Current technologies for analysis of biomass thermochemical processing: a review.

Pyrolysis and gasification are two of the more promising utilization methods for the conversion of biomass toward a clean fuel source. To truly understand and model these processes requires detailed knowledge ranging from structural information of raw biomass, elemental composition, gas-phase reaction kinetics and mechanisms, and product distributions (both desired and undesired). The various analytical methods of biomass pyrolysis/gasification processing are discussed, including reactor types, analytical tools, and recent examples in the areas of (a) compositional analysis, (b) structural analysis, (c) reaction mechanisms, and (d) kinetic studies on biomass thermochemical processing.

[1]  Dietrich Meier,et al.  Norms and standards for fast pyrolysis liquids: 1. Round robin test , 2005 .

[2]  Serge Bourbigot,et al.  Model-free method for evaluation of activation energies in modulated thermogravimetry and analysis of cellulose decomposition , 2006 .

[3]  Hermann Hofbauer,et al.  Stoichiometric Water Consumption of Steam Gasification by the FICFB‐Gasification Process , 2008 .

[4]  D. Meier,et al.  Characterization of the water-insoluble fraction from fast pyrolysis liquids (pyrolytic lignin) , 2001 .

[5]  Dietrich Meier,et al.  Characterization of the water-insoluble fraction from fast pyrolysis liquids (pyrolytic lignin). Part IV: Structure elucidation of oligomeric molecules. , 2009 .

[6]  María U. Alzueta,et al.  Pyrolysis of eucalyptus at different heating rates: studies of char characterization and oxidative reactivity , 2005 .

[7]  S. Bourbigot,et al.  Three model-Free methods for calculation of activation energy in TG , 2004 .

[8]  D. Meier,et al.  State of the art of applied fast pyrolysis of lignocellulosic materials - a review , 1999 .

[9]  Eric M. Suuberg,et al.  Thermal Effects in Cellulose Pyrolysis: Relationship to Char Formation Processes , 1996 .

[10]  I. Ericsson Influence of pyrolysis parameters on results in pyrolysis-gas chromatography , 1985 .

[11]  Mark F. Davis,et al.  Rapid analysis of the chemical composition of agricultural fibers using near infrared spectroscopy and pyrolysis molecular beam mass spectrometry , 2004 .

[12]  P. Rosenberg,et al.  Char porosity characterisation by scanning electron microscopy and image analysis , 2000 .

[13]  J. Diebold A review of the toxicity of biomass pyrolysis liquids formed at low temperatures , 1997 .

[14]  J. Daily,et al.  Characterization of biomass pyrolysis vapors with molecular beam, single photon ionization time-of-flight mass spectrometry. , 2001, Chemosphere.

[15]  Liao Bin,et al.  Experimental Investigation of Biomass Gasification in a Fluidized Bed Reactor , 2008 .

[16]  C. Blasi,et al.  An Experimental Investigation of Heat-Transfer Limitations in the Flash Pyrolysis of Cellulose , 1997 .

[17]  Alexander L. Brown,et al.  A Study of Cellulose Pyrolysis Chemistry and Global Kinetics at High Heating Rates , 2001 .

[18]  M. Klein,et al.  Model pathways in lignin thermolysis. 1. Phenethyl phenyl ether , 1983 .

[19]  Maurice A. Bergougnou,et al.  The role of temperature in the fast pyrolysis of cellulose and wood , 1988 .

[20]  Calculation of activation energies using the sinusoidally modulated temperature , 2002 .

[21]  S. Yaman Pyrolysis of biomass to produce fuels and chemical feedstocks , 2004 .

[22]  M. Antal,et al.  Cellulose Pyrolysis Kinetics: The Current State of Knowledge , 1995 .

[23]  David E. Comings,et al.  Principles and techniques of electron microscopy: Biological applications , 1971 .

[24]  T. Górecki,et al.  Analytical pyrolysis as a tool for the characterization of natural organic matter—A comparison of different approaches , 2007 .

[25]  Aw Drews,et al.  Standard Test Methods for Instrumental Determination of Carbon, Hydrogen, and Nitrogen in Petroleum Products and Lubricants , 1998 .

