论文信息 - Reinvestigation of NH4[Co(H2O)6]PO4 based on single-crystal data

Reinvestigation of NH4[Co(H2O)6]PO4 based on single-crystal data

The structure of the title compound, ammonium hexaaquacobalt(II) orthophosphate, known from powder data, has been refined based on single-crystal data. The compound crystallizes in the struvite [NH4Mg(H2O)6PO4] structure type and is isotypic with the homologous nickel phase. The framework is built of NH4+, [Co(H2O)6]2+ and PO43− ions stacked in two kinds of ribbons parallel to (010). CoII atoms are well separated in the framework, with the shortest Co⋯Co distance being over 6 A.

[1] Ericka Stricklin-Parker,et al. Ann , 2005 .

[2] R. Blachnik,et al. The crystal structure of ammonium hexaaquanickel(II) phosphate , 1997 .

[3] Maria Cristina Burla,et al. SIR97: a new tool for crystal structure determination and refinement , 1999 .

[4] H. Flack,et al. On enantiomorph‐polarity estimation , 1983 .

[5] G. Stucky,et al. Structural and chemical studies of zeolite ABW type phases : Syntheses and characterizations of an ammonium zincophosphate and an ammonium beryllophosphate zeolite ABW structure , 1997 .