Large‐Area Freestanding Graphene Paper for Superior Thermal Management

Large-area freestanding graphene papers (GPs) are fabricated by electrospray deposition integrated with a continuous roll-to-roll process. Upon mechanical compaction and thermal annealing, GPs can achieve a thermal conductivity of as high as 1238.3-1434 W m(-1) K(-1) . The super-thermally conductive GPs display an outstanding heat-spread ability and are more efficient in removing hot spots than Cu and Al foils.

[1]  Changsheng Liu,et al.  Rapid synthesis of nitrogen-doped graphene for a lithium ion battery anode with excellent rate performance and super-long cyclic stability. , 2014, Physical chemistry chemical physics : PCCP.

[2]  Sang Bong Lee,et al.  Direct electrospray deposition of graphene onto paper and effect of binder on its surface resistance. , 2013, Journal of nanoscience and nanotechnology.

[3]  H. Chae,et al.  Electrospray deposition of carbon nanotube thin films for flexible transparent electrodes. , 2013, Journal of nanoscience and nanotechnology.

[4]  Chi Cheng,et al.  Liquid-Mediated Dense Integration of Graphene Materials for Compact Capacitive Energy Storage , 2013, Science.

[5]  Jianhui Chen,et al.  Self healing of defected graphene , 2013 .

[6]  P. Ajayan,et al.  Effect of high-temperature thermal treatment on the structure and adsorption properties of reduced graphene oxide , 2013, Carbon.

[7]  E. Pop,et al.  Thermal properties of graphene: Fundamentals and applications , 2012, 1301.6181.

[8]  L. J. Lee,et al.  High-performance nanopapers based on benzenesulfonic functionalized graphenes. , 2012, ACS nano.

[9]  Changhong Liu,et al.  High-density carbon nanotube buckypapers with superior transport and mechanical properties. , 2012, Nano letters.

[10]  M. Awais,et al.  Electrospray deposition of a graphene-oxide thin film, its characterization and investigation of its resistive switching performance , 2012 .

[11]  A. Balandin,et al.  Thermal properties of graphene and multilayer graphene: Applications in thermal interface materials , 2012 .

[12]  R. Ruoff,et al.  Thermal transport in three-dimensional foam architectures of few-layer graphene and ultrathin graphite. , 2012, Nano letters.

[13]  Huang Wu,et al.  Graphene nanoplatelet paper as a light-weight composite with excellent electrical and thermal conductivity and good gas barrier properties , 2012 .

[14]  Changsheng Liu,et al.  Flexible pillared graphene-paper electrodes for high-performance electrochemical supercapacitors. , 2012, Small.

[15]  J. Nam,et al.  Solution-Processed Graphite Membrane from Reassembled Graphene Oxide , 2012 .

[16]  Hua Zhang,et al.  Graphene-based composites. , 2012, Chemical Society reviews.

[17]  U. Pal,et al.  Effects of crystallization and dopant concentration on the emission behavior of TiO2:Eu nanophosphors , 2012, Nanoscale Research Letters.

[18]  B. Chakraborty,et al.  Molecular charge-transfer interaction with single-layer graphene , 2011 .

[19]  S. Xie,et al.  Facile Physical Route to Highly Crystalline Graphene , 2011 .

[20]  L. Brinson,et al.  Evolution of order during vacuum-assisted self-assembly of graphene oxide paper and associated polymer nanocomposites. , 2011, ACS nano.

[21]  A. Balandin.  Thermal properties of graphene and nanostructured carbon materials. , 2011, Nature materials.

[22]  L. Drzal,et al.  Electron and phonon transport in Au nanoparticle decorated graphene nanoplatelet nanostructured paper. , 2011, ACS applied materials & interfaces.

[23]  L. Drzal,et al.  Thermal conductivity of exfoliated graphite nanoplatelet paper , 2011 .

[24]  U. Waghmare,et al.  Temperature effects on the Raman spectra of graphenes: dependence on the number of layers and doping , 2011, Journal of physics. Condensed matter : an Institute of Physics journal.

[25]  Bei Wang,et al.  Advanced mechanical properties of graphene paper , 2011 .

[26]  Heeyeop Chae,et al.  A graphene sheet exfoliated with microwave irradiation and interlinked by carbon nanotubes for high-performance transparent flexible electrodes , 2010, Nanotechnology.

[27]  C. Rao,et al.  A study of the synthetic methods and properties of graphenes , 2010, Science and technology of advanced materials.

[28]  Li Shi,et al.  Two-Dimensional Phonon Transport in Supported Graphene , 2010, Science.

[29]  C. Rao,et al.  Characteristics of field-effect transistors based on undoped and B-and N-doped few-layer graphenes , 2010 .

[30]  R. Ruoff,et al.  Thin Film Fabrication and Simultaneous Anodic Reduction of Deposited Graphene Oxide Platelets by Electrophoretic Deposition , 2010 .

[31]  Samia Subrina,et al.  Dimensional crossover of thermal transport in few-layer graphene. , 2010, Nature materials.

[32]  C. N. R. Rao,et al.  NO2 and humidity sensing characteristics of few-layer graphenes , 2009, 0905.2852.

[33]  Yang Yang,et al.  Low-temperature solution processing of graphene-carbon nanotube hybrid materials for high-performance transparent conductors. , 2009, Nano letters.

[34]  Franklin Kim,et al.  Langmuir-Blodgett assembly of graphite oxide single layers. , 2009, Journal of the American Chemical Society.

[35]  H. Dai,et al.  Highly conducting graphene sheets and Langmuir-Blodgett films. , 2008, Nature nanotechnology.

[36]  A. T. Sobczyk,et al.  Electrospraying route to nanotechnology: An overview , 2008 .

[37]  Changhong Liu,et al.  Highly oriented carbon nanotube papers made of aligned carbon nanotubes , 2008, Nanotechnology.

[38]  S. Stankovich,et al.  Preparation and characterization of graphene oxide paper , 2007, Nature.

[39]  H. Chae,et al.  Graphene oxide/N-methyl-2-pyrrolidone charge-transfer complexes for molecular detection , 2013 .

[40]  Yang Yang,et al.  High-throughput solution processing of large-scale graphene. , 2009, Nature nanotechnology.

[41]  K. Müllen,et al.  Transparent, conductive graphene electrodes for dye-sensitized solar cells. , 2008, Nano letters.

[42]  A. Yoshida,et al.  Graphitization behavior of Kapton-derived carbon film related to structure, microtexture and transport properties , 1997 .

[43]  M. Inagaki,et al.  Graphite films prepared from carbonized polyimide films , 1992 .

[44]  J. Sembera,et al.  Nano Express Open Access , 2022 .