[26]  Dinesh Mohan,et al.  Pyrolysis of Wood and Bark in an Auger Reactor: Physical Properties and Chemical Analysis of the Produced Bio-oils , 2008 .

[27]  M. S. Thomsen,et al.  Pressurized laser pyrolysis of coal , 1995 .

[28]  Serge Bourbigot,et al.  Modulated thermogravimetry in analysis of decomposition kinetics , 2005 .

[29]  Anthony V. Bridgwater,et al.  Renewable fuels and chemicals by thermal processing of biomass , 2003 .

[30]  Lan Tang,et al.  Characterization of gaseous and solid product from thermal plasma pyrolysis of waste rubber. , 2003, Environmental science & technology.

[31]  I. Hasegawa,et al.  Pyrolysis of the mixture of biomass and plastics in countercurrent flow reactor Part I: Experimental analysis and modeling of kinetics , 2008 .

[32]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[33]  A. Bridgwater,et al.  Effect of reactor configuration on the yields and structures of pine-wood derived pyrolysis liquids: A comparison between ablative and wire-mesh pyrolysis , 1994 .

[34]  F. Agblevor,et al.  Molecular-beam mass-spectrometric analysis of lignocellulosic materials: I. Herbaceous biomass , 1994 .

[35]  A. Rao,et al.  Overview of combustion and gasification of rice husk in fluidized bed reactors , 1998 .

[36]  Guy Cox,et al.  Optical Imaging Techniques in Cell Biology , 2006 .

[37]  Desmond Radlein,et al.  Liquid products from the continuous flash pyrolysis of biomass , 1985 .

[38]  Andrew G. Glen,et al.  APPL , 2001 .

[39]  I. Bari,et al.  Air Gasification of Biomass in a Downdraft Fixed Bed: A Comparative Study of the Inorganic and Organic Products Distribution , 2000 .

[40]  S. Camarero,et al.  Absolute quantitation of lignin pyrolysis products using an internal standard , 1997 .

[41]  J. Daily,et al.  Thermal decomposition of furan generates propargyl radicals. , 2009, The journal of physical chemistry. A.

[42]  Mark Bates,et al.  Three-Dimensional Super-Resolution Imaging by Stochastic Optical Reconstruction Microscopy , 2008, Science.

[43]  G. Gerbaud,et al.  Investigation with 13C NMR, EPR and magnetic susceptibility measurements of char residues obtained by pyrolysis of biomass , 2007 .

[44]  Ashok Pandey,et al.  Handbook of Plant Based Biofuels , 2007 .

[45]  Z. Bai,et al.  Studies on pyrolysis of wheat straw residues from ethanol production by solid-state fermentation , 2008 .

[46]  M. Sephton,et al.  Quantitative flash pyrolysis Fourier transform infrared spectroscopy of organic materials. , 2009, Analytica chimica acta.

[47]  Piotr Majerski,et al.  A second look at fast pyrolysis of biomass—the RTI process , 1999 .

[48]  Stephen Y. Lin,et al.  Methods in Lignin Chemistry , 1992, Springer Series in Wood Science.

[49]  Woojin Lee,et al.  Fast pyrolysis of Oil Mallee Woody Biomass : Effect of temperature on the yield and quality of pyrolysis products , 2008 .

[50]  Vladimir Strezov,et al.  Thermal characterisation of microalgae under slow pyrolysis conditions , 2009 .

[51]  Woojin Lee,et al.  Effects of Temperature on the Formation of Lignin-Derived Oligomers during the Fast Pyrolysis of Mallee Woody Biomass , 2008 .

[52]  H. Pereira,et al.  Influence of tree eccentric growth on syringyl/guaiacyl ratio in Eucalyptus globulus wood lignin assessed by analytical pyrolysis , 2001 .

[53]  Ayşe Eren Pütün,et al.  Biomass to Bio-Oil via Fast Pyrolysis of Cotton Straw and Stalk , 2002 .

[54]  Anders Nordin,et al.  Effect of Coal Minerals on Chlorine and Alkali Metals Released during Biomass/Coal Cofiring , 1999 .

[55]  Yi Li,et al.  FT-IR imaging and pyrolysis-molecular beam mass spectrometry: new tools to investigate wood tissues , 2005, Wood Science and Technology.

