Treatment of Restaurant Wastewater by Pilot-Scale Electrocoagulation-Electroflotation: Optimization of Operating Conditions

AbstractIn the present study, restaurant wastewater containing high concentrations of chemical oxygen demand (COD), total suspended solids (TSS), and oil and grease (OG) was treated by the combined electrocoagulation-electroflotation (EC-EF) process on a pilot scale. A central composite design was applied to the experiment design and the response surface methodology was adopted to build the response surface models of effluent COD, TSS, and OG. The sequential quadratic programming method was utilized to optimize the operating conditions of the treatment process. The analysis of variance of the experimental data shows that the coefficients of determination of the response surface models of effluent COD, TSS, and OG were 0.98, 0.982, and 0.989, respectively. The validity of these models was tested by confirmation experiments with satisfactory results. Zero trade effluent surcharges were achieved under optimized operating conditions. In spite of the operating cost calculated with respects to energy, electrode...

[1]  Mohammad Y A Mollah,et al.  Fundamentals, present and future perspectives of electrocoagulation. , 2004, Journal of hazardous materials.

[2]  Douglas C. Montgomery,et al.  Response Surface Methodology: Process and Product Optimization Using Designed Experiments , 1995 .

[3]  N. Brandon,et al.  Laboratory study of electro-coagulation-flotation for water treatment. , 2002, Water research.

[4]  K. Rajeshwar,et al.  Electrochemistry and the environment , 1994 .

[5]  Guohua Chen Electrochemical technologies in wastewater treatment , 2004 .

[6]  R. H. Myers Generalized Linear Models: With Applications in Engineering and the Sciences , 2001 .

[7]  L. Dijk,et al.  Membrane bioreactors for wastewater treatment: The state of the art and new developments , 1997 .

[8]  Douglas C. Montgomery,et al.  Generalized Linear Models: With Applications in Engineering and the Sciences: Second Edition , 2012 .

[9]  A. S. Koparal,et al.  Removal of nitrate from water by electroreduction and electrocoagulation. , 2002, Journal of hazardous materials.

[10]  Belkacem Merzouk,et al.  Using electrocoagulation–electroflotation technology to treat synthetic solution and textile wastewater, two case studies , 2010 .

[11]  R. H. Myers,et al.  Response Surface Methodology: Process and Product Optimization Using Designed Experiments , 1995 .

[12]  Po Lock Yue,et al.  Electrocoagulation and Electroflotation of Restaurant Wastewater , 2000 .

[13]  Jiuhui Qu,et al.  New bipolar electrocoagulation–electroflotation process for the treatment of laundry wastewater , 2004 .

[14]  Mahmut Bayramoglu,et al.  Optimization of Electrocoagulation Process for the Treatment of Metal Cutting Wastewaters with Response Surface Methodology , 2011 .

[15]  Guohua Chen,et al.  Separation of pollutants from restaurant wastewater by electrocoagulation , 2000 .

[16]  Guohua Chen,et al.  Combined electrocoagulation and electroflotation for removal of fluoride from drinking water. , 2008, Journal of hazardous materials.

[17]  M. Tir,et al.  Coupling flocculation with electroflotation for waste oil/water emulsion treatment. Optimization of the operating conditions , 2004 .

[18]  Z. Al-Hamouz,et al.  Ground water coagulation using soluble stainless steel electrodes , 2002 .

[19]  Karen A. F. Copeland Design and Analysis of Experiments, 5th Ed. , 2001 .

[20]  M. Gómez-García,et al.  Treatment of automotive industry oily wastewater by electrocoagulation: statistical optimization of the operational parameters. , 2009, Water science and technology : a journal of the International Association on Water Pollution Research.

[21]  Yung-Tse Hung,et al.  Electrocoagulation in Wastewater Treatment , 2011 .

[22]  Bahadir K Körbahti Response surface optimization of electrochemical treatment of textile dye wastewater. , 2007, Journal of hazardous materials.

[23]  Xinhua Xu,et al.  Treatment of refectory oily wastewater by electro-coagulation process. , 2004, Chemosphere.

[24]  Philip E. Gill,et al.  Practical optimization , 1981 .

[25]  M. J. D. Powell,et al.  A fast algorithm for nonlinearly constrained optimization calculations , 1978 .

[26]  M. Feki,et al.  Behavior of aluminum electrodes in electrocoagulation process. , 2008, Journal of hazardous materials.

[27]  S Prabhakar,et al.  Separation of pollutants from tannery effluents by electro flotation , 2004 .

