Detection of SCC on prestressing steel wire by the simultaneous use of electrochemical noise and acoustic emission measurements

Abstract Electrochemical voltage and current noise were measured simultaneously with acoustic emission (AE) measurements during the stress-corrosion cracking (SCC) of prestressing steel wire. Elongation of the specimens was also measured. Constant load tests were performed on specimens made from prestressing steel with a diameter of 3.2 mm: the central wire of a seven-wire strand was used. The specimens were exposed to diluted sodium thiocyanate (a modified version of the test as proposed in EN ISO 15630–3), with and without the addition of an organic corrosion inhibitor. EN was measured between the stressed central cold-drawn wire and the neighbouring wires which acted as reference electrodes for the electrochemical current and voltage measurements. AE was measured by two AE sensors fixed to the specimen. In order to characterize the SCC processes on the prestressing steel wire, the results of all the used techniques were analysed and compared. The effect of the inhibitor on these processes was also studied. A significantly longer time to failure was observed in the experiments with the added inhibitor. The results of the techniques, in combination with SEM and metallographic inspections, confirmed that the inhibitor had a specific influence on SCC. It was concluded that measurements of combined methods are promising for the reliable detection of SCC.

[1]  R. H. Jones,et al.  Evaluation of stress corrosion crack initiation using acoustic emission , 1991 .

[2]  M. C. Alonso,et al.  Susceptibility to stress corrosion cracking of a prestressing steel in NaHCO3 solutions , 1993 .

[3]  K. Sieradzki,et al.  Stress-corrosion cracking of sensitized type 304 stainless steel in thiosulfate solutions , 1982 .

[4]  P. M. Scott,et al.  The mechanism of intergranular stress corrosion cracking of sensitised austenitic stainless steel in dilute thiosulphate solution , 1992 .

[5]  A. Legat,et al.  Chaotic Analysis of Electrochemical Noise Measured on Stainless Steel , 1995 .

[6]  J. Galland,et al.  Electrochemical noise analysis of cathodically polarised AISI 4140 steel. II. Identification of potential fluctuation sources for unstressed electrodes , 2002 .

[7]  T. Kondo,et al.  Current and Potential Fluctuation Characteristics in Intergranular Stress Corrosion Cracking Processes of Stainless Steels , 2000 .

[8]  P. M. Scott,et al.  Electrochemical noise measurements of stress corrosion cracking of sensitised austenitic stainless steel in high-purity oxygenated water at 288°C , 1992 .

[9]  U. Nürnberger,et al.  Corrosion induced failure mechanisms of prestressing steel , 2002 .

[10]  B. D. Lichter,et al.  A fully plastic microcracking model for transgranular stress-corrosion cracking in planar-slip materials , 1994 .

[11]  M. A. Friesel,et al.  Acoustic emission from integranular subcritical crack growth , 1989, Metallurgical and Materials Transactions A.

[12]  C. Loto,et al.  Electrochemical Noise Generation during Stress Corrosion Cracking , 1986 .

[13]  C. Loto,et al.  Electrochemical Noise Generation during Stress Corrosion Cracking of Alpha-Brass , 1987 .

[14]  D. Macdonald,et al.  Stress corrosion cracking of sensitized Type 304 stainless steel in thiosulphate solution. II. Dynamics of fracture , 2006 .

[15]  J. Broomfield Corrosion of Steel in Concrete: Understanding, investigation and repair , 1996 .

[16]  A. Legat,et al.  Comparative Analysis of Electrochemical Noise Generated During Stress Corrosion Cracking of AISI 304 Stainless Steel , 2000 .

[17]  F. Huet,et al.  Electrochemical noise analysis of cathodically polarised AISI 4140 steel. III. Influence of hydrogen absorption for stressed electrodes , 2002 .

[18]  Alan Turnbull,et al.  Modelling of environment assisted cracking , 1993 .

[19]  Robert Baboian,et al.  Corrosion tests and standards : application and interpretation , 1995 .

[20]  A. Legat,et al.  Corrosion monitoring system based on measurement and analysis of electrochemical noise , 1995 .

[21]  Andraz Legat,et al.  Electrochemical noise during non-stationary corrosion processes , 2001 .

[22]  A. Legat,et al.  Detection and differentiation between cracking processes based on electrochemical and mechanical measurements , 2004 .

[23]  Russel H. Jones,et al.  Environment-induced cracking of materials , 2008 .

[24]  C. Andrade,et al.  Relation between resistivity and corrosion rate of reinforcements in carbonated mortar made with several cement types , 1988 .

[25]  Edoardo Proverbio,et al.  Failure mechanisms of high strength steels in bicarbonate solutions under anodic polarization , 2003 .

[26]  B. Isecke,et al.  Assessment of test methods for evaluation stress corrosion cracking susceptibility of prestressing steels , 2002 .