[56]  N. Papayannakos,et al.  Modelling of the pyrolysis of biomass particles. Studies on kinetics, thermal and heat transfer effects , 1991 .

[57]  Irvin Glassman,et al.  Pyrolysis and Oxidation of Anisole near 1000 K , 1997 .

[58]  José L. Figueiredo,et al.  Pyrolysis kinetics of lignocellulosic materials—three independent reactions model , 1999 .

[59]  Ch. Bühler,et al.  Curie Point Pyrolysis Gas Chromatography , 1970 .

[60]  C. F. Cullis,et al.  The pyrolysis of cellulose under conditions of rapid heating , 1983 .

[61]  A. Corma,et al.  Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering. , 2006, Chemical reviews.

[62]  Jesse A. Contreras,et al.  Multidimensional GC/MS analysis of pyrolytic oils , 2005 .

[63]  M. Klein,et al.  Modeling of Lignin Thermolysis , 2008 .

[64]  Thomas A. Milne,et al.  Direct mass-spectrometric studies of the pyrolysis of carbonaceous fuels: III. Primary pyrolysis of lignin , 1986 .

[65]  W. Peters,et al.  Product compositions and kinetics for rapid pyrolysis of cellulose , 1982 .

[66]  Anthony V. Bridgwater,et al.  Progress in Thermochemical Biomass Conversion , 2001 .

[67]  Fusion-like behaviour of wood pyrolysis , 1987 .

[68]  Anthony V. Bridgwater,et al.  Research in thermochemical biomass conversion. , 1988 .

[69]  F. Hileman,et al.  Pyrolysis mass spectrometry of recent and fossil biomaterials: Compendium and atlas , 1982 .

[70]  R Zimmermann,et al.  Comprehensive on-line characterization of complex gas mixtures by quasi-simultaneous resonance-enhanced multiphoton ionization, vacuum-UV single-photon ionization, and electron impact ionization in a time-of-flight mass spectrometer: setup and instrument characterization. , 2004, Analytical chemistry.

[71]  L. Danielsson,et al.  Estimation of effective sample size when analysing powders with diffuse reflectance near-infrared spectrometry , 1998 .

[72]  Chun-Zhu Li,et al.  Volatilisation and catalytic effects of alkali and alkaline earth metallic species during the pyrolysis and gasification of Victorian brown coal. Part VII. Raman spectroscopic study on the changes in char structure during the catalytic gasification in air , 2006 .

[73]  A. Lifshitz,et al.  Decomposition and ring expansion in methylcyclopentadiene: single-pulse shock tube and modeling study , 2005 .

[74]  Anthony V. Bridgwater,et al.  Ablative plate pyrolysis of biomass for liquids , 1994 .

[75]  T. A. Milne,et al.  Biomass Gasifier "Tars": Their Nature, Formation, and Conversion , 1998 .

[76]  C. Blasi,et al.  GC/MS characterization of liquids generated from low-temperature pyrolysis of wood , 2003 .

[77]  T. Wampler,et al.  Introduction to pyrolysis-capillary gas chromatography. , 1999, Journal of chromatography. A.

[78]  S. Stout,et al.  Laser pyrolysis—gas chromatography / mass spectrometry of two synthetic organic polymers , 1991 .

[79]  H. Nimz Beech Lignin—Proposal of a Constitutional Scheme , 1974 .

[80]  Haiping Yang,et al.  Characteristics of hemicellulose, cellulose and lignin pyrolysis , 2007 .

[81]  K. Fukushima,et al.  Application of ToF-SIMS to the study on heartwood formation in Cryptomeria japonica trees , 2008 .

[82]  J. Boon,et al.  On-line Curie-point pyrolysis-high-performance liquid chromatographic-mass spectrometric analysis of lignin polymers , 1996 .

[83]  K. Kadam,et al.  Fourier transform infrared quantitative analysis of sugars and lignin in pretreated softwood solid residues , 2001, Applied biochemistry and biotechnology.

[84]  K. Kuroda,et al.  Pyrolysis of lignin in the presence of tetramethylammonium hydroxide: a convenient method for S/G ratio determination. , 2002, Journal of agricultural and food chemistry.

[85]  Anthony V. Bridgwater,et al.  Fast pyrolysis of biomass : a handbook , 1999 .

