A comprehensive model for sub-10 nm electron-beam patterning through the short-time and cold development

In this study, we propose a set of single-spot experiment to construct a comprehensive model of electron-beam lithography to describe the relation among the incident electrons, resist, and the development conditions such as durations and temperatures. Through the experiments, small feature can be achieved by performing a short-time development due to the high acceleration voltage and large depth of focus of electron-beam system. The singular point in the beginning of the development is also observed in our model and supported by the experimental data. In addition, we verify the characteristic region of each incident spot induced by the point spread function of the electron-beam system. We further fabricate the single line with narrow groove width by utilizing the results from single-spot experiment at low developing temperatures. The line is formed by arranging a series of incident points with a distance close to the characteristic radius. This method can eliminate the proximity effect effectively and thus the groove width is scaled down to 8 nm. By adopting the successful experience in the single line formation, dense array with narrow linewidth is also demonstrated under well suppression of the proximity effect. The minimum groove width of 9 nm with 30 nm pitch is achieved with 5 s development time at -10 °C. Finally, the exceptional capability of pattern transfer is presented due to the high aspect ratio of the resist.

[1]  M. Steinhart,et al.  Large-Scale Diffusion of Entangled Polymers along Nanochannels. , 2015, ACS macro letters.

[2]  R. Pease,et al.  Low voltage alternative for electron beam lithography , 1992 .

[3]  M. A. Mohammad,et al.  Interdependence of optimum exposure dose regimes and the kinetics of resist dissolution for electron beam nanolithography of polymethylmethacrylate , 2010 .

[4]  R. Kunz,et al.  193-nm lithography , 1995 .

[5]  K. Sarveswaran,et al.  Sub-10 nm electron beam lithography using cold development of poly(methylmethacrylate) , 2004 .

[6]  Donis G. Flagello,et al.  Benefits and limitations of immersion lithography , 2004 .

[7]  Christophe Vieu,et al.  Electron beam lithography: resolution limits and applications , 2000 .

[8]  K. Westra,et al.  Comparison between ZEP and PMMA resists for nanoscale electron beam lithography experimentally and by numerical modeling , 2011 .

[9]  J. Linnros,et al.  Controlled fabrication of silicon nanowires by electron beam lithography and electrochemical size reduction. , 2005, Nano letters.

[10]  Gary H. Bernstein,et al.  Low temperature development of PMMA for sub-10-nm electron beam lithography , 2003, 2003 Third IEEE Conference on Nanotechnology, 2003. IEEE-NANO 2003..

[11]  E. V. D. Drift,et al.  Experimental study on proximity effects in high voltage e-beam lithography , 1990 .

[12]  Masaya Notomi,et al.  Quantum Wire Fabrication by E-Beam Elithography Using High-Resolution and High-Sensitivity E-Beam Resist ZEP-520 , 1992 .

[13]  T. Chang Proximity effect in electron-beam lithography , 1975 .

[14]  Steven K. Dew,et al.  Simulation of electron beam lithography of nanostructures , 2010 .

[15]  Tadashi Inoue,et al.  Self diffusion of polymers in the concentrated regime. Part 2. Self diffusion and tracer-diffusion coefficient and viscosity of concentrated solutions of linear polystyrenes in dibutyl phthalate , 1989 .

[16]  P. G. de Gennes,et al.  Dynamics of Entangled Polymer Solutions. I. The Rouse Model , 1976 .

[17]  Jack L. Koenig,et al.  A review of polymer dissolution , 2003 .

[18]  A. Neureuther,et al.  Energy deposition and transfer in electron-beam lithography , 2001 .

[19]  Neal Lafferty,et al.  Immersion lithography fluids for high NA 193 nm lithography , 2004, SPIE Advanced Lithography.

[20]  H. Duan,et al.  Resolution limits of electron-beam lithography toward the atomic scale. , 2013, Nano letters (Print).

[21]  J. Greeneich,et al.  Time evolution of developed contours in poly‐(methyl methacrylate) electron resist , 1974 .

[22]  Mohammad Ali Mohammad,et al.  Fundamentals of Electron Beam Exposure and Development , 2012 .

[23]  J. Jacobson,et al.  Nanoscale patterning on insulating substrates by critical energy electron beam lithography. , 2006, Nano letters.

[24]  Makoto Aida,et al.  Enhanced resolution and groove-width simulation in cold development of ZEP520A , 2011 .

[25]  Z. Cui,et al.  Low-energy Electron-beam Lithography of ZEP-520 Positive Resist , 2006, 2006 1st IEEE International Conference on Nano/Micro Engineered and Molecular Systems.

[26]  R. J. Bojko,et al.  Quantitative lithographic performance of proximity correction for electron beam lithography , 1990 .

[27]  S. Decoutere,et al.  Determination of the proximity parameters in electron beam lithography using doughnut-structures , 1986 .

[28]  X. Zhu,et al.  Physical models of diffusion for polymer solutions, gels and solids , 1999 .

[29]  M. Rooks,et al.  Low stress development of poly(methylmethacrylate) for high aspect ratio structures , 2002 .

[30]  Chris A. Mack,et al.  Three-dimensional electron-beam lithography simulation , 1997, Advanced Lithography.