3-(4-Chlorophenyl)-2-methylacrylic acid

In the crystal structure of the title compound, C10H9ClO2, dimers form as a result of intermolecular O—H⋯O bonding. These dimers are linked to each other via C—H⋯O bonds, where the CH group belongs to the benzene ring and the O atom is from the carbonyl group of an adjacent molecule. There exist two intermolecular C—H⋯O hydrogen bonds, which individually form five-membered rings. There also exists a π–π interaction between the aromatic ring and its symmetry counterpart, with a centroid–centroid distance of 4.0202 (17) Å, and a C—H⋯π interaction between a methyl CH group and the aromatic ring.

[1]  Louis J. Farrugia,et al.  WinGX suite for small-molecule single-crystal crystallography , 1999 .

[2]  Raymond E. Davis,et al.  Patterns in Hydrogen Bonding: Functionality and Graph Set Analysis in Crystals , 1995 .

[3]  D Kromhout,et al.  Flavonoid intake and long-term risk of coronary heart disease and cancer in the seven countries study. , 1995, Archives of internal medicine.

[4]  Anthony L. Spek,et al.  Journal of , 1993 .

[5]  良二 上田 J. Appl. Cryst.の発刊に際して , 1970 .

[6]  Zia-ur-Rehman,et al.  2-Methyl-3-(3-methylphenyl)acrylic acid , 2008, Acta crystallographica. Section E, Structure reports online.

[7]  M. Nawaz Tahir,et al.  (E)-2-(2-Fluorobenzylidene)butanoic acid , 2008, Acta crystallographica. Section E, Structure reports online.

[8]  L Bravo,et al.  Polyphenols: chemistry, dietary sources, metabolism, and nutritional significance. , 2009, Nutrition reviews.

[9]  G. Sheldrick A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[10]  王晓燕 Arch Intern Med:住院增加老年人出院后骨折危险 , 2009 .

[11]  Louis J. Farrugia,et al.  ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) , 1997 .

[12]  S. Burt,et al.  Essential oils: their antibacterial properties and potential applications in foods--a review. , 2004, International journal of food microbiology.

[13]  M. Nawaz Tahir,et al.  Bis[2-(3-chlorobenzylidene)propanoato-κ2 O,O′]diethyltin(IV) , 2008, Acta crystallographica. Section E, Structure reports online.

[14]  Zia-ur-Rehman,et al.  catena-Poly[[trimethyltin(IV)]-μ-[(E)-2-methyl-3-(3-methylphenyl)acrylato-κ2 O:O′]] , 2008, Acta crystallographica. Section E, Structure reports online.