[86]  Guillaume Boissonnet,et al.  Biomass pyrolysis experiments in an analytical entrained flow reactor between 1073 K and 1273 K , 2008 .

[87]  Michael Jerry Antal,et al.  A Round-Robin Study of Cellulose Pyrolysis Kinetics by Thermogravimetry , 1999 .

[88]  A. Zukal,et al.  Synthesis of liquid fuels from products of biomass gasification , 1994 .

[89]  Ravikishan R. Guddeti,et al.  Depolymerization of Polyethylene Using Induction-Coupled Plasma Technology , 2000 .

[90]  Chun-Zhu Li,et al.  Drastic changes in biomass char structure and reactivity upon contact with steam , 2008 .

[91]  Steve Deutch,et al.  Quantitative measurement of biomass gasifier tars using a molecular-beam mass spectrometer : Comparison with traditional impinger sampling , 2007 .

[92]  Chun-Zhu Li,et al.  Volatilisation and catalytic effects of alkali and alkaline earth metallic species during the pyrolysis and gasification of Victorian brown coal. Part VIII. Catalysis and changes in char structure during gasification in steam , 2006 .

[93]  O. Ito,et al.  Exploring Radicals in Carbonaceous Solids by Means of Pulsed EPR Spectroscopy , 2002 .

[94]  S. Phillips Technoeconomic Analysis of a Lignocellulosic Biomass Indirect Gasification Process To Make Ethanol via Mixed Alcohols Synthesis , 2007 .

[95]  A. Chaala,et al.  Characterization of bio-oils in chemical families , 2007 .

[96]  Eric M. Suuberg,et al.  Cellulose Thermal Decomposition Kinetics: Global Mass Loss Kinetics , 1995 .

[97]  Hartmut Spliethoff,et al.  Science in Thermal and Chemical Biomass Conversion , 2006 .

[98]  The production of liquid fuel by fast pyrolysis of biomass , 1995 .

[99]  R. Evans,et al.  The pyrolysis of anisole (C6H5OCH3) using a hyperthermal nozzle , 2001 .

[100]  John B. Shoven,et al.  I , Edinburgh Medical and Surgical Journal.

[101]  R. Evans,et al.  Kinetic analysis of the gas-phase pyrolysis of carbohydrates , 2001 .

[102]  Manuel Garcia-Perez,et al.  Production and fuel properties of pine chip bio-oil/biodiesel blends , 2007 .

[103]  Katta G. Murty,et al.  On KΔ , 1986, Discret. Appl. Math..

[104]  M. Baron,et al.  Recent trends and developments in pyrolysis-gas chromatography. , 2008, Journal of chromatography. A.

[105]  Gerrit Brem,et al.  Experimental comparison of biomass chars with other catalysts for tar reduction , 2008 .

[106]  S. George,et al.  Applications of laser micropyrolysis-gas chromatography-mass spectrometry , 1998 .

[107]  J. Lédé,et al.  Fast pyrolysis of wood: direct measurement and study of ablation rate☆ , 1985 .

[108]  A. Lifshitz,et al.  Decomposition, isomerization, and ring expansion in 2-methylindene: Single-pulse shock tube and modeling study , 2004 .

[109]  Serge Bourbigot,et al.  Kinetic analysis of the thermal decomposition of cellulose: The main step of mass loss , 2007 .

[110]  Joo-Sik Kim,et al.  Influence of Reaction Temperature, Pretreatment, and a Char Removal System on the Production of Bio-oil from Rice Straw by Fast Pyrolysis, Using a Fluidized Bed , 2005 .

[111]  Chun-Zhu Li Some recent advances in the understanding of the pyrolysis and gasification behaviour of Victorian brown coal , 2007 .

[112]  Aw Drews,et al.  Standard Test Method for Density and Relative Density of Liquids by Digital Density Meter , 1998 .

[113]  Asri Gani,et al.  Effect of cellulose and lignin content on pyrolysis and combustion characteristics for several types of biomass. , 2007 .

[114]  Anthony V. Bridgwater,et al.  Developments in thermochemical biomass conversion , 1997 .

