Influence of Soil Moisture Content on the Corrosion Behavior of X60 Steel in Different Soils

The influence of soil moisture content on the corrosion behavior of X60 steel in soils of different cities of Saudi Arabia (Riyadh, Rabigh and Jeddah) was investigated at ambient temperature (29 ± 1 ◦C) using weight loss (WL) method and various electrochemical methods [open circuit potential (OCP), potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS)]. Optical photographs for X60 steel surface at different conditions were obtained. It was found that WL data followed the power law kinetic relationship with a penetration factor (n) more than unity. The data of EOCP and Ecorr revealed that with increasing the soil moisture content, the corrosion of X60 steel becomes under cathodic control. The EIS spectra suggested two corrosion processes. One process related to the dissolution of corrosion products formed on the metal surface and the other process related to the charge transfer process at the metal/film and metal/soil interfaces. WL, PDP and EIS measurements indicated that the corrosion rate of X60 increases with increasing the moisture content of the studied soils up to critical limit (10 wt%), then it starts to decrease with further increase of moisture content. Various corrosion patterns (general, striations, general deep pitting and channel form corrosion) were detected on X60 steel surface after prolonged immersion in the studied soils at different moisture contents. At the critical moisture content, the corrosivity of the studied soils is given in the order: Jeddah > Rabigh > Riyadh. Correlation between the soils variables and the order of soils corrosivity was achieved.

[1]  P. Pernice,et al.  Steel corrosion rate in soils by a.c. and d.c. electrochemical methods , 1990 .

[2]  Cai Duo-chang INFLUENCE OF SOIL HUMIDITY ON CORROSION BEHAVIOR OF X70 STEEL IN YELLOW PEBBLE SOIL , 2007 .

[3]  Ricardo M. Souto,et al.  Origins of pitting corrosion , 2004 .

[4]  M. Pourbaix Atlas of Electrochemical Equilibria in Aqueous Solutions , 1974 .

[5]  Z. Szklarska‐Śmiałowska,et al.  Pitting Corrosion of Metals , 1986 .

[6]  Pierre R. Roberge,et al.  Corrosion Engineering: Principles and Practice , 2008 .

[7]  J. Bessone,et al.  An EIS study of aluminium barrier-type oxide films formed in different media , 1992 .

[8]  Z. Szklarska‐Śmiałowska,et al.  Pitting And Crevice Corrosion , 2004 .

[9]  John A. Beavers,et al.  Techniques for Assessment of Soil Corrosivity , 1998 .

[10]  Donavan Marney,et al.  The science of pipe corrosion: A review of the literature on the corrosion of ferrous metals in soils , 2012 .

[11]  J. M. Malo,et al.  Electrochemical Evaluation of Pipelines Materials of the Miravalles Geothermal Field in Costa Rica , 2007 .

[12]  Christian Camerlynck,et al.  LABORATORY MEASUREMENTS OF ELECTRICAL RESISTIVITY VERSUS WATER CONTENT ON SMALL SOIL CORES , 2003 .

[13]  Melvin Romanoff,et al.  Circular of the Bureau of Standards no. 579:: underground corrosion , 1957 .

[14]  Pierre R. Roberge,et al.  Handbook of Corrosion Engineering , 1999 .

[15]  J. Alamilla,et al.  Modelling steel corrosion damage in soil environment , 2009 .

[16]  C. Chu INFLUENCE OF MOISTURE CONTENT ON SOIL CORROSION BEHAVIOR OF CARBON STEEL , 2000 .

[17]  A. Ismail,et al.  Engineering behaviour of soil materials on the corrosion of mild steel , 2009 .

[18]  F. W. Hewes,et al.  Underground corrosion of water pipes in Calgary, Canada , 1987 .

[19]  Satyandra K. Gupta,et al.  The critical soil moisture content in the underground corrosion of mild steel , 1979 .

[20]  A. Al-Judaibi,et al.  Microbial analysis and surface characterization of SABIC carbon steel corrosion in soils of different moisture levels , 2013 .

[21]  K. Jüttner,et al.  Frequency response analysis of the Ag/Ag+ system: a partially active electrode approach , 1984 .

[22]  N. Palaniswamy,et al.  Kinetics of atmospheric corrosion of mild steel, zinc, galvanized iron and aluminium at 10 exposure stations in India , 2006 .

[23]  V. Lins,et al.  Corrosion Resistance of API X52 Carbon Steel in Soil Environment , 2012 .

[24]  Xiaogang Li,et al.  Characterization of corrosion products formed on the surface of carbon steel by Raman spectroscopy , 2009 .

[25]  R Baboian,et al.  Corrosion Tests and Standards: Application and Interpretation-Second Edition , 2005 .

[26]  B. A. Abd-El-Nabey,et al.  The role of acid anion on the inhibition of the acidic corrosion of steel by lupine extract , 2009 .

[27]  J. N. Murray,et al.  Influence of Moisture on Corrosion of Pipeline Steel in Soils Using In Situ Impedance Spectroscopy , 1989 .

[28]  N. D. Tomashov Theory of corrosion and protection of metals : the science of corrosion , 1966 .

[29]  Emeka Emanuel Oguzie,et al.  Monitoring the corrosion susceptibility of mild steel in varied soil textures by corrosion product count technique , 2004 .

[30]  K. Hladky,et al.  Corrosion Rates from Impedance Measurements: An Introduction , 1980 .

[31]  J. Galbraith,et al.  Update on monitoring microbial corrosion in Prudhoe Bay's produced water and seawater floods , 1987 .

[32]  P. Marcus,et al.  Corrosion Mechanisms in Theory and Practice , 1995 .

[33]  M. Norin,et al.  Corrosion of carbon steel in filling material in an urban environment , 2003 .

[34]  M. J. Wilmott,et al.  Corrosion by Soils , 2011 .

[35]  K. Cole,et al.  Dispersion and Absorption in Dielectrics I. Alternating Current Characteristics , 1941 .

[36]  Y. Katano,et al.  Predictive model for pit growth on underground pipes , 2003 .