Azeotropic phase equilibrium diagrams: a survey

Abstract An analysis of the structural properties of vapor–liquid equilibrium (VLE) diagrams provides a fundamental understanding of the thermodynamic behavior of azeotropic mixtures upon distillation. In addition to a review of well-known fundamental work on the analysis of VLE diagrams, this survey comprises less-known published results, especially from the Russian literature. Some new results are also presented for the first time.

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