[115]  J. Boon,et al.  Resonance-Enhanced Multiphoton Ionization Mass Spectrometric Analysis of Lignin Using Laser Pyrolysis with Entrainment into a Supersonic Jet , 1994 .

[116]  Steven E. Ruzin,et al.  Plant Microtechnique and Microscopy , 1999 .

[117]  A. Demirbas,et al.  An Overview of Biomass Pyrolysis , 2002 .

[118]  G. A. Petersson,et al.  A complete basis set model chemistry. VI. Use of density functional geometries and frequencies , 1999 .

[119]  Alexander L. Brown,et al.  Design and characterization of an entrained flow reactor for the study of biomass pyrolysis chemistry at high heating rates , 2001 .

[120]  G. Daniel,et al.  Imaging of wood tissue by ToF-SIMS: Critical evaluation and development of sample preparation techniques , 2007 .

[121]  P. K. Aldridge,et al.  On-line monitoring of powder blend homogeneity by near-infrared spectroscopy. , 1996, Analytical chemistry.

[122]  Kinetic study of pulverized coal combustion at high pressure using a shock tube , 1997 .

[123]  Heewon Lee,et al.  Direct chemical analysis of uv laser ablation products of organic polymers by using selective ion monitoring mode in gas chromatography/mass spectrometry , 1994, Journal of the American Society for Mass Spectrometry.

[124]  J. Obst,et al.  Analytical Pyrolysis of Hardwood and Softwood Lignins and Its use in Lignin-Type Determination of Hardwood Vessel Elements , 1983 .

[125]  A. Jess,et al.  Kinetic study of Chinese biomass slow pyrolysis : Comparison of different kinetic models , 2007 .

[126]  Olof Svensson,et al.  Classification of Chemically Modified Celluloses Using a Near-Infrared Spectrometer and Soft Independent Modeling of Class Analogies , 1997 .

[127]  P. A. Ambler,et al.  Residence time distribution of solids in a circulating fluidized bed: Experimental and modelling studies , 1990 .

[128]  N. Mahinpey,et al.  Kinetics of the Pyrolysis of Lignin Using Thermogravimetric and Differential Scanning Calorimetry Methods , 2008 .

[129]  L. Tang,et al.  Treatment of organic waste using thermal plasma pyrolysis technology , 2007 .

[130]  Anthony V. Bridgwater,et al.  Advances in Thermochemical Biomass Conversion , 1993 .

[131]  P. Hatcher,et al.  Laser micropyrolysis GC–MS of lignin , 2002 .

[132]  S. Morgan,et al.  UV laser pyrolysis fast gas chromatography/time-of-flight mass spectrometry for rapid characterization of synthetic polymers: optimization of instrumental parameters , 2004 .

[133]  Blackledge Rd Application of Pyrolysis Gas Chromatography in Forensic Science. , 1992 .

[134]  Raimo Alén,et al.  Analytical Methods in Wood Chemistry, Pulping, and Papermaking , 1999, Springer Series in Wood Science.

[135]  Anja Oasmaa,et al.  Fuel oil quality of biomass pyrolysis oils-state of the art for the end users , 1999 .

[136]  G. A. Norton,et al.  Wet Chemical Method for Determining Levels of Ammonia in Syngas from a Biomass Gasifier , 2005 .

[137]  Thomas A. Milne,et al.  Molecular characterization of the pyrolysis of biomass , 1987 .

[138]  Olivier Boutin,et al.  Radiant flash pyrolysis of cellulose—Evidence for the formation of short life time intermediate liquid species , 1998 .

[139]  Miss A.O. Penney (b) , 1974, The New Yale Book of Quotations.

[140]  M. M. Mulder,et al.  Structural characterization of lignin polymers by temperature-resolved in-source pyrolysis—mass spectrometry and Curie-point pyrolysis—gas chromatography/mass spectrometry , 1993 .

[141]  Z. Qi,et al.  Review of biomass pyrolysis oil properties and upgrading research , 2007 .

[142]  P. Baglioni,et al.  SANS analysis of the microstructural evolution during the aging of pyrolysis oils from biomass. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[143]  Chun-Zhu Li,et al.  FT-Raman spectroscopic study of the evolution of char structure during the pyrolysis of a Victorian brown coal , 2006 .

