Screen Printing Carbon Nanotubes Textiles Antennas for Smart Wearables

Electronic textiles have become a dynamic research field in recent decades, attracting attention to smart wearables to develop and integrate electronic devices onto clothing. Combining traditional screen-printing techniques with novel nanocarbon-based inks offers seamless integration of flexible and conformal antenna patterns onto fabric substrates with a minimum weight penalty and haptic disruption. In this study, two different fabric-based antenna designs called PICA and LOOP were fabricated through a scalable screen-printing process by tuning the conductive ink formulations accompanied by cellulose nanocrystals. The printing process was controlled and monitored by revealing the relationship between the textiles’ nature and conducting nano-ink. The fabric prototypes were tested in dynamic environments mimicking complex real-life situations, such as being in proximity to a human body, and being affected by wrinkling, bending, and fabric care such as washing or ironing. Both computational and experimental on-and-off-body antenna gain results acknowledged the potential of tunable material systems complimenting traditional printing techniques for smart sensing technology as a plausible pathway for future wearables.

[1]  P.S. Hall,et al.  Comparison between two different antennas for UWB on-body propagation measurements , 2005, IEEE Antennas and Wireless Propagation Letters.

[2]  Siti Nor Hafizah Sa'don,et al.  A 5G graphene antenna produced by screen printing method , 2019, Indonesian Journal of Electrical Engineering and Computer Science.

[3]  K. Umemura,et al.  A Review of Applications Using Mixed Materials of Cellulose, Nanocellulose and Carbon Nanotubes , 2020, Nanomaterials.

[4]  Shuo Chen,et al.  Layer-by-layer assembly of all carbon nanotube ultrathin films for electrochemical applications. , 2009, Journal of the American Chemical Society.

[5]  Xin Wang,et al.  Direct dip-coating of carbon nanotubes onto polydopamine-templated cotton fabrics for wearable applications , 2019, Cellulose.

[6]  Mohamed Basel Bazbouz,et al.  Double-Walled Carbon Nanotubes Ink for High-Conductivity Flexible Electrodes , 2020 .

[7]  Dragoljub Novaković,et al.  THE INFLUENCE OF WASHING TREATMENT ON SCREEN PRINTED TEXTILE SUBSTRATES YIKAMA İŞLEMİNİN ŞABLON BASKILI TEKSTİL MALZEMELERİNE ETKİSİ , 2014 .

[8]  K. Novoselov,et al.  All Inkjet-Printed Graphene-Silver Composite Ink on Textiles for Highly Conductive Wearable Electronics Applications , 2019, Scientific Reports.

[9]  P. Avouris,et al.  Carbon-based electronics. , 2007, Nature nanotechnology.

[10]  Rita Faddoul,et al.  Formulation and screen printing of water based conductive flake silver pastes onto green ceramic tapes for electronic applications , 2012 .

[11]  B. Cathala,et al.  Highly Efficient and Predictable Noncovalent Dispersion of Single-Walled and Multi-Walled Carbon Nanotubes by Cellulose Nanocrystals , 2016 .

[12]  Nadia Grossiord,et al.  Controlling the dispersion of multi-wall carbon nanotubes in aqueous surfactant solution , 2007 .

[14]  Haitao Wang,et al.  Binder-free carbon nanotube electrode for electrochemical removal of chromium. , 2014, ACS applied materials & interfaces.

[15]  M. Nedil,et al.  CNT-RFID passive tag antenna for gas sensing in underground mine , 2015, 2015 IEEE International Symposium on Antennas and Propagation & USNC/URSI National Radio Science Meeting.

[16]  Zhaowei Zhong,et al.  A study of screen printing of stretchable circuits on polyurethane substrates , 2019 .

[17]  Dries Vande Ginste,et al.  Stability and Efficiency of Screen-Printed Wearable and Washable Antennas , 2012, IEEE Antennas and Wireless Propagation Letters.

