A methodology for the generation and evaluation of biorefinery process chains, in order to identify the most promising biorefineries for the EU

The topic of bioenergy, biofuels and bioproducts remains at the top of the current political and research agenda. Identification of the optimum processing routes for biomass, in terms of efficiency, cost, environment and socio-economics is vital as concern grows over the remaining fossil fuel resources, climate change and energy security. It is known that the only renewable way of producing conventional hydrocarbon fuels and organic chemicals is from biomass, but the problem remains of identifying the best product mix and the most efficient way of processing biomass to products. The aim is to move Europe towards a biobased economy and it is widely accepted that biorefineries are key to this development. A methodology was required for the generation and evaluation of biorefinery process chains for converting biomass into one or more valuable products that properly considers performance, cost, environment, socio-economics and other factors that influence the commercial viability of a process. In this thesis a methodology to achieve this objective is described. The completed methodology includes process chain generation, process modelling and subsequent analysis and comparison of results in order to evaluate alternative process routes. A modular structure was chosen to allow greater flexibility and allowing the user to generate a large number of different biorefinery configurations The significance of the approach is that the methodology is defined and is thus rigorous and consistent and may be readily re-examined if circumstances change. There was the requirement for consistency in structure and use, particularly for multiple analyses. It was important that analyses could be quickly and easily carried out to consider, for example, different scales, configurations and product portfolios and so that previous outcomes could be readily reconsidered. The result of the completed methodology is the identification of the most promising biorefinery chains from those considered as part of the European Biosynergy Project.

[1]  Ye Sun,et al.  Hydrolysis of lignocellulosic materials for ethanol production: a review. , 2002, Bioresource technology.

[2]  J. A. Ramírez,et al.  Hydrolysis of sorghum straw using phosphoric acid: evaluation of furfural production. , 2007, Bioresource technology.

[3]  B. Coda,et al.  Entrained flow gasification of biomass Ash behaviour, feeding issues, system analyses , 2004 .

[4]  Robert C. Brown,et al.  Establishing the optimal sizes of different kinds of biorefineries , 2007 .

[5]  Francesco Cherubini,et al.  LCA of a biorefinery concept producing bioethanol, bioenergy, and chemicals from switchgrass , 2010 .

[6]  Michael Narodoslawsky,et al.  Sustainable processes—The challenge of the 21st century for chemical engineering , 2008 .

[7]  A. Aden,et al.  Process Design Report for Stover Feedstock: Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis for Corn Stover , 2002 .

[8]  Carlos A Cardona,et al.  Fuel ethanol production: process design trends and integration opportunities. , 2007, Bioresource technology.

[9]  James M. Douglas,et al.  Conceptual Design of Chemical Processes , 1988 .

[10]  Gail Taylor,et al.  Biofuels and the biorefinery concept , 2008 .

[11]  Christodoulos A. Floudas,et al.  Analyzing the interaction of design and control—1. A multiobjective framework and application to binary distillation synthesis , 1994 .

[12]  André Faaij,et al.  Outlook for advanced biofuels , 2006 .

[13]  Daniela Thomas,et al.  Biorefinery: Toward an industrial metabolism. , 2009, Biochimie.

[14]  Aidong Yang,et al.  On the use of systems technologies and a systematic approach for the synthesis and the design of future biorefineries , 2010, Comput. Chem. Eng..

[15]  A. Demirbas,et al.  Biorefineries: Current activities and future developments , 2009 .

[16]  Wei Yuan,et al.  A Flexible Framework for Optimal Biorefinery Product Allocation , 2007 .

[17]  Fuat E. Celik,et al.  Large‐scale gasification‐based coproduction of fuels and electricity from switchgrass , 2009 .

[18]  B. Kamm,et al.  Biorefinery – Systems , 2004 .

[19]  Hans-Jürgen Zimmermann,et al.  Multi-Criteria Analyse , 1991 .

[20]  L. Halász,et al.  Sustainable processes synthesis for renewable resources , 2005 .

[21]  A. Faaij,et al.  Ethanol from lignocellulosic biomass: techno-economic performance in short-, middle- and long-term , 2005 .

[22]  C. Igathinathane,et al.  Process engineering evaluation of ethanol production from wood through bioprocessing and chemical catalysis , 2009 .

[23]  Michael Stöcker,et al.  Biofuels and biomass-to-liquid fuels in the biorefinery: catalytic conversion of lignocellulosic biomass using porous materials. , 2008, Angewandte Chemie.

[24]  K. Ptasinski Thermodynamic efficiency of biomass gasification and biofuels conversion , 2008 .