[144]  D. Dayton,et al.  Direct Observation of Alkali Vapor Release during Biomass Combustion and Gasification. 1. Application of Molecular Beam/Mass Spectrometry to Switchgrass Combustion , 1995 .

[145]  A. Bridgwater,et al.  Fast pyrolysis processes for biomass , 2000 .

[146]  O. Faix,et al.  Characterization of Beech Milled Wood Lignin by Pyrolysis-Gas Chromatography-Photoionization Mass Spectrometry , 1987 .

[147]  Y. Schwob,et al.  From methane to hydrogen, carbon black and water , 1995 .

[148]  D. Mohan,et al.  Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review , 2006 .

[149]  S. Morgan,et al.  UV laser pyrolysis fast gas chromatography/time-of-flight mass spectrometry for rapid characterization of synthetic polymers: instrument development , 2004 .

[150]  Herbert Baumann,et al.  Pyrolysis of coal in hydrogen and helium plasmas , 1988 .

[151]  Dietrich Meier,et al.  Characterization of the water-insoluble fraction from pyrolysis oil (pyrolytic lignin). Part I. PY–GC/MS, FTIR, and functional groups , 2001 .

[152]  A. Di Tullio,et al.  Mass spectrometry in the biosynthetic and structural investigation of lignins. , 2004, Mass spectrometry reviews.

[153]  I. S. Goldstein,et al.  Organic Chemicals From Biomass , 1981 .

[154]  M. Nimlos,et al.  Real-Time and Post-reaction Microscopic Structural Analysis of Biomass Undergoing Pyrolysis , 2009 .

[155]  A. Drews,et al.  Standard Test Method for Kinematic Viscosity of Transparent and Opaque Liquids (the Calculation of Dynamic Viscosity) , 1998 .

[156]  Ting-Chien Chen,et al.  Pyrolysis characteristics of integrated circuit boards at various particle sizes and temperatures. , 2007, Journal of hazardous materials.

[157]  G. Daniel,et al.  Analysis of wood tissues by time-of-flight secondary ion mass spectrometry , 2007 .

[158]  J. Rouzaud,et al.  Maturation grade of coals as revealed by Raman spectroscopy: progress and problems. , 2005, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[159]  L. Puigjaner,et al.  Thermogravimetric study of the pyrolysis of waste wood , 1998 .

[160]  A. Kercher,et al.  Microstructural evolution during charcoal carbonization by X-ray diffraction analysis , 2003 .

[161]  E. Mathias,et al.  Separation and characterization of lignin compounds from the walnut (Juglans regia) shell oil using preparative TLC, GC–MS and 1H NMR , 2004 .

[162]  Thomas A. Milne,et al.  Pyrolysis oils from biomass : producing, analyzing, and upgrading , 1988 .

[163]  Edwin D. Mares,et al.  On S , 1994, Stud Logica.

[164]  Cordt Zollfrank,et al.  Decomposition and carbonisation of wood biopolymers—a microstructural study of softwood pyrolysis , 2005 .

[165]  Kim Dam-Johansen,et al.  Agglomeration in bio-fuel fired fluidized bed combustors , 2003 .

[166]  Manuel Garcia-Perez,et al.  Co-pyrolysis of sugarcane bagasse with petroleum residue. Part II. Product yields and properties , 2002 .

[167]  P. R. Solomon,et al.  Measurement and modeling of lignin pyrolysis , 1994 .

[168]  Jinsong Zhou,et al.  Research on biomass fast pyrolysis for liquid fuel , 2004 .

[169]  Robert L. White Microfurnace pyrolysis injector for capillary gas chromatography , 1991 .

[170]  Thomas A. Milne,et al.  Molecular characterization of the pyrolysis of biomass. 2. Applications , 1987 .

[171]  Richard C. Lord,et al.  Introduction to Infrared and Raman Spectroscopy. , 1965 .

[172]  K. H. Shafer,et al.  Real-time evolved gas analysis by FTIR method: an experimental study of cellulose pyrolysis , 2001 .

[173]  Kaori Saito,et al.  A new analysis of the depolymerized fragments of lignin polymer in the plant cell walls using ToF-SIMS , 2006 .

[174]  Yi Weiming,et al.  Flash pyrolysis of agricultural residues using a plasma heated laminar entrained flow reactor , 2005 .