[18]  Robert Weigel,et al.  Microwave electronics , 2003 .

[19]  K. Oh,et al.  Fabrication of for , 2014 .

[20]  Jo Anne Shatkin,et al.  Current characterization methods for cellulose nanomaterials. , 2018, Chemical Society reviews.

[21]  Amin Shahsavar,et al.  An experimental investigation for study the rheological behavior of water–carbon nanotube/magnetite nanofluid subjected to a magnetic field , 2019, Physica A: Statistical Mechanics and its Applications.

[22]  Kenneth J. Loh,et al.  Wearable carbon nanotube-based fabric sensors for monitoring human physiological performance , 2017 .

[23]  Nikolay Atanasov,et al.  Small Antennas for Wearable Sensor Networks: Impact of the Electromagnetic Properties of the Textiles on Antenna Performance , 2020, Sensors.

[24]  K. Moon,et al.  Rheological properties and screen printability of UV curable conductive ink for flexible and washable E-textiles , 2021 .

[25]  Vijay K. Varadan,et al.  Wearable Wireless Cardiovascular Monitoring Using Textile-Based Nanosensor and Nanomaterial Systems , 2014 .

[26]  K. N. Al-Milaji,et al.  Inkjet Printing of Silver Nanowires for Stretchable Heaters , 2018, ACS Applied Nano Materials.

[27]  Zhong Lin Wang,et al.  Screen-Printed Washable Electronic Textiles as Self-Powered Touch/Gesture Tribo-Sensors for Intelligent Human-Machine Interaction. , 2018, ACS nano.

[28]  C. Kocabas,et al.  Graphene-based soft wearable antennas , 2020, Applied Materials Today.

[29]  Qi Zhang,et al.  Synthesis of silver nano particles and fabrication of aqueous Ag inks for inkjet printing , 2011 .

[30]  Mahmoud Wagih,et al.  Overcoming the Efficiency Barrier of Textile Antennas: A Transmission Lines Approach , 2019 .

[31]  Yong Zhu,et al.  Printing Conductive Nanomaterials for Flexible and Stretchable Electronics: A Review of Materials, Processes, and Applications , 2019, Advanced Materials Technologies.

[32]  H. A. Wheeler The Radiansphere around a Small Antenna , 1959, Proceedings of the IRE.

[33]  R. Farnood,et al.  Poly(3,4-ethylenedioxythiophene):Poly(styrene sulfonate) Inkjet Inks Doped with Carbon Nanotubes and a Polar Solvent: The Effect of Formulation and Adhesion on Conductivity , 2010 .

[34]  Bin Li,et al.  CNT-based conformal antenna design suitable for inkjet printing , 2017, 2017 International Applied Computational Electromagnetics Society Symposium (ACES).

[35]  Ashlie Martini,et al.  Cellulose nanomaterials review: structure, properties and nanocomposites. , 2011, Chemical Society reviews.

[36]  Ya‐Ping Sun,et al.  Advances in Bioapplications of Carbon Nanotubes , 2009 .

[37]  Xiao Dong Chen,et al.  Study of CPW-fed circular disc monopole antenna for ultra wideband applications , 2005 .

[38]  S. Mall,et al.  Time-dependent electrical properties of carbon nanotube yarns , 2015 .

[39]  M. T. Myint,et al.  Development and Improvement of Carbon Nanotube-Based Ammonia Gas Sensors Using Ink-Jet Printed Interdigitated Electrodes , 2013, IEEE Transactions on Nanotechnology.

[40]  H. Shahariar,et al.  Fabrication of low cost and scalable carbon-based conductive ink for E-textile applications , 2019, Materials Today Communications.

[41]  H. T. Nagle,et al.  Utility of nonwovens in the production of integrated electrical circuits via printing conductive inks , 2008 .

[42]  R. H. Johnston,et al.  An improved small antenna radiation-efficiency measurement method , 1998 .

