Synthesis, crystal structures and magnetic characterization of four β-diketonate-alkoxide iron(III) dimers. Dependence of the magnetic properties on geometrical and electronic parameters

[1]  A. Caneschi,et al.  Magnetism of large iron-oxo clusters , 2010 .

[2]  V. Gramlich,et al.  Metal Binding of Polyalcohols. 4. Structure and Magnetism of the Hexanuclear, &mgr;(6)-Oxo-Centered [OFe(6)(H(-)(3)thme)(3)(OCH(3))(3)Cl(6)](2)(-) (thme = 1,1,1-Tris(hydroxymethyl)ethane). , 1996, Inorganic chemistry.

[3]  A. Caneschi,et al.  Structure and Magnetic Properties of a Decanuclear Oxoiron(III) Cluster: A Further Step to Understanding Iron Aggregation Processes , 1996 .

[4]  A. Caneschi,et al.  Polyiron(III)-Alkoxo Clusters: a Novel Trinuclear Complex and Its Relevance to the Extended Lattices of Iron Oxides and Hydroxides , 1995 .

[5]  A. Caneschi,et al.  A Cyclic Hexairon(III) Complex with an Octahedrally Coordinated Sodium Ion at the Center, an Example of the [12]Metallacrown‐6 Structure Type , 1995 .

[6]  P. Maitlis,et al.  Discotic metallomesogens: Synthesis and properties of square planar metal bis(β-diketonate) complexes , 1994 .

[7]  D. Gatteschi,et al.  Magnetic Exchange Coupling in the FeIII6(.mu.6-O) Core: A Hint to the Magnetic Properties of Higher-Nuclearity Spin Clusters , 1994 .

[8]  S. Lippard,et al.  [Fe(OMe)2(O2CCH2Cl)]10, a Molecular Ferric Wheel , 1994 .

[9]  A. Caneschi,et al.  Iron and manganese alkoxide cubes , 1993 .

[10]  J. Zubieta,et al.  Hydrothermal synthesis and characterization of hexavanadium polyoxo alkoxide anion clusters: crystal structures of the vanadium(IV) species Ba[V6O7(OH)3{(OCH2)3CCH3}3].3H2O and Na2[V6O7{(OCH2)3CCH2CH3}4], of the mixed-valence complex (Me3NH)[VIV5VVO7(OH)3{(OCH2)3CCH3}3], and of the fluoro derivative , 1993 .

[11]  A. Rappé,et al.  Ab initio calculation of the magnetic exchange interactions in (.mu.-oxo)diiron(III) systems using a broken symmetry wave function , 1992 .

[12]  K. Hagen,et al.  Iron oxo aggregation: Fe3 to Fe6. Synthesis, structure, and magnetic properties of the hexanuclear dication [Fe6(.mu.4-O)2(.mu.2-OMe)8(OMe)4(tren)2]2+, a soluble, crystalline model of iron oxo hydroxo nanoparticles, the core of ferritin and rust formation , 1992 .

[13]  S. Lippard,et al.  Magnetostructural correlations in magnetically coupled (.mu.-oxo)diiron(III) complexes , 1991 .

[14]  G. Fallon,et al.  A doubly bridged binuclear iron(III) complex containing inequivalent metal environments. Synthesis, structure and magnetism , 1991 .

[15]  H. Schmalle,et al.  Synthesis and structure of a novel hexanuclear iron(III) complex containing six terminal and twelve bridging alkoxo groups and one μ6-Oxo bridge , 1990 .

[16]  D. Kurtz Oxo- and hydroxo-bridged diiron complexes: a chemical perspective on a biological unit , 1990 .

[17]  L. Que,et al.  A Bis(μ-alkoxo)diiron Complex with Novel Terminally Ligated Carboxylates , 1990 .

[18]  R. H. Holm,et al.  Binuclear iron system ferromagnetic in three oxidation states: synthesis, structures, and electronic aspects of molecules with a Fe2(OR)2 bridge unit containing Fe(III,III), Fe(III,II), and Fe(II,II) , 1989 .

