Highly efficient recycling of a "sandwich" type polyoxometalate oxidation catalyst using solvent resistant nanofiltration.

A "sandwich" type polyoxometalate catalyst ([MeN(n-C8H17)3]12[WZn3(ZnW9O34)2]) was very efficiently recycled by nanofiltration with almost quantitative retention, using an alpha-alumina supported mesoporous gamma-alumina membrane.

[1]  J. E. Elshof,et al.  Development and comparative study of different nanofiltration membranes for recovery of highly charged large ions , 2002 .

[2]  R. Neumann,et al.  Self-Assembled Na12[WZn3(ZnW9O34)2] as an Industrially Attractive Multi-Purpose Catalyst for Oxidations with Aqueous Hydrogen Peroxide , 2004 .

[3]  Justin T. Scarpello,et al.  The separation of homogeneous organometallic catalysts using solvent resistant nanofiltration , 2002 .

[4]  H. Dijkstra,et al.  Shape-persistent nanosize organometallic complexes: synthesis and application in a nanofiltration membrane reactor. , 2003, The Journal of organic chemistry.

[5]  R. Neumann,et al.  A highly chemoselective, diastereoselective, and regioselective epoxidation of chiral allylic alcohols with hydrogen peroxide, catalyzed by sandwich-type polyoxometalates: enhancement of reactivity and control of selectivity by the hydroxy group through metal-alcoholate bonding. , 2003, The Journal of organic chemistry.

[6]  H. Christenson Capillary condensation in systems of immiscible liquids , 1985 .

[7]  A. Buekenhoudt,et al.  Recycling of the homogeneous Co-Jacobsen catalyst through solvent-resistant nanofiltration (SRNF). , 2004, Chemical communications.

[8]  Andrew G. Livingston,et al.  Homogeneous catalyst separation and re-use through nanofiltration of organic solvents , 2002 .

[9]  J. E. ten Elshof,et al.  Effect of trace amounts of water on organic solvent transport through gamma-alumina membranes with varying pore sizes. , 2004, Langmuir.

[10]  Koen De Smet,et al.  Nanofiltration-coupled catalysis to combine the advantages of homogeneous and heterogeneous catalysis , 2001 .

[11]  H. Dijkstra,et al.  The use of ultra- and nanofiltration techniques in homogeneous catalyst recycling. , 2002, Accounts of chemical research.

[12]  R. Neumann,et al.  A water-soluble and "self-assembled" polyoxometalate as a recyclable catalyst for oxidation of alcohols in water with hydrogen peroxide. , 2003, Journal of the American Chemical Society.

[13]  R. Neumann,et al.  Aqueous Biphasic Oxidation: A Water‐Soluble Polyoxometalate Catalyst for Selective Oxidation of Various Functional Groups with Hydrogen Peroxide , 2004 .

[14]  Andrew G. Livingston,et al.  Increased catalytic productivity for nanofiltration-coupled Heck reactions using highly stable catalyst systems , 2002 .