Enhanced CO2 binding affinity of a high-uptake rht-type metal-organic framework decorated with acylamide groups.

An rht-type metal-organic framework (MOF) prepared from M(2)(carboxylate)(4) (M = Cu, Co) paddlewheel clusters and a flexible C(3)-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO(2) uptake, an enhanced heat of adsorption, and higher selectivity toward CO(2)/N(2) in comparison with what was previously observed for an analogous MOF with alkyne groups.

[1]  Alan L. Myers,et al.  Thermodynamics of mixed‐gas adsorption , 1965 .

[2]  Frank V. Bright,et al.  Specific Intermolecular Interaction of Carbon Dioxide with Polymers , 1996 .

[3]  T. Groy,et al.  Establishing Microporosity in Open Metal−Organic Frameworks: Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate) , 1998 .

[4]  Klaus S. Lackner,et al.  A Guide to CO2 Sequestration , 2003, Science.

[5]  E. Beckman,et al.  A challenge for green chemistry: designing molecules that readily dissolve in carbon dioxide. , 2004, Chemical communications.

[6]  Michael J. Zaworotko,et al.  Suprasupermolecular Chemistry: Infinite Networks from Nanoscale Metal−Organic Building Blocks† , 2004 .

[7]  Alírio E. Rodrigues,et al.  Adsorption Equilibrium of Methane, Carbon Dioxide, and Nitrogen on Zeolite 13X at High Pressures , 2004 .

[8]  S. Himeno,et al.  High-Pressure Adsorption Equilibria of Methane and Carbon Dioxide on Several Activated Carbons , 2005 .

[9]  Colin E. Snape,et al.  CO2 capture using some fly ash-derived carbon materials , 2005 .

[10]  Sam Holloway,et al.  Underground sequestration of carbon dioxide—a viable greenhouse gas mitigation option , 2005 .

[11]  Omar M Yaghi,et al.  Effects of functionalization, catenation, and variation of the metal oxide and organic linking units on the low-pressure hydrogen adsorption properties of metal-organic frameworks. , 2006, Journal of the American Chemical Society.

[12]  Sean Parkin,et al.  A mesoporous metal-organic framework with permanent porosity. , 2006, Journal of the American Chemical Society.

[13]  Michael J Zaworotko,et al.  Bottom up synthesis that does not start at the bottom: quadruple covalent cross-linking of nanoscale faceted polyhedra. , 2007, Journal of the American Chemical Society.

[14]  Hang Xing,et al.  Unprecedented interweaving of single-helical and unequal double-helical chains into chiral metal-organic open frameworks with multiwalled tubular structures. , 2007, Chemical communications.

[15]  X. You,et al.  An unprecedented nanoporous and fluorescent supramolecular framework with an SrAl2 topology controllably synthesized from a flexible ditopic acid. , 2007, Chemical communications.

[16]  Timothy E. Fout,et al.  Advances in CO2 capture technology—The U.S. Department of Energy's Carbon Sequestration Program ☆ , 2008 .

[17]  Mohamed Eddaoudi,et al.  Supermolecular building blocks (SBBs) and crystal design: 12-connected open frameworks based on a molecular cubohemioctahedron. , 2008, Journal of the American Chemical Society.

[18]  C. Serre,et al.  High uptakes of CO2 and CH4 in mesoporous metal-organic frameworks MIL-100 and MIL-101. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[19]  Patrick Ryan,et al.  Separation of CO2 from CH4 using mixed-ligand metal-organic frameworks. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[20]  Myoung Soo Lah,et al.  A designed metal-organic framework based on a metal-organic polyhedron. , 2008, Chemical communications.

[21]  Michael J. Zaworotko,et al.  Supermolecular building blocks (SBBs) for the design and synthesis of highly porous metal-organic frameworks. , 2008, Journal of the American Chemical Society.

[22]  Liang-Shih Fan,et al.  Clean coal conversion processes – progress and challenges , 2008 .