[25]  L. Schebek,et al.  Environmental impacts of a lignocellulose feedstock biorefinery system: An assessment , 2009 .

[26]  A. Ragauskas,et al.  Enhanced enzymatic hydrolysis of spruce by alkaline pretreatment at low temperature , 2008, Biotechnology and bioengineering.

[27]  A. Faaij,et al.  Fischer–Tropsch diesel production in a well-to-wheel perspective: a carbon, energy flow and cost analysis , 2009 .

[28]  B. W. Ang,et al.  Decision analysis in energy and environmental modeling , 1995 .

[29]  Mark Laser,et al.  Fractionating recalcitrant lignocellulose at modest reaction conditions. , 2007, Biotechnology and bioengineering.

[30]  Ilias P. Tatsiopoulos,et al.  Comparative techno-economic analysis of ORC and gasification for bioenergy applications , 2009 .

[31]  J. Luciani,et al.  Technical and economical evaluation of enhanced biomass to liquid fuel processes , 2010 .

[32]  M. Balat,et al.  Main routes for the thermo-conversion of biomass into fuels and chemicals. Part 2: Gasification systems , 2009 .

[33]  Jhuma Sadhukhan,et al.  Value analysis tool for feasibility studies of biorefineries integrated with value added production , 2008 .

[34]  Danae Diakoulaki,et al.  Multi-criteria decision analysis and cost–benefit analysis of alternative scenarios for the power generation sector in Greece , 2007 .

[35]  Richard Turton,et al.  Analysis, Synthesis and Design of Chemical Processes , 2002 .

[36]  B. Dale,et al.  Environmental and economic analysis of the fully integrated biorefinery , 2009 .

[37]  Piotr Oleskowicz-Popiel,et al.  Technoeconomic analysis of biofuels: A wiki-based platform for lignocellulosic biorefineries , 2010 .

[38]  Huajiang Huang,et al.  A review of separation technologies in current and future biorefineries , 2008 .

[39]  B. Kamm,et al.  Principles of biorefineries , 2004, Applied Microbiology and Biotechnology.

[40]  M. Balat,et al.  Main routes for the thermo-conversion of biomass into fuels and chemicals. Part 1: Pyrolysis systems , 2009 .

[41]  Denny K. S. Ng,et al.  Automated targeting for the synthesis of an integrated biorefinery , 2010 .

[42]  Daniele Cocco,et al.  Energy and economic assessment of IGCC power plants integrated with DME synthesis processes , 2006 .

[43]  Hongzhang Chen,et al.  Evaluation of enzymatic hydrolysis of wheat straw pretreated by atmospheric glycerol autocatalysis , 2007 .

[44]  Andrew J. Toft,et al.  A comparison of integrated biomass to electricity systems , 1996 .

[45]  Johnathan E. Holladay,et al.  Top Value Added Chemicals From Biomass. Volume 1 - Results of Screening for Potential Candidates From Sugars and Synthesis Gas , 2004 .

[46]  A. Corma,et al.  Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering. , 2006, Chemical reviews.

[47]  Alex Goodall,et al.  The guide to expert systems , 1985 .

[48]  James Hettenhaus Biomass Commercialization and Agriculture Residue Collection , 2008 .

[49]  D. Montané,et al.  High-temperature dilute-acid hydrolysis of olive stones for furfural production , 2002 .

[50]  Ratna R. Sharma-Shivappa,et al.  Potential of Agricultural Residues and Hay for Bioethanol Production , 2007, Applied biochemistry and biotechnology.

[51]  Robert C. Brown,et al.  Comparative economics of biorefineries based on the biochemical and thermochemical platforms , 2007 .

[52]  Kevin C. Furman,et al.  A Critical Review and Annotated Bibliography for Heat Exchanger Network Synthesis in the 20th Century , 2002 .

[53]  François Maréchal,et al.  Methodology for the optimal thermo-economic, multi-objective design of thermochemical fuel production from biomass , 2009, Comput. Chem. Eng..

[54]  Rgh Prince,et al.  FUELS FROM BIOMASS , 1982 .

[55]  Nasib Qureshi,et al.  Production of butanol (a biofuel) from agricultural residues: Part I – Use of barley straw hydrolysate☆ , 2010 .

[56]  André Faaij,et al.  Production of FT transportation fuels from biomass; technical options, process analysis and optimisation, and development potential , 2004 .

[57]  Krist V. Gernaey,et al.  Biorefining: Computer aided tools for sustainable design and analysis of bioethanol production , 2009 .

