Dielectric absorption in mixtures of anisole with some primary alcohols at microwave frequency

Dielectric properties of binary mixtures of anisole with methanol (MeOH), 1-propanol (1-PrOH), 1-butanol (1-BuOH) and 1-heptanol (1-HeOH) over an entire concentration range have been studied at a fixed temperature 40°C. The dielectric constant (ε′) and dielectric loss (ε″) of the binary mixtures of polar liquids have been determined at a microwave frequency of 9.1 GHz. The static dielectric permittivity (ε 0) of the liquid samples was also determined using a precision LCR meter. Determined values of static dielectric permittivity (ε 0) and dielectric permittivity (ε*) at 9.1 GHz frequency were used to evaluate relaxation time (τ) and high frequency limit dielectric permittivity (ε ∞). Dielectric parameters were interpreted in terms of molecular interaction between the anisole and alcohol molecules.

[1]  G. Parthipan,et al.  Dielectric and thermodynamic behavior of binary mixture of anisole with morpholine and aniline at different temperatures , 2008 .

[2]  P. Sivagurunathan,et al.  Dielectric Relaxation Properties of Alcohols and Acrylic Esters , 2007 .

[3]  J. Al-Kandary,et al.  Densities, viscosities, and refractive indices of binary mixtures of anisole with benzene, methylbenzene, ethylbenzene, propylbenzene, and butylbenzene at (293.15 and 303.15) K , 2006 .

[4]  P. Gawali,et al.  Dielectric studies of binary mixtures ofn-propyl alcohol and ethylenediamine , 2005 .

[5]  S. Mehrotra,et al.  TEMPERATURE DEPENDENT DIELECTRIC RELAXATION STUDY OF TETRAHYDROFURAN IN METHANOL AND ETHANOL AT MICROWAVE FREQUENCY USING TIME DOMAIN TECHNIQUE. , 1999 .

[6]  Camelia Gabriel,et al.  Dielectric parameters relevant to microwave dielectric heating , 1998 .

[7]  R. H. Fattepur,et al.  Temperature- and frequency-dependent dielectric studies of p-fluorophenylacetonitrile–methanol mixtures using time-domain reflectometry , 1995 .

[8]  P. Sakellaridis,et al.  Dielectric relaxation behaviour of some primary and secondary alcohols in heptane solutions , 1972 .

[9]  C. P. Smyth,et al.  Microwave Absorption and Molecular Structure in Liquids. LXVIII. Dielectric Behavior at 2.2-mm Wavelength and Intramolecular Motion in Five Substituted Benzenes and Cyclohexanes , 1967 .

[10]  J. Poley Ellipsoidal Molecular Shape and Dielectric Relaxation Analysis , 1954 .

[11]  D. Haynes,et al.  CV.—The dielectric constants of phenols and their ethers dissolved in benzene and m-xylene , 1905 .