[43]  Zhenan Bao,et al.  Electronic Skin: Recent Progress and Future Prospects for Skin‐Attachable Devices for Health Monitoring, Robotics, and Prosthetics , 2019, Advanced materials.

[44]  Paolo Lugli,et al.  Fabrication of carbon nanotube thin films on flexible substrates by spray deposition and transfer printing , 2013 .

[45]  N. Brandon,et al.  Screen-printing inks for the fabrication of solid oxide fuel cell films: A review , 2017 .

[46]  Majid Baniadam,et al.  Inkjet printing of carbon nanotubes (CNTs) with a binary surfactant mixture: The effect of the nonionic surfactant on the uniformity of the printed surface , 2019 .

[47]  D. Beamish Coating thickness measurement , 1971 .

[48]  U. Hashim,et al.  A CPW-fed 2.45 GHz wearable antenna using conductive nanomaterials for on-body applications , 2014, 2014 IEEE REGION 10 SYMPOSIUM.

[49]  P. Serra,et al.  Laser-induced forward transfer of conductive screen-printing inks , 2020 .

[50]  W. Tseng,et al.  Dispersion and rheology of nickel nanoparticle inks , 2006 .

[51]  Mohammed M. Bait-Suwailam,et al.  Impedance Enhancement of Textile Grounded Loop Antenna Using High-Impedance Surface (HIS) for Healthcare Applications , 2020, Sensors.

[52]  Tutku Karacolak,et al.  Flexible Antennas: A Review , 2020, Micromachines.

[53]  Matteo Pasquali,et al.  Influence of Carbon Nanotube Characteristics on Macroscopic Fiber Properties. , 2017, ACS applied materials & interfaces.

[54]  Jacek Leśnikowski Dielectric permittivity measurement methods of textile substrate of textile transmission lines , 2012 .

[55]  H. Raissi,et al.  Solvent effects on the stability and the electronic properties of histidine/Pd-doped single-walled carbon nanotube biosensor , 2016 .

[56]  K. Novoselov,et al.  Scalable Production of Graphene-Based Wearable E-Textiles , 2017, ACS nano.

[57]  K. P. Surendran,et al.  Screen printable MWCNT inks for printed electronics , 2017 .

[58]  C. W. Trueman,et al.  Carbon Nanotube Composites for Wideband Millimeter-Wave Antenna Applications , 2011, IEEE Transactions on Antennas and Propagation.

[59]  Elif Ozden Yenigun,et al.  Electrically conductive high-performance thermoplastic filaments for fused filament fabrication , 2020 .

[60]  Zhi-gang Shen,et al.  Highly conductive graphene/carbon black screen printing inks for flexible electronics. , 2020, Journal of colloid and interface science.

[61]  W.E. McKinzie,et al.  A modified Wheeler cap method for measuring antenna efficiency , 1997, IEEE Antennas and Propagation Society International Symposium 1997. Digest.

[62]  H. Boyen,et al.  Inkjet Printing of PEDOT:PSS Based Conductive Patterns for 3D Forming Applications , 2020, Polymers.

[63]  S. Sharma,et al.  Carbon nanotubes: synthesis, properties and engineering applications , 2019, Carbon Letters.

[64]  C. Kitchens,et al.  Carbon Nanotube and Cellulose Nanocrystal Hybrid Films , 2019, Molecules.

[65]  Shahid M Ali,et al.  Recent Advances of Wearable Antennas in Materials, Fabrication Methods, Designs, and Their Applications: State-of-the-Art , 2020, Micromachines.

[66]  Tomi Tuomaala,et al.  Basics of screen printing for printable and flexible electronics. Video , 2019 .

[67]  V. Kothari,et al.  Moisture management properties of plated knit structures with varying fiber types , 2015 .

[68]  Atif Shamim,et al.  A Reconfigurable Inkjet-Printed Antenna on Paper Substrate for Wireless Applications , 2018, IEEE Antennas and Wireless Propagation Letters.

