Electric dipole moment function of the X 1Σ+ state of CO: Vibration-rotation matrix elements for transitions of gas laser and astrophysical interest

The electric dipole moment function of the ground electronic state of carbon monoxide has been determined by combining numerical solutions of the radial Schrodinger equation with absolute intensity data of vibration–rotation bands. The derived dipole moment function is used to calculate matrix elements of interest to stellar astronomy and of importance in the carbon monoxide laser.

[1]  F. Valero,et al.  Absolute intensity measurement of the 4-0 vibration-rotation band of carbon monoxide , 1976 .

[2]  R. Tipping Vibration-rotation intensities for “hot” bands☆ , 1976 .

[3]  J. Bouanich,et al.  Vibration-rotation matrix elements for diatomic molecules; vibration-rotation interaction functions Fv'v (m) for CO , 1976 .

[4]  J. Vergès,et al.  Measurements of line strengths in the 2-0 band of CO , 1975 .

[5]  Sunil Sarangi,et al.  Measurements of intensities and nitrogen-broadened linewidths in the CO fundamental at low temperatures☆ , 1975 .

[6]  J. Muenter,et al.  Electric dipole moment of carbon monoxide , 1975 .

[7]  A. Sauval,et al.  The CO fundamental bands in the solar spectrum , 1975 .

[8]  J. Bouanich,et al.  Moments de transition vibrationnelle des molecules diatomiques. Intensite des raies rovibrationnelles des bandes 0→2 et 0→3 et fonction dipolaire de CO , 1974 .

[9]  M. Krauss,et al.  Multiconfiguration self-consistent-field calculation of the dipole moment function of CO/X 1 sigma +/ , 1974 .

[10]  J. Watson,et al.  Second-order semiclassical calculations for diatomic molecules , 1974 .

[11]  W. Roh,et al.  CO laser spectra , 1974 .

[12]  D. Cerny,et al.  Emission infra-rouge de la molecule co dans la zone de reaction d'une flamme oxyacetylenique , 1974 .

[13]  M. Weisbach,et al.  Linewidths and transition probabilities for the carbon monoxide laser lines , 1973 .

[14]  N. Djeu,et al.  Method for Measuring Relative Transition Probabilities of Cascading Molecular Bands: Application to CO Fundamental Bands , 1972 .

[15]  I. Suzuki Dipole Moment Functions of CO and HCl , 1972 .

[16]  R. H. Hunt,et al.  Line intensities in the 3-0 band of CO and dipole moment matrix elements for the CO molecule☆ , 1969 .

[17]  Robert H. Hunt,et al.  High‐Resolution Determination of the Widths of Self‐Broadened Lines of Carbon Monoxide , 1968 .

[18]  R. H. Hunt,et al.  Measurement of Line Strengths at Low Pressures—Application to the 2–0 Band of CO , 1968 .

[19]  L. Young,et al.  Dipole Moment Function and Vibration—Rotation Matrix Elements for CO , 1966 .

[20]  W. Huo Electronic Structure of CO and BF , 1965 .

[21]  R. Nesbet Electronic Structure of N2, CO, and BF , 1964 .

[22]  J. W. Trischka,et al.  Dipole Moment Function of Diatomic Molecules , 1959 .

[23]  R. F. Wallis,et al.  Influence of Vibration‐Rotation Interaction on Line Intensities in Vibration‐Rotation Bands of Diatomic Molecules , 1955 .

[24]  G. Contopoulos Highlights of Astronomy , 1974 .

[25]  C. Effantin,et al.  Forces d'oscillateur absolues de rotation dans les transitions 2-0, 3-1, 4-2, 5-3, du spectre de vibration-rotation de la molecule CO, deduites de mesures d'intensites en emission , 1972 .

[26]  K. Cashion,et al.  A method for calculating vibrational transition probabilities , 1963 .