Synthesis, structure, and properties of group 1 metal complexes containing nitrogen-rich hydrotris(tetrazolyl)borate ligands.

Nitrogen-rich hydrotris(tetrazolyl)borate salts of lithium, sodium, and potassium have been prepared for the first time by thermolysis of the borohydride ion with three equivalents of tetrazoles in ether solvents at 160-162 °C. Despite the high nitrogen contents, these complexes have low sensitivity to impact, electrostatic discharge, and friction.

[1]  G. Tao,et al.  Nitrogen-rich 5-(1-methylhydrazinyl)tetrazole and its copper and silver complexes. , 2012, Inorganic chemistry.

[2]  Magdy Bichay,et al.  DBX‐1 – A Lead Free Replacement for Lead Azide , 2011 .

[3]  T. Klapötke,et al.  The taming of CN7(-): the azidotetrazolate 2-oxide anion. , 2011, Chemistry.

[4]  J. Shreeve,et al.  Azole-based energetic salts. , 2011, Chemical reviews.

[5]  C. Winter,et al.  Complexes of the [K(18-Crown-6)]+ fragment with bis(tetrazolyl)borate ligands: unexpected boron-nitrogen bond isomerism and associated enforcement of kappa3-N,N',H-ligand chelation. , 2010, Inorganic chemistry.

[6]  T. Groshens.  Synthesis, characterization, and coordination chemistry of the dihydrobis(5-aminotetrazol-1-yl)borate anion , 2010 .

[7]  G. Tao,et al.  Energetic salts based on monoanions of N,N-bis(1H-tetrazol-5-yl)amine and 5,5'-bis(tetrazole). , 2010, Chemistry.

[8]  James C. Knight,et al.  A novel route to rhodaboratranes [Rh(CO)(PR3){B(taz)3}]+ via the redox activation of scorpionate complexes [RhLL'Tt]. , 2009, Dalton transactions.

[9]  S. Batten,et al.  Three-centre, two-electron bonds in complexes of Mn, Ni, Co and Cd with 3-(4-benzonitrile)pyrazolyl scorpionates , 2009 .

[10]  C. Winter,et al.  Volatility, high thermal stability, and low melting points in heavier alkaline earth metal complexes containing tris(pyrazolyl)borate ligands. , 2009, Inorganic chemistry.

[11]  Xian‐Ming Zhang,et al.  Spin frustration and long-range ordering in an AlB(2)-like metal-organic framework with unprecedented N,N,N-tris-tetrazol-5-yl-amine ligand. , 2009, Inorganic chemistry.

[12]  T. Klapötke,et al.  The CN7(-) anion. , 2009, Journal of the American Chemical Society.

[13]  T. Cundari,et al.  Sandwiched sodium and half-sandwiched copper carbonyl complexes featuring polyfluorinated tris(triazolyl)borate [HB(3,5-(CF(3))(2)Tz)(3)](-). , 2009, Dalton transactions.

[14]  Dong-Yao Wang,et al.  Syntheses, structures and properties of seven H2BTA coordinating 3-D metallic complexes containing 0-, 1-, 2-, and 3-D frameworks (H2BTA = bis(tetrazolyl)amine) , 2009 .

[15]  T. Klapötke,et al.  Synthesis and characterization of perfluorinated nitriles and the corresponding sodium 5-perfluoroalkyltetrazolate salts , 2008 .

[16]  Song Gao,et al.  Syntheses, structures and properties of seven isomorphous 1D Ln3+complexes Ln(BTA)(HCOO)(H2O)3 (H2BTA = bis(tetrazoly)amine, Ln = Pr, Gd, Eu, Tb, Dy, Er, Yb) and two 3D Ln3+ complexes Ln(HCOO)3 (Ln = Pr, Nd). , 2008, Dalton transactions.

[17]  C. Hamaker,et al.  Synthesis, characterization, and crystal structure of [Cu{(3,5-Ph2Pz)2BH2}2]0: Evidence of a B–H–Cu agostic interaction , 2008 .

[18]  Yan-Qin Wang,et al.  Coordination compounds of bis(5-tetrazolyl)amine with manganese(II), zinc(II) and cadmium(II): synthesis, structure and magnetic properties. , 2008, Dalton transactions.

[19]  T. Klapötke,et al.  Salts of 1H‐Tetrazole – Synthesis, Characterization and Properties , 2008 .

[20]  Xian‐Ming Zhang,et al.  Temperature Tuned Synthesis of Zinc N,N-bis-(1(2)H-tetrazol-5-yl)-amine Complexes : From Zn3O Cluster-Based 3-Connected 63-hcb and (3,6)-Connected (43)2(46)-kgd Layers to Zn5(OH)4 Chain-Based 3D Open Framework , 2008 .

[21]  Loroño-Gonzalez Dj.  Polymeric [dihydrobis(pyrazol-1-yl)borato]potassium(I) and three dihydrobis(pyrazol-1-yl)borate-magnesium(I) compounds obtained by disproportionation of the Grignard reagent. , 2008 .

[22]  T. Klapötke,et al.  Pyrotechnik mit dem “Ökosiegel”: eine chemische Herausforderung , 2008 .

[23]  Georg Steinhauser,et al.  "Green" pyrotechnics: a chemists' challenge. , 2008, Angewandte Chemie.