[69]  Ian Oppermann,et al.  UWB theory and applications , 2004 .

[70]  Akram Alomainy,et al.  Dielectric Characterization of Non-Conductive Fabrics for Temperature Sensing through Resonating Antenna Structures , 2020, Materials.

[71]  T. Shi,et al.  Conductivity and foldability enhancement of Ag patterns formed by PVAc modified Ag complex inks with low-temperature and rapid sintering , 2020 .

[72]  Q. Pei,et al.  A Water‐Based Silver‐Nanowire Screen‐Print Ink for the Fabrication of Stretchable Conductors and Wearable Thin‐Film Transistors , 2016, Advanced materials.

[73]  J. Yeo,et al.  Highly Stretchable and Reliable, Transparent and Conductive Entangled Graphene Mesh Networks , 2018, Advanced materials.

[74]  M. Fuhrer,et al.  Properties and applications of high-mobility semiconducting nanotubes , 2004 .

[75]  F. Chinesta,et al.  A review of the microstructure and rheology of carbon nanotube suspensions , 2008 .

[76]  S. Ramakrishna,et al.  A review on inkjet printing of CNT composites for smart applications , 2017 .

[77]  G.E. Bridges,et al.  RF Cavity Passive Wireless Sensors With Time-Domain Gating-Based Interrogation for SHM of Civil Structures , 2009, IEEE Sensors Journal.

[78]  A. Rajabpour,et al.  Viscosity of carbon nanotube/water nanofluid , 2018, Journal of Thermal Analysis and Calorimetry.

[79]  W. Yeo,et al.  Advances in Screen Printing of Conductive Nanomaterials for Stretchable Electronics , 2021, ACS omega.

[80]  Ki-Bum Kim,et al.  Sheet Resistance Analysis of Interface-Engineered Multilayer Graphene: Mobility vs. Sheet Carrier Concentration. , 2020, ACS applied materials & interfaces.

[81]  Xueni Hou,et al.  Reactive ink formulated with various alcohols for improved properties and printing quality onto cotton fabrics , 2019, Journal of Engineered Fibers and Fabrics.

[82]  Takao Someya,et al.  Printable elastic conductors with a high conductivity for electronic textile applications , 2015, Nature Communications.

[83]  Jiyong Hu,et al.  A UV Curable Conductive Ink for the Fabrication of Textile-based Conductive Circuits and Wearable UHF RFID Tags. , 2019, ACS applied materials & interfaces.

[84]  B. Hwang,et al.  Printability of the Screen-Printed Strain Sensor with Carbon Black/Silver Paste for Sensitive Wearable Electronics , 2020, Applied Sciences.

[85]  Zhanhu Guo,et al.  Constructing fully carbon-based fillers with a hierarchical structure to fabricate highly thermally conductive polyimide nanocomposites , 2019, Journal of Materials Chemistry C.

[86]  Chuck Zhang,et al.  Effects of surfactants and alignment on the physical properties of single-walled carbon nanotube buckypaper , 2009 .

[87]  N. Dutta,et al.  Graphene inks for printed flexible electronics: Graphene dispersions, ink formulations, printing techniques and applications. , 2018, Advances in colloid and interface science.

[88]  S. Shariatnia,et al.  Hybrid Cellulose Nanocrystal-Bonded Carbon Nanotubes/Carbon Fiber Polymer Composites for Structural Applications , 2020 .

[89]  Christian J. Long,et al.  Carbon nanotube thin film patch antennas for wireless communications , 2019, Applied Physics Letters.

[90]  O. Chauvet,et al.  Cellulose nanocrystal-assisted dispersion of luminescent single-walled carbon nanotubes for layer-by-layer assembled hybrid thin films. , 2012, Langmuir : the ACS journal of surfaces and colloids.

[91]  Wenlong Yang,et al.  A green method for synthesizing novel nanoparticles and their application in flexible conductive patterns , 2020 .