Static scattering from polyelectrolyte solutions

Etude theorique de l'intensite de diffusion statique d'un systeme constitue de polyions en pelote, de contre-ions et de co-ions. La configuration du polyion est decrite par un facteur de forme de chaine aleatoire avec une longueur de persistance et un parametre de volume exclu derives de la theorie d'Odjik. En representant les segments de polymere (monomere) comme des spheres dures chargees, on exprime les correlations entre segments de chaines differentes et ions libres en fonction de la taille et de la charge des constituants

[1]  M. Grimson,et al.  Neutron scattering from polyelectrolyte solutions , 1987 .

[2]  M. Grimson,et al.  Scattering from polyelectrolyte solutions , 1987 .

[3]  G. Jannink.  Structure factors of polyelectrolyte solutions revealed by neutron scattering , 1986 .

[4]  R. Oberthur,et al.  Radius of gyration of a polyion in salt free polyelectrolyte solutions measured by S. A. N. S. , 1985 .

[5]  J. Dalbiez,et al.  Light scattering by dilute solutions of salt-free polyelectrolytes , 1984 .

[6]  R. Koyama.  Small-angle scattering of polyelectrolyte solutions , 1984 .

[7]  M. Mandel,et al.  Scaling relations for aqueous polyelectrolyte-salt solutions. 1. Quasi-elastic light scattering as a function of polyelectrolyte concentration and molar mass , 1983 .

[8]  J. Hayter,et al.  Observation of the dynamics of polyelectrolyte strong solutions by quasi-elastic neutron scattering , 1983 .

[9]  P. Gennes,et al.  Correlations and dynamics of polyelectrolyte solutions , 1980 .

[10]  T. Odijk.  Possible Scaling Relations for Semidilute Polyelectrolyte Solutions , 1979 .

[11]  P. Gennes,et al.  Small angle neutron scattering by semi-dilute solutions of polyelectrolyte , 1979 .

[12]  J. Skolnick,et al.  Electrostatic Persistence Length of a Wormlike Polyelectrolyte , 1977 .

[13]  Rosa María Velasco,et al.  Remarks on polyelectrolyte conformation , 1976 .

[14]  L. Blum,et al.  Mean spherical model for asymmetric electrolytes , 1975 .

[15]  R. Koyama.  Light Scattering of Stiff Chain Polymers , 1973 .

[16]  J. Lebowitz,et al.  Mean Spherical Model Integral Equation for Charged Hard Spheres I. Method of Solution , 1972 .

[17]  Gerald S. Manning,et al.  Limiting Laws and Counterion Condensation in Polyelectrolyte Solutions I. Colligative Properties , 1969 .

[18]  H. Yamakawa,et al.  Excluded‐Volume Effects in Linear Polymer Chains: A Hierarchy of Differential Equations , 1967 .