Application of Zinc Oxide Varistors

This paper deals with the application of ZnO varistors—an area which has not been treated in a systematic way in the literature. The paper starts with a brief description of the fundamental properties comprising the electrical behavior as well as the physics, chemistry, and microstructure of the varistor. These properties then form the basis for defining the application parameters that are directly related to the nonlinear current-voltage characteristics of the varistor. This paper provides a detailed description of these parameters and their relation to microstructure and the processing of the varistor. Finally, a discussion is presented on the reliability of the varistor by considering a grain-boundary defect model which explains both the instability and the stability under use conditions.

[1]  R. Lindner,et al.  Die Diffusion von radioaktivem Zink in Zink-Eisen-Spinell und Zinkoxyd. , 1952 .

[2]  D. G. Thomas Interstitial zinc in zinc oxide , 1957 .

[3]  Non-stoichiometry of zinc oxide and its relation to sintering. Part 1.—Determination of non-stoichiometry in zinc oxide , 1959 .

[4]  E. L. Williams,et al.  II. Diffusion of zinc and oxygen in zinc oxide , 1959 .

[5]  M. Matsuoka Nonohmic Properties of Zinc Oxide Ceramics , 1971 .

[6]  William G. Morris,et al.  Electrical Properties of ZnO‐Bi2O3 Ceramics , 1973 .

[7]  J. Wong Nature of Intergranular Phase in Nonohmic ZnO Ceramics Containing 0.5 Mol% Bi2O3 , 1974 .

[8]  J. D. Levine Theory of varistor electronic properties , 1975 .

[9]  H. R. Philipp,et al.  The physics of metal oxide varistors , 1975 .

[10]  E. F. Koch,et al.  Nature of an intergranular thin−film phase in a highly non−Ohmic metal oxide varistor , 1975 .

[11]  J. Wong,et al.  Microstructure and phase transformation in a highly non−Ohmic metal oxide varistor ceramic , 1975 .

[12]  J. Wong,et al.  Barrier voltage measurement in metal oxide varistors , 1976 .

[13]  Effect of Heat-Treatment on Current Creep Phenomena in Nonohmic ZnO Ceramics , 1976 .

[14]  C. Yo,et al.  Study of the nonstoichiometric composition op zinc oxide , 1976 .

[15]  F. Caralp,et al.  Caractérisation chimique et étude des propriétés électroniques de l'oxyde de zinc non stoechiométrique. Nature et répartition des défauts , 1976 .

[16]  W. Morris Physical properties of the electrical barriers in varistors , 1976 .

[17]  J. Bernasconi,et al.  Zinc oxide based varistors: A possible mechanism , 1976 .

[18]  A. Iga,et al.  Effect of Phase Transition of Intergranular Bi2O3 Layer in Nonohmic ZnO Ceramics , 1976 .

[19]  P. R. Emtage,et al.  The physics of zinc oxide varistors , 1977 .

[20]  T. Gupta,et al.  Effect of externally applied pressure on zinc oxide varistors , 1977 .

[21]  D. Clarke The microstructural location of the intergranular metal‐oxide phase in a zinc oxide varistor , 1977 .

[22]  E.C. Sakshaug,et al.  A new concept in station arrester design , 1977, IEEE Transactions on Power Apparatus and Systems.

[23]  Masanori Inada,et al.  Microstructure of Nonohmic Zinc Oxide Ceramics , 1978 .

[24]  R. Einzinger Metal oxide varistor action -a homojunction breakdown mechanism , 1978 .

[25]  Kazuo Eda,et al.  Conduction mechanism of non‐Ohmic zinc oxide ceramics , 1978 .

[26]  Masanori Inada,et al.  Crystal Phases of Nonohmic Zinc Oxide Ceramics , 1978 .

[27]  L. Lou Current‐voltage characteristics of ZnO‐Bi2O3 heterojunction , 1979 .

[28]  Current Creep in Nonohmic ZnO Ceramics , 1979 .

[29]  H. Philipp,et al.  High‐temperature behavior of ZnO‐based ceramic varistors , 1979 .

[30]  T. Gupta,et al.  Microstructural evaluation of multicomponent ZnO ceramics , 1979 .

[31]  J. V. Kemenade,et al.  Direct determination of barrier voltage in ZnO varistors , 1979 .

[32]  T. Gupta,et al.  A barrier model for ZnO varistors , 1979 .

[33]  W. Paulson,et al.  The pulse‐degradation characteristic of ZnO varistors , 1979 .

[34]  W. Kingery,et al.  A Scanning Transmission Electron Microscopy Investigation of Grain‐Boundary Segregation in a ZnO‐Bi2O3 Varistor , 1979 .

[35]  H. R. Philipp,et al.  Theory of conduction in ZnO varistors , 1979 .