[19]  T. D. Stack,et al.  Angle dependence of the properties of the [Fe2X]4+ bridge unit (X = O, S): structures, antiferromagnetic coupling, and properties in solution , 1988 .

[20]  R. Willett Magneto-Structural Correlations in Copper(II) Compounds , 1985 .

[21]  Kazuhiro Takahashi,et al.  Crystal structures and magnetism of binuclear iron(III) complexes with a linear oxo-bridge, [Fe2O(bbimae)2X2][NO3]2{bbimae =2-[bis(benzimidazol-2-ylmethyl)amino]ethanol, X = Cl or NCS} , 1985 .

[22]  T. Tarantelli,et al.  Exchange interaction in multinuclear transition-metal complexes. 6. Nature of metal-metal coupling in dinuclear iron(III) systems containing FeOFeO bridging units , 1984 .

[23]  K. Raymond,et al.  Coordination chemistry of microbial iron transport compounds. 26. Dimeric dialkoxo-bridged iron(III) complexes of linear dihydroxamate ligands , 1984 .

[24]  W. Schneider Hydrolysis of Iron(III)…Chaotic Olation Versus Nucleation , 1984 .

[25]  T. Tarantelli,et al.  Exchange interaction in multinuclear transition-metal complexes. 2. Synthesis and structural and magnetic studies of a dinuclear iron(III) derivative of the heptadentate Schiff base trisalicylidenetriethylenetetramine , 1982 .

[26]  T. Tarantelli,et al.  Exchange interaction in multinuclear transition-metal complexes. 1. Synthesis, x-ray structure, and magnetic and spectroscopic properties of di-.mu.-methoxy-dichloro[1,4-piperazinebis(N-ethylenesalicylaldiminato)]diiron(III), Fe2L(OCH3)2Cl2 , 1982 .

[27]  H. Lemay,et al.  Synthesis, magnetic, and structural characterization of di-µ-(benzyloxo)-bis[(2,2,6,6-tetramethylheptane-3,5-dionato)copper(II)] , 1979 .

[28]  H. Schugar,et al.  Molecular structure and magnetic properties of .mu.-oxo-bis[4-chloro-2,6-pyridinedicarboxylatodiaquoiron(III)]tetrahydrate, [Cl-C7H2NO4(H2O)2Fe]2O.4H2O, a complex with linear Fe2O4+ unit , 1978 .

[29]  D. Hendrickson,et al.  Reaction of .mu.-oxo-bridged iron(III) complexes with organic acids: a characterization of the products , 1978 .

[30]  H. Schugar,et al.  Molecular structure and magnetic properties of .mu.-dihydroxo-bis[4-dimethylamino-2,6-pyridinedicarboxylatoaquoiron(III)]dihydrate, [(CH3)2NC7H2NO4(H2O)FeOH]2.2H2O , 1978 .

[31]  D. Hodgson,et al.  Relation between the singlet-triplet splitting and the copper-oxygen-copper bridge angle in hydroxo-bridged copper dimers , 1976 .

[32]  D. Mastropaolo,et al.  Molecular structure and magnetic properties of .mu.-dihydroxo-bis[2,6-pyridinedicarboxylatoaquoiron(III)] and .mu.-dihydroxo-bis[4-hydroxo-2,6-pyridinedicarboxylatoaquoiron(III)] tetrahydrate , 1976 .

[33]  Roald Hoffmann,et al.  Orbital interactions in metal dimer complexes , 1975 .

[34]  P. Eller,et al.  Structure studies of iron(III) salicylaldimine complexes. Five-coordinate monomeric and dimeric complexes , 1974 .

[35]  G. Rossman,et al.  Chelates of β-diketones. VI. Synthesis and characterization of dimeric dialkoxo-bridged iron(III) complexes with acetylacetone and 2,2,6,6-tetramethylheptane-3,5-dione (HDPM) , 1972 .

[36]  G. Long,et al.  Preparation, electronic properties, and structure of a binuclear iron(III) complex containing a four-membered iron-oxygen ring , 1970 .

[37]  K. Kopecky,et al.  Preparation of Dipivaloylmethane , 1962 .