[58]  K. McDonnell,et al.  An economic assessment of potential ethanol production pathways in Ireland , 2009 .

[59]  S. Adhikari,et al.  Biorefineries: Current Status, Challenges, and Future Direction , 2006 .

[60]  Christodoulos A. Floudas,et al.  For the Special Issue Honoring Professor Roy Jackson Optimization Framework for the Synthesis of Chemical Reactor Networks , 1998 .

[61]  Martin Kumar Patel,et al.  Applying distance-to-target weighing methodology to evaluate the environmental performance of bio-based energy, fuels, and materials , 2007 .

[62]  Donald L. Van Dyne,et al.  The Lignocellulosic Biorefinery‐ A Strategy for Returning to a Sustainable Source of Fuels and Industrial Organic Chemicals , 2008 .

[63]  Christodoulos A. Floudas,et al.  Heat exchanger network synthesis without decomposition , 1991 .

[64]  D. Hayes An examination of biorefining processes, catalysts and challenges , 2009 .

[65]  M. Galbe,et al.  Techno-Economic Evaluation of Bioethanol Production from Three Different Lignocellulosic Materials , 2008 .

[66]  M. Galbe,et al.  Steam pretreatment of dilute H2SO4-impregnated wheat straw and SSF with low yeast and enzyme loadings for bioethanol production. , 2008 .

[67]  Francesco Cherubini,et al.  Energy- and greenhouse gas-based LCA of biofuel and bioenergy systems: Key issues, ranges and recommendations , 2009 .

[68]  T. Foust,et al.  An economic and environmental comparison of a biochemical and a thermochemical lignocellulosic ethanol conversion processes , 2009 .

[69]  David K. Johnson,et al.  Top Value-Added Chemicals from Biomass - Volume II—Results of Screening for Potential Candidates from Biorefinery Lignin , 2007 .

[70]  Anthony V. Bridgwater,et al.  Renewable fuels and chemicals by thermal processing of biomass , 2003 .

[71]  Avelino Corma,et al.  Synergies between bio- and oil refineries for the production of fuels from biomass. , 2007, Angewandte Chemie.

[72]  John N. Saddler,et al.  An integrated model for the technical and economic evaluation of an enzymatic biomass conversion process , 1991 .

[73]  P. V. Pannirselvam,et al.  Lignocellulosic biomass fractionation: I - solvent extraction in a novel reactor , 1985, Biotechnology Letters.

[74]  R.W.R. Zwart,et al.  High efficient co-production of Fischer-Tropsch (FT) transportation fuels and Substitute Natural Gas (SNG) from biomass , 2004 .

[75]  Klaus D. Timmerhaus,et al.  Plant design and economics for chemical engineers , 1958 .

[76]  N. Qureshi,et al.  Butanol recovery from model solution/fermentation broth by pervaporation: evaluation of membrane performance , 1999 .

[77]  Ignacio Ballesteros,et al.  Ethanol production from steam-explosion pretreated wheat straw , 2006, Applied biochemistry and biotechnology.

[78]  D. Johnson,et al.  Strategic Biorefinery Analysis: Analysis of Biorefineries , 2005 .

[79]  Fabrizio Bezzo,et al.  A techno-economic comparison between two technologies for bioethanol production from lignocellulose. , 2009 .

[80]  Francesco Cherubini,et al.  The biorefinery concept: Using biomass instead of oil for producing energy and chemicals , 2010 .

[81]  A. Corma,et al.  Chemical routes for the transformation of biomass into chemicals. , 2007, Chemical reviews.

[82]  Krisztina Cziner,et al.  Multicriteria decision making in process integration , 2005 .

[83]  Miguel J. Bagajewicz,et al.  Mass/heat‐exchange network representation of distillation networks , 1992 .

[84]  Seungdo Kim,et al.  Biomass Refining Global Impact–The Biobased Economy of the 21st Century , 2008 .

[85]  Zdravko Kravanja,et al.  Challenges in sustainable integrated process synthesis and the capabilities of an MINLP process synthesizer MipSyn , 2010, Comput. Chem. Eng..

[86]  E. Georgopoulou,et al.  A multicriteria decision aid approach for energy planning problems: The case of renewable energy option , 1997 .

[87]  A. Faaij,et al.  Exploration of the possibilities for production of Fischer Tropsch liquids and power via biomass gasification , 2002 .

[88]  Robert H. Williams,et al.  Fischer-Tropsch Fuels from Coal and Biomass , 2008 .

[89]  J. F. RICHARDSON,et al.  Advances in Chemical Engineering , 1965, Nature.

