Fabrication of surface plasmon waveguides and devices in Cytop with integrated microfluidic channels

Long range surface plasmon-polariton waveguides and devices suitable for biosensing were fabricated and characterized physically and optically. The structures consist of thin (∼35 nm) patterned Au stripes embedded in thick Cytop claddings (∼8 μm each). Portions of Au stripes were exposed by patterning and etching though the top Cytop cladding using an O2 plasma etch. The etched Cytop cavities act as microfluidic channels to contain and direct the sensing fluid. Intermediate process steps were verified through physical characterization as were fully fabricated structures. Optical testing was performed on Cytop-embedded structures and on channel-filled (with sensing fluid) structures. The structures were excited through end-fire coupling to optical fibers.Long range surface plasmon-polariton waveguides and devices suitable for biosensing were fabricated and characterized physically and optically. The structures consist of thin (∼35 nm) patterned Au stripes embedded in thick Cytop claddings (∼8 μm each). Portions of Au stripes were exposed by patterning and etching though the top Cytop cladding using an O2 plasma etch. The etched Cytop cavities act as microfluidic channels to contain and direct the sensing fluid. Intermediate process steps were verified through physical characterization as were fully fabricated structures. Optical testing was performed on Cytop-embedded structures and on channel-filled (with sensing fluid) structures. The structures were excited through end-fire coupling to optical fibers.

[1]  A. Otto Excitation of nonradiative surface plasma waves in silver by the method of frustrated total reflection , 1968 .

[2]  Jung Jin Ju,et al.  Low-Loss Polymer-Based Long-Range Surface Plasmon-Polariton Waveguide , 2007, IEEE Photonics Technology Letters.

[3]  M. Ishida,et al.  A novel deposition technique for fluorocarbon films and its applications for bulk- and surface-micromachined devices , 1998 .

[4]  P. Berini Long-range surface plasmon polaritons , 2009 .

[5]  P. Berini,et al.  Fabrication of surface plasmon waveguides on thin CYTOP membranes , 2009 .

[6]  W. Knoll,et al.  Long range surface plasmon fluorescence spectroscopy , 2006 .

[7]  Broadside excitation of surface plasmon waveguides on Cytop , 2009 .

[8]  W. Barnes,et al.  Surface plasmon subwavelength optics , 2003, Nature.

[9]  Pierre Berini,et al.  Characterization of long-range surface-plasmon-polariton waveguides , 2005 .

[10]  Burke,et al.  Surface-polariton-like waves guided by thin, lossy metal films. , 1986, Physical review. B, Condensed matter.

[11]  P. Berini,et al.  Long-range surface plasmons on ultrathin membranes. , 2007, Nano letters.

[12]  P. Berini Bulk and surface sensitivities of surface plasmon waveguides , 2008 .

[13]  P. Berini,et al.  Passive integrated optics elements based on long-range surface plasmon polaritons , 2006, Journal of Lightwave Technology.

[14]  Pierre Berini,et al.  Long-range surface plasmon-polariton mode cutoff and radiation in embedded strip waveguides , 2006 .

[15]  Magnus Malmqvist,et al.  Biospecific interaction analysis using biosensor technology , 1993, Nature.

[16]  William L. Barnes,et al.  REVIEW ARTICLE: Surface plasmon polariton length scales: a route to sub-wavelength optics , 2006 .

[17]  Pierre Berini,et al.  Demonstration of surface sensing using long-range surface plasmon waveguides on silica , 2008 .

[18]  P. Berini Air gaps in metal stripe waveguides supporting long-range surface plasmon polaritons , 2007 .

[19]  K. Kjaer,et al.  Integrated optical components utilizing long-range surface plasmon polaritons , 2005, Journal of Lightwave Technology.

[20]  V. Konopsky,et al.  Long-range plasmons in lossy metal films on photonic crystal surfaces. , 2009, Optics letters.

[21]  E. Kretschmann Die Bestimmung optischer Konstanten von Metallen durch Anregung von Oberflächenplasmaschwingungen , 1971 .

[22]  Sergey I. Bozhevolnyi,et al.  Polymer-based surface-plasmon-polariton stripe waveguides at telecommunication wavelengths , 2003 .

[23]  C. Callender,et al.  Long-range surface plasmon polariton waveguides embedded in fluorinated polymer. , 2008, Applied optics.

[24]  J. Homola Surface plasmon resonance sensors for detection of chemical and biological species. , 2008, Chemical reviews.

[25]  Radan Slavik,et al.  Ultrahigh resolution long range surface plasmon-based sensor , 2007 .

[26]  D. Sarid Long-Range Surface-Plasma Waves on Very Thin Metal Films , 1981 .

[27]  David R. Smith,et al.  Directional coupling between dielectric and long-range plasmon waveguides , 2009 .

[28]  P. Berini Plasmon-polariton waves guided by thin lossy metal films of finite width: Bound modes of asymmetric structures , 2000 .

[29]  Kristjan Leosson,et al.  Fabrication of planar polymer waveguides for evanescent-wave sensing in aqueous environments , 2010 .

[30]  Seng-Tiong Ho,et al.  Polymer waveguides useful over a very wide wavelength range from the ultraviolet to infrared , 2000 .

[31]  Suntak Park,et al.  Vertical coupling of long-range surface plasmon polaritons , 2006 .

[32]  B. Liedberg,et al.  Surface plasmon resonance for gas detection and biosensing , 1983 .

[33]  W. Knoll,et al.  Long Range Surface Plasmons for Observation of Biomolecular Binding Events at Metallic Surfaces , 2007 .

[34]  R. Corn,et al.  Long-range surface plasmon resonance imaging for bioaffinity sensors. , 2005, Analytical chemistry.