 2013 .

[10]  Cheng Ma,et al.  Recycling lead from spent lead pastes using oxalate and sodium oxalate and preparation of novel lead oxide for lead-acid batteries , 2015 .

[11]  Wei Liu,et al.  Electrochemical property of α-PbO prepared from the spent negative powders of lead acid batteries , 2016, Journal of Solid State Electrochemistry.

[12]  Marianne Bigum,et al.  Metal recovery from high-grade WEEE: a life cycle assessment. , 2012, Journal of hazardous materials.

[13]  Chao Zhang,et al.  A new process of lead recovery from waste lead-acid batteries by electrolysis of alkaline lead oxide solution , 2012 .

[14]  Chen Su,et al.  Energy Consumption and Emission of Pollutants from Electric Bicycles , 2014 .

[15]  Yuchen Hu,et al.  Structural study of a lead (II) organic complex – a key precursor in a green recovery route for spent lead-acid battery paste , 2016 .

[16]  Wei Han,et al.  Recycling and management of waste lead-acid batteries: A mini-review , 2016, Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA.

[17]  Deepak P. Singh,et al.  Combustion synthesis of PbO from lead carboxylate precursors relevant to developing a new method for recovering components from spent lead–acid batteries , 2012 .

[18]  Yongming Chen,et al.  Reductive smelting of spent lead–acid battery colloid sludge in a molten Na2CO3 salt , 2015, International Journal of Minerals, Metallurgy, and Materials.

[19]  Denise Crocce Romano Espinosa,et al.  Recycling of batteries: a review of current processes and technologies , 2004 .

[20]  Nerilso Bocchi,et al.  Lead recovery from a typical Brazilian sludge of exhausted lead-acid batteries using an electrohydrometallurgical process , 2002 .

[21]  Olivier Pourret,et al.  Lead distribution in soils impacted by a secondary lead smelter: Experimental and modelling approaches. , 2016, The Science of the total environment.

[22]  N. Palaniswamy,et al.  Elecrokinetic separation of sulphate and lead from sludge of spent lead acid battery. , 2011, Journal of hazardous materials.

[23]  Xin Tong,et al.  From Legal Transplants to Sustainable Transition , 2013 .

[24]  Sohrab Rohani,et al.  Treatment of landfill waste, leachate and landfill gas: A review , 2015, Frontiers of Chemical Science and Engineering.

[25]  Yuchen Hu,et al.  Lead citrate precursor route to synthesize nanostructural lead oxide from spent lead acid battery paste , 2013 .

[26]  Christopher R. Cherry,et al.  Lead emissions from solar photovoltaic energy systems in China and India , 2011 .

[27]  Y. Huang,et al.  Recovery of lead from smelting fly ash of waste lead-acid battery by leaching and electrowinning. , 2016, Waste management.

[28]  Tieyong Zuo,et al.  Management of used lead acid battery in China: Secondary lead industry progress, policies and problems , 2014 .

[29]  Mario Maja,et al.  Dissolution of pastes in lead-acid battery recycling plants , 1993 .

[30]  Yi Zhang,et al.  Spent lithium-ion battery recycling - Reductive ammonia leaching of metals from cathode scrap by sodium sulphite. , 2017, Waste management.

[31]  F. Silva,et al.  Citric acid-assisted phytoextraction of lead: a field experiment. , 2013, Chemosphere.

[32]  Valeriu Gabriel Ghica,et al.  Processing oxidic waste of lead‐acid batteries in order to recover lead , 2015 .

[33]  Carl D. Parker,et al.  Lead-acid battery energy-storage systems for electricity supply networks , 2001 .

[34]  D. Kammen,et al.  Driving rural energy access: a second-life application for electric-vehicle batteries , 2014 .

[35]  David Finlow,et al.  The lead and lead-acid battery industries during 2002 and 2007 in China ☆ , 2009 .

[36]  Shaoli Feng,et al.  Lead-acid battery use in the development of renewable energy systems in China , 2009 .

[37]  Wei Li,et al.  A green lead hydrometallurgical process based on a hydrogen-lead oxide fuel cell , 2013, Nature Communications.

[38]  A. Sánchez,et al.  Lead production from recycled paste of lead acid batteries with SiC-Na2CO3 , 2016 .

[39]  D. P. Boden,et al.  Improved oxides for production of lead/acid battery plates , 1998 .

[40]  R. Vasant Kumar,et al.  Preparation of lead carbonate from spent lead paste via chemical conversion , 2013 .

[41]  Richard S. Treptow The Lead-Acid Battery: Its Voltage in Theory and in Practice , 2002 .

[42]  R. Vasant Kumar,et al.  Preparation and characterization of nano-structured lead oxide from spent lead acid battery paste. , 2012, Journal of hazardous materials.

[43]  Jilt Sietsma,et al.  A Cleaner Process for Selective Recovery of Valuable Metals from Electronic Waste of Complex Mixtures of End-of-Life Electronic Products. , 2015, Environmental science & technology.

[44]  Wei Liu,et al.  Temporal and spatial characteristics of lead emissions from the lead-acid battery manufacturing industry in China. , 2017, Environmental pollution.

[45]  P. Hills,et al.  Extended producer responsibility and eco-design changes: perspectives from China , 2008 .

[46]  Donald Huisingh,et al.  Consumer behavior and perspectives concerning spent household battery collection and recycling in China: a case study , 2015 .

[47]  R. V. Kumar,et al.  Leaching of waste battery paste components. Part 1: Lead citrate synthesis from PbO and PbO2 , 2009 .

[48]  Wei Liu,et al.  Life cycle assessment of lead-acid batteries used in electric bicycles in China , 2015 .

[49]  Wenjing Luo,et al.  Lead poisoning in China: a nightmare from industrialisation , 2011, The Lancet.

[50]  D Andrews,et al.  Environmentally sound technologies for recycling secondary lead , 2000 .

[51]  Archana Agrawal,et al.  Iron and Copper Recovery/Removal from Industrial Wastes: A Review , 2009 .

[52]  Keiko Wada,et al.  Reduction in toxicity and generation of slag in secondary lead process , 2011 .

[53]  Tieyong Zuo,et al.  The lead-acid battery industry in China: outlook for production and recycling , 2015, Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA.

[54]  Aditya Jayan,et al.  Inverse Charging Techniques for Sulfation Reversal in Flooded Lead-Acid Batteries , 2016 .

[55]  Wei Li,et al.  Preparation of High Purity Lead Oxide from Spent Lead Acid Batteries via Desulfurization and Recrystallization in Sodium Hydroxide , 2016 .

[56]  Jiang Ji-m Situation and Development Trend of Lead Smelting Technology at Home and Abroad , 2013 .

[57]  Roberta Salomone,et al.  An Eco-balance of a Recycling Plant for Spent Lead–Acid Batteries , 2005, Environmental management.

[58]  Xiaochun Peng,et al.  Lead exposure assessment from study near a lead-acid battery factory in China. , 2012, The Science of the total environment.