[90]  S. Phillips Technoeconomic Analysis of a Lignocellulosic Biomass Indirect Gasification Process To Make Ethanol via Mixed Alcohols Synthesis , 2007 .

[91]  Cardona Alzate,et al.  Energy consumption analysis of integrated flowsheets for production of fuel ethanol from lignocellulosic biomass , 2006 .

[92]  Thore Berntsson,et al.  What is a biorefinery , 2012 .

[93]  Jiangjiang Wang,et al.  Review on multi-criteria decision analysis aid in sustainable energy decision-making , 2009 .

[94]  Shulin Chen Industrial biosystems engineering and biorefinery systems. , 2008, Sheng wu gong cheng xue bao = Chinese journal of biotechnology.

[95]  G. Gellerstedt,et al.  Steam explosion lignins; their extraction, structure and potential as feedstock for biodiesel and chemicals. , 2009, Bioresource technology.

[96]  A. Bjerre,et al.  Pretreatment of wheat straw using combined wet oxidation and alkaline hydrolysis resulting in convertible cellulose and hemicellulose , 2000, Biotechnology and bioengineering.

[97]  Carlos Romero,et al.  A multiple criteria decision making approach for electricity planning in Spain: economic versus environmental objectives , 2000, J. Oper. Res. Soc..

[98]  Warren D. Seider,et al.  Product and Process Design Principles: Synthesis, Analysis, and Evaluation , 1998 .

[99]  M. Hanna,et al.  THERMOCHEMICAL BIOMASS GASIFICATION—A REVIEW OF THE CURRENT STATUS OF THE TECHNOLOGY , 2009 .

[100]  Warren Mabee,et al.  Biorefining of softwoods using ethanol organosolv pulping: preliminary evaluation of process streams for manufacture of fuel-grade ethanol and co-products. , 2005, Biotechnology and bioengineering.

[101]  P. Claassen,et al.  Pretreatment of Miscanthus for hydrogen production by Thermotoga elfii , 2002 .

[102]  Lorenz T. Biegler,et al.  Synthesis of Optimal Chemical Reactor Networks , 1996 .

[103]  E. Koukios,et al.  Two-stage acid-catalyzed fractionation of lignocellulosic biomass in aqueous ethanol systems at low temperatures , 1995 .

[104]  M. Ramachandran,et al.  Application of multi-criteria decision making to sustainable energy planning--A review , 2004 .

[105]  A. Aden,et al.  Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass , 2007 .

[106]  R. Heijungs,et al.  Life cycle assessment An operational guide to the ISO standards , 2001 .

[107]  R. Clift,et al.  Developing a sustainability framework for the assessment of bioenergy systems , 2007 .

[108]  Ronald L. Madl,et al.  Bio-butanol vs. bio-ethanol: a technical and economic assessment for corn and switchgrass fermented by yeast or Clostridium acetobutylicum. , 2010 .

[109]  Xiao-Ning Li,et al.  Conceptual process synthesis: past and current trends , 2004 .

[110]  Stephen R. Hughes,et al.  Production of butanol (a biofuel) from agricultural residues: Part II – Use of corn stover and switchgrass hydrolysates☆ , 2010 .

[111]  C. Cardona,et al.  Trends in biotechnological production of fuel ethanol from different feedstocks. , 2008, Bioresource technology.

[112]  Wei Yuan,et al.  Optimal biorefinery product allocation by combining process and economic modeling , 2008 .

[113]  M. Fatih Demirbas,et al.  Biorefineries for biofuel upgrading: A critical review , 2009 .

[114]  John A. Heitmann,et al.  Feedstock pretreatment strategies for producing ethanol from wood, bark, and forest residues , 2008, BioResources.

[115]  David D. Hsu,et al.  Techno-economic comparison of process technologies for biochemical ethanol production from corn stover , 2010 .

[116]  T. Seager,et al.  Comparative Life Cycle Assessment of Lignocellulosic Ethanol Production: Biochemical Versus Thermochemical Conversion , 2010, Environmental management.

[117]  Huajiang Huang,et al.  Effect of biomass species and plant size on cellulosic ethanol: A comparative process and economic analysis , 2009 .

[118]  G. Zacchi,et al.  A techno-economical comparison of three processes for the production of ethanol from pine. , 1995 .

[119]  M. Balat,et al.  Progress in bioethanol processing , 2008 .

[120]  E. Løken Use of multicriteria decision analysis methods for energy planning problems , 2007 .

[121]  Jeffrey S. Tolan,et al.  Iogen's Demonstration Process for Producing Ethanol from Cellulosic Biomass , 2008 .