[24]  Song Gao,et al.  Novel frustrated magnetic lattice based on triangular [Mn3(micro3-F)] clusters with tetrazole ligands. , 2007, Chemical communications.

[25]  H. V. Rasika Dias,et al.  FLUORINATED TRIS(PYRAZOLYL)BORATES AND SILVER(I) COMPLEXES OF GROUP 14 LIGANDS , 2007 .

[26]  Alexander Gaenko,et al.  Synthesis and structure of tris(5-phenyltetrazol-1-yl)methane , 2007 .

[27]  H. Schlegel,et al.  Experimental and theoretical study of the coordination of 1,2,4-triazolato, tetrazolato, and pentazolato ligands to the [K(18-crown-6)]+ fragment. , 2006, Inorganic chemistry.

[28]  M. D. Coburn,et al.  Green primary explosives: 5-Nitrotetrazolato-N2-ferrate hierarchies , 2006, Proceedings of the National Academy of Sciences.

[29]  O. Ivashkevich,et al.  Metal derivatives of tetrazoles , 2006 .

[30]  C. Marzano,et al.  New copper(I) phosphane complexes of dihydridobis(3-nitro-1,2,4-triazolyl)borate ligand showing cytotoxic activity. , 2006, Journal of inorganic biochemistry.

[31]  J. Weigand,et al.  BTA copper complexes. , 2005, Inorganic chemistry.

[32]  B. Twamley,et al.  Energetic salts of azotetrazolate, iminobis(5-tetrazolate) and 5, 5'-bis(tetrazolate). , 2005, Chemical communications.

[33]  R. Cao,et al.  Syntheses and characterizations of Co(II) and Ni(II) complexes of dihydrobis(thioxotetrazolyl)borato with Co[S4] and Ni[S4H2] cores , 2005 .

[34]  C. Pettinari,et al.  Copper and silver derivatives of scorpionates and related ligands , 2004 .

[35]  C. Janiak,et al.  Supramolecular CH⋯O, CH⋯N and CH⋯Cl interactions in metal compounds with multi-topic poly(pyrazolyl)borate ligands , 2003 .

[36]  P. Junk,et al.  Ether and crown ether adduct complexes of sodium and potassium cyclopentadienide and methylcyclopentadienide—molecular structures of [Na(dme)Cp]∞, [K(dme)0.5Cp]∞, [Na(15-crown-5)Cp], [Na(18-crown-6)CpMe] and the “naked Cp−” complex [K(15-crown-5)2][Cp] , 2002 .

[37]  C. Slugovc,et al.  Rhodium- and iridium-trispyrazolylborate complexes , 2001 .

[38]  J. Elguero,et al.  Effects of Nitrogen Substitution in Poly(Pyrazolyl)Borato Ligands: From Orbital Energy Levels to C–H ⃛ O Hydrogen Bonding , 1996 .

[39]  M. Pender,et al.  Synthesis and characterization of dihydrobis(3,5-dimethylpyrazolyl)borate complexes of gallium(III) and indium(III) , 1996 .

[40]  H. V. Rasika Dias,et al.  Synthesis and Characterization of Copper(II), Zinc(II), and Potassium Complexes of a Highly Fluorinated Bis(pyrazolyl)borate Ligand. , 1996, Inorganic chemistry.

[41]  W. Hinrichs,et al.  Ligand‐Field Control and Hydrogen Bonding as Design Elements in the Assembly and Crystallization of Poly(azolyl)borate‐Metal Complexes: Chelate Complexes Versus Coordination Polymers and Symmetrical Versus Distorted Grid Sheets , 1995 .

[42]  C. Janiak,et al.  Transition‐Metal Complexes with the Novel Scorpionate Ligand Dihydrobis‐(tetrazolyl)borate: Synthesis and Characterization of Infinite Two‐Dimensional Metal‐Ligand Frameworks and One‐Dimensional Water Substructures , 1995 .

[43]  C. Janiak.  Clathrates and coordination polymers: new dimensions in poly(azolyl)borate chemistry with poly-(triazolyl)- and -(tetrazolyl)-borate ligands , 1994 .

[44]  S. Trofimenko.  Recent advances in poly(pyrazolyl)borate (scorpionate) chemistry , 1993 .

[45]  L. Esser,et al.  Notizen: The Bishydridobis(tetrazol-1-yl)borate Anion, [H2B(CHN4)2]-: Synthesis and Structure of the First Tetrazolylborate , 1993 .

[46]  L. Lebioda,et al.  Organometallic complexes of gallium stabilized by the dihydrobis(pyrazolyl)borate ligand , 1990 .

[47]  L. Lebioda,et al.  Mixed poly(pyrazolyl)borate-cyclopentadienyl zirconium(IV) complexes. Crystal and molecular structure of [dihydrobis(1-pyrazolyl)borato]dichloro(cyclopentadienyl)zirconium(IV) , 1986 .

[48]  L. Lebioda,et al.  Synthesis, x-ray crystal structure, and study of dynamic behavior of [dihydrobis(3,5-dimethyl-1-pyrazolyl)borato]chlorotrimethyltantalum(V), a molecule with a strong 3-center, 2-electron bond , 1983 .

[49]  S. Trofimenko.  Boron-pyrazole chemistry. IV. Carbon- and boron-substituted poly[(1-pyrazolyl) borates] , 1967 .

[50]  S. Trofimenko.  Boron-pyrazole chemistry. II. Poly(1-pyrazolyl)-borates , 1967 .