[36]  D. Clarke Grain‐boundary segregation in a commercial ZnO‐based varistor , 1979 .

[37]  M. Inada Formation Mechanism of Nonohmic Zinc Oxide Ceramics , 1980 .

[38]  Joe Wong,et al.  Sintering and varistor characteristics of ZnO‐Bi2O3 ceramics , 1980 .

[39]  Atsushi Iga,et al.  Degradation mechanism of non-Ohmic zinc oxide ceramics , 1980 .

[40]  P. Williams,et al.  Microstructure-property relationships of rare-earth-zinc-oxide varistors , 1980 .

[41]  S. Tominaga,et al.  Electrical Conduction of ZnO Varistors under Continuous DC Stress , 1980 .

[42]  T. Gupta,et al.  Low voltage ZnO varistor: Device process and defect model , 1980 .

[43]  Degradation of Zinc Oxide Varistors , 1981 .

[44]  G. Pike Electronic Properties of ZnO Varistors: A New Model , 1981 .

[45]  P. L. Hower,et al.  Current instability phenomena in ZnO varistors under a continuous ac stress , 1981 .

[46]  M. Reiser Current limits in linear accelerators , 1981 .

[47]  D. Hinz,et al.  Degradation phenomena of ZnO varistors , 1981 .

[48]  Y. Takada,et al.  A mechanism of degradation in leakage currents through ZnO varistors , 1982 .

[49]  T. K. Gupta,et al.  Barrier voltage and its effect on stability of ZnO varistor , 1982 .

[50]  T. Gupta,et al.  Improved varistor nonlinearity via donor impurity doping , 1982 .

[51]  A. Mizukoshi,et al.  Influence of Uniformity on Energy Absorption Capabilities of Zinc Oxide Elements as Applied in Arresters , 1983, IEEE Transactions on Power Apparatus and Systems.

[52]  60 Hz ac characteristic of ZnO varistor below breakdown voltage , 1984, Conference on Electrical Insulation & Dielectric Phenomena - Annual Report 1984.

[53]  G. Pike Semiconductor grain-boundary admittance: Theory , 1984 .

[54]  K. Eda Destruction mechanism of ZnO varistors due to high currents , 1984 .

[55]  Tapan K. Gupta,et al.  A grain-boundary defect model for instability/stability of a ZnO varistor , 1985 .

[56]  B. Hoffmann,et al.  Model experiments describing the microcontact of ZnO varistors , 1985 .

[57]  Eva Olsson,et al.  The microstructure of a ZnO varistor material , 1985 .

[58]  Y. Takada,et al.  Effects of Bismuth Sesquioxide on the Characteristics of ZnO Varistors , 1986 .

[59]  T. Gupta Influence of Microstructure and Chemistry on the Electrical Characteristic of ZnO Varistors , 1986 .

[60]  Blatter,et al.  Carrier transport through grain boundaries in semiconductors. , 1986, Physical review. B, Condensed matter.

[61]  T. Gupta,et al.  Thermal properties of pure and varistor ZnO at low temperatures , 1986 .

[62]  H. R. Philipp,et al.  Zinc oxide varistors ― a review , 1986 .

[63]  Blatter,et al.  Electrical breakdown at semiconductor grain boundaries. , 1986, Physical review. B, Condensed matter.

[64]  W. G. Carlson,et al.  A Procedure for Estimating the Lifetime of Gapless Metal Oxide Surge Arresters for AC Application , 1986, IEEE Power Engineering Review.

[65]  Eun Dong Kim,et al.  Effects of annealing on the grain boundary potential barrier of ZnO varistor , 1986 .

[66]  Richard Einzinger,et al.  Metal Oxide Varistors , 1987 .

[67]  T. Gupta Effect of material and design parameters on the life and operating voltage of a ZnO varistor , 1987 .

[68]  M. Tao,et al.  Different ‘‘single grain junctions’’ within a ZnO varistor , 1987 .

[69]  T. Asokan,et al.  Studies on microstructure and density of sintered ZnO-based non-linear resistors , 1987 .

[70]  M. Ieda,et al.  Electrical properties of ZnO-Bi2O3 thin-film varistors , 1987 .

[71]  C. F. Clark,et al.  Electrical and thermal properties of a varistor at cryogenic temperatures , 1988 .

[72]  T. Gupta,et al.  Improved stability of the ZnO varistor via donor and acceptor doping at the grain boundary , 1988 .

[73]  The deep level transient spectroscopy studies of a ZnO varistor as a function of annealing , 1988 .

[74]  K. Eda,et al.  Zinc oxide varistors , 1989, IEEE Electrical Insulation Magazine.

[75]  G. Dunlop,et al.  Characterization of individual interfacial barriers in a ZnO varistor material , 1989 .