Conduction studies on copper indium diselenide thin films

Abstract Thin films of CuInSe2 were prepared by thermal evaporation onto well cleaned glass substrates kept at 303 K. The thicknesses of the films were measured by Tolansky (Fizeau fringes) technique. XRD results reveal that the films are polycrystalline in nature. Thin film capacitors of the type (Al–CuInSe2–Al) have been fabricated. Dielectric and ac conduction studies were performed on a stabilised sample of thickness 175 nm at various frequencies (10 kHz to 5 MHz) and temperatures (303–353 K). DC conduction studies were also carried out on a sample of thickness 230 nm. The value of dielectric constant has been evaluated as 10.8 at 5 MHz and at room temperature. From the ac conduction studies, it was confirmed that the mechanism responsible for the conduction process is electronic hopping. From the dc conduction mechanism, it has been observed that the Schottky type of conduction is predominant in the high field region and the Schottky barrier height has been determined as 0.1 eV. The ac and dc activation energies have also been calculated as 0.12 and 0.27 eV, respectively.

[1]  C. Balasubramanian,et al.  Dielectric studies on tellurium oxide thin films , 1982 .

[2]  C. Balasubramanian,et al.  Structure, Dielectric, and AC Conduction Studies on Germanium Dioxide Thin Films , 1987 .

[3]  Low temperature conduction and breakdown phenomena in Au-SiO x -Au thin-film sandwich structures , 1975 .

[4]  S. Wasim Transport properties of CuInSe2 , 1986 .

[5]  R. Sladek,et al.  Capacitance and dielectric constant of Cd1−xMnxTe , 1985 .

[6]  D. S. Campbell,et al.  Amorphous PbTiO capacitors , 1968 .

[7]  L. Kazmerski,et al.  Growth and properties of vacuum deposited CuInSe2 thin films , 1976 .

[8]  D. Mangalaraj,et al.  Structure, Composition, Dielectric, and AC Conduction Studies on Tin Selenide Films , 1996 .

[9]  D. Hughes,et al.  Electrical conduction in reactively sputtered tantalum oxide thin films , 1974 .

[10]  Samuel Tolansky,et al.  Multiple-beam interferometry of surfaces and films , 1948 .

[11]  A. Goswami A. C. behaviour and dielectric relaxation in indium oxide films , 1977 .

[12]  L. Kazmerski Status and assessment of photovoltaic technologies , 1989 .

[13]  J. Schmidt,et al.  Preparation and properties of CuInSe2 thin films produced by selenization of co-sputtered Cu-In films , 1994 .

[14]  C. Balasubramanian,et al.  Structure, dielectric, and AC conduction properties of amorphous germanium thin films , 1992 .

[15]  G. Kühn,et al.  Structural and electrical properties of CuInSe2 epitaxial layers prepared by single-source evaporation , 1980 .

[16]  J. M. Codina,et al.  Electrical conductivity of polycrystalline CuInSe2 thin films , 1984 .

[17]  H. Birey,et al.  Dielectric properties of aluminum oxide films , 1978 .