[28]  M. Ongwandee,et al.  Optimizing electrocoagulation process for the treatment of biodiesel wastewater using response surface methodology. , 2009, Journal of environmental sciences.

[29]  S. Lo,et al.  Treating chemical mechanical polishing (CMP) wastewater by electro-coagulation-flotation process with surfactant. , 2005, Journal of hazardous materials.

[30]  Ashraf Y. Hosny,et al.  Separating oil from oil-water emulsions by electroflotation technique , 1996 .

[31]  Robert L. Mason,et al.  Statistical Design and Analysis of Experiments , 2003 .

[32]  Muttucumaru Sivakumar,et al.  Review of pollutants removed by electrocoagulation and electrocoagulation/flotation processes. , 2009, Journal of environmental management.

[33]  F. Vahabzadeh,et al.  Application of the central composite design and response surface methodology to the advanced treatment of olive oil processing wastewater using Fenton's peroxidation. , 2005, Journal of hazardous materials.

[34]  Y. Kuo,et al.  Removal of COD from laundry wastewater by electrocoagulation/electroflotation. , 2009, Journal of hazardous materials.

[35]  Guohua Chen,et al.  Removal of chromium(VI) from wastewater by combined electrocoagulation–electroflotation without a filter , 2005 .

[36]  Guohua Chen,et al.  Investigation on the electrolysis voltage of electrocoagulation , 2002 .

[37]  D. Hadjiev,et al.  Electrocoagulation-electroflotation as a surface water treatment for industrial uses , 2010 .

[38]  C. Vial,et al.  Defluoridation of drinking water by electrocoagulation/electroflotation in a stirred tank reactor with a comparative performance to an external-loop airlift reactor. , 2009, Journal of hazardous materials.

[39]  Genichi Taguchi System Of Experimental Design: Engineering Methods To Optimize Quality And Minimize Costs , 1987 .

[40]  M. J. D. Powell,et al.  Variable Metric Methods for Constrained Optimization , 1982, ISMP.

[41]  N. Balasubramanian,et al.  Arsenic Removal from Industrial Effluent through Electrocoagulation , 2001 .

[42]  Richard J. Cleary,et al.  Statistical Methods for Engineers , 1999 .

[43]  Geoffrey W Barton,et al.  The future for electrocoagulation as a localised water treatment technology. , 2005, Chemosphere.

[44]  F. N. B. Nahui,et al.  Electroflotation of emulsified oil in industrial wastes evaluated with a full factorial design , 2008 .

[45]  Ashwani Kumar Thukral,et al.  Electrocoagulation removal of Cr(VI) from simulated wastewater using response surface methodology. , 2009, Journal of hazardous materials.

[46]  K. Schittkowski NLPQL: A fortran subroutine solving constrained nonlinear programming problems , 1986 .

[47]  Guohua Chen,et al.  Novel electrode system for electroflotation of wastewater. , 2002, Environmental science & technology.

[48]  P. Mohammad,et al.  Application of response surface methodology for optimization of important parameters in decolorizing treated distillery wastewater using Aspergillus fumigatus UB2 60 , 2006 .

[49]  M. I. Toral,et al.  Optimization of the electrocoagulation process for the removal of copper, lead and cadmium in natural waters and simulated wastewater. , 2006, Journal of environmental management.

[50]  B. Bowerman Statistical Design and Analysis of Experiments, with Applications to Engineering and Science , 1989 .

[51]  R. Fletcher Practical Methods of Optimization , 1988 .

[52]  P. Aravinthan,et al.  Removal of hydroquinone from water by electrocoagulation using flow cell and optimization by response surface methodology , 2010, Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering.

[53]  Tuğba Ölmez,et al.  The optimization of Cr(VI) reduction and removal by electrocoagulation using response surface methodology. , 2009 .

[54]  N. Moulai-Mostefa,et al.  Optimization of oil removal from oily wastewater by electrocoagulation using response surface method. , 2008, Journal of hazardous materials.

[55]  M. J. D. Powell,et al.  THE CONVERGENCE OF VARIABLE METRIC METHODS FOR NONLINEARLY CONSTRAINED OPTIMIZATION CALCULATIONS , 1978 .

[56]  R. R. Renk,et al.  Electrocoagulation of tar sand and oil shale wastewaters , 1988 .

[57]  Klaus Schittkowski,et al.  A comparative performance evaluation of 27 nonlinear programming codes , 1983, Computing.

[58]  Christos Comninellis,et al.  Oxidation of organics by intermediates of water discharge on IrO2 and synthetic diamond anodes , 1999 .

[59]  Shih-Ping Han A globally convergent method for nonlinear programming , 1975 .