[175]  Martyn C. R. Symons,et al.  Chemical and Biochemical Aspects of Electron Spin Resonance Spectroscopy , 1978 .

[176]  L. K. Mudge,et al.  Fundamentals of thermochemical biomass conversion , 1985 .

[177]  P. Udén,et al.  Analytical chemistry of liquid fuel sources: tar sands, oil shale, coal, and petroleum , 1978 .

[178]  Colomba Di Blasi,et al.  Modeling chemical and physical processes of wood and biomass pyrolysis , 2008 .

[179]  John A. Weil,et al.  Electron paramagnetic resonance : elementary theory and practical applications , 1995 .

[180]  K. Lonsdale X-Ray Diffraction , 1971, Nature.

[181]  Yuji Imamura,et al.  Electron microscopic study on pyrolysis of CCA (chromium, copper and arsenic oxide)-treated wood , 2003 .

[182]  S. Bhattacharya,et al.  Thermogravimetric analysis of Thai lignite—I. pyrolysis kinetics , 1991 .

[183]  D. Meier,et al.  Studies on isolated lignins and lignins in woody materials by pyrolysis-gas chromatography-mass spectrometry and off-line pyrolysis-gas chromatography with flame ionization detection , 1987 .

[184]  T. Ozawa A New Method of Analyzing Thermogravimetric Data , 1965 .

[185]  Manuel Garcia-Perez,et al.  Vacuum pyrolysis of sugarcane bagasse , 2002 .

[186]  Pennycook,et al.  High-resolution incoherent imaging of crystals. , 1990, Physical review letters.

[187]  Michael Jerry Antal,et al.  Thermal Lag, Fusion, and the Compensation Effect during Biomass Pyrolysis† , 1996 .

[188]  Dietrich Meier,et al.  Design, Construction, and Operation of a Fast Pyrolysis Plant for Biomass , 2002 .

[189]  R. Lehrle,et al.  An improved (“thermocouple-feedback”) pyrolysis-GLC technique and its application to study polyacrylonitrile degradation kinetics , 1982 .

[190]  Barry Goodell,et al.  Use of NIR and pyrolysis-MBMS coupled with multivariate analysis for detecting the chemical changes associated with brown-rot biodegradation of spruce wood. , 2002, FEMS microbiology letters.

[191]  L. Tang,et al.  Plasma Pyrolysis of Biomass for Production of Syngas and Carbon Adsorbent , 2005 .

[192]  M. Castaldi,et al.  Syngas production via CO2 enhanced gasification of biomass fuels. , 2009 .

[193]  D. Neale,et al.  Identification of QTLs influencing wood property traits in loblolly pine (Pinus taeda L.). II. Chemical wood properties , 2000, Theoretical and Applied Genetics.

[194]  R. Evans,et al.  The formation of aromatics from the gas-phase pyrolysis of stigmasterol: kinetics , 2001 .

[195]  D. Fanter,et al.  Temperature rise time and true pyrolysis temperature in pulse mode pyrolysis gas chromatography , 1972 .

[196]  Maurice A. Bergougnou,et al.  The kinetics of vapour-phase cellulose fast pyrolysis reactions , 1994 .

[197]  Ulrich Schurr,et al.  Characterization of the water-insoluble fraction from fast pyrolysis liquids (pyrolytic lignin) Part III. Molar mass characteristics by SEC, MALDI-TOF-MS, LDI-TOF-MS, and Py-FIMS , 2006 .

[198]  Ayşe Eren Pütün,et al.  Rice straw as a bio-oil source via pyrolysis and steam pyrolysis. , 2004 .

[199]  O. Folmer,et al.  A Laser Pyrolysis Apparatus for Gas Chromatography , 1969 .

[200]  H. Hatakeyama,et al.  Thermal properties of green polymers and biocomposites , 2004 .

[201]  A. Perdih,et al.  FRACTIONATION OF SPRUCE TRICHLOROACETIC LIGNIN , 1999 .

[202]  B. V. Babu Biomass pyrolysis: a state‐of‐the‐art review , 2008 .

[203]  R. Blanken Equivalent width method for quantitative FTIR analysis of biomass pyrolysis using HITRAN database , 2008 .