[23]  Jun Zhang,et al.  Alkali and alkaline-earth cation exchanged chabazite zeolites for adsorption based CO2 capture , 2008 .

[24]  Bjørnar Arstad,et al.  Amine functionalised metal organic frameworks (MOFs) as adsorbents for carbon dioxide , 2008 .

[25]  Myoung Soo Lah,et al.  Large H2 storage capacity of a new polyhedron-based metal-organic framework with high thermal and hygroscopic stability. , 2009, Chemical communications.

[26]  Freek Kapteijn,et al.  An amine-functionalized MIL-53 metal-organic framework with large separation power for CO2 and CH4. , 2009, Journal of the American Chemical Society.

[27]  Xiang Lin,et al.  Exceptionally high H2 storage by a metal-organic polyhedral framework. , 2009, Chemical communications.

[28]  D. D’Alessandro,et al.  Strong CO2 binding in a water-stable, triazolate-bridged metal-organic framework functionalized with ethylenediamine. , 2009, Journal of the American Chemical Society.

[29]  Bo Wang,et al.  Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites , 2009, Proceedings of the National Academy of Sciences.

[30]  Maochun Hong,et al.  A Porous Polyhedral Metal-Organic Framework Based on Zn2(COO)3 and Zn2(COO)4 SBUs , 2009 .

[31]  G. Shimizu,et al.  An amine-functionalized metal organic framework for preferential CO(2) adsorption at low pressures. , 2009, Chemical communications.

[32]  S. Xiang,et al.  A new MOF-505 analog exhibiting high acetylene storage. , 2009, Chemical communications.

[33]  Michael J Zaworotko,et al.  Design and synthesis of metal-organic frameworks using metal-organic polyhedra as supermolecular building blocks. , 2009, Chemical Society reviews.

[34]  Omar M Yaghi,et al.  Storage of hydrogen, methane, and carbon dioxide in highly porous covalent organic frameworks for clean energy applications. , 2009, Journal of the American Chemical Society.

[35]  Dan Zhao,et al.  Stabilization of metal-organic frameworks with high surface areas by the incorporation of mesocavities with microwindows. , 2009, Journal of the American Chemical Society.

[36]  P. Feng,et al.  Multiroute synthesis of porous anionic frameworks and size-tunable extraframework organic cation-controlled gas sorption properties. , 2009, Journal of the American Chemical Society.

[37]  H. Müller,et al.  In situ synthesis of an imidazolate-4-amide-5-imidate ligand and formation of a microporous zinc-organic framework with H2- and CO2-storage ability. , 2010, Angewandte Chemie.

[38]  A. Torrisi,et al.  Functionalized MOFs for Enhanced CO2 Capture , 2010 .

[39]  Dan Zhao,et al.  An isoreticular series of metal-organic frameworks with dendritic hexacarboxylate ligands and exceptionally high gas-uptake capacity. , 2010, Angewandte Chemie.

[40]  Jihyun An,et al.  High and selective CO2 uptake in a cobalt adeninate metal-organic framework exhibiting pyrimidine- and amino-decorated pores. , 2010, Journal of the American Chemical Society.

[41]  Graham de Ruiter,et al.  Inside Cover: Sequential Logic Operations with Surface‐Confined Polypyridyl Complexes Displaying Molecular Random Access Memory Features (Angew. Chem. Int. Ed. 1/2010) , 2010 .

[42]  Jie‐Peng Zhang,et al.  Nonclassical active site for enhanced gas sorption in porous coordination polymer. , 2010, Journal of the American Chemical Society.

[43]  Randall Q. Snurr,et al.  Ultrahigh Porosity in Metal-Organic Frameworks , 2010, Science.

[44]  Hong-Cai Zhou,et al.  Gas storage in porous metal-organic frameworks for clean energy applications. , 2010, Chemical communications.

[45]  Alexander J. Blake,et al.  Metal-organic polyhedral frameworks: high h(2) adsorption capacities and neutron powder diffraction studies. , 2010, Journal of the American Chemical Society.