Silver high-aspect-ratio micro- and nanoimprinting for optical applications

Metal direct nanoimprinting is a fabrication technique based on plastic deformation of ductile metals such as silver and gold pressed into a structured rigid mold. While this process can be exploited to manufacture metallic micro- and nanoparts by removing the mold after processing, it can also be used as a metallization method for producing two-dimensional metallo-dielectric composites. Dense silver-pillar arrays with diameters down to 140 nm, aspect ratios up to 13, and excellent uniformity over large areas were fabricated. The sample quality was confirmed by near-infrared optical reflectances of Si–Ag photonic crystals, which showed strong collective surface plasmon-polariton resonances.

[1]  Stella W. Pang,et al.  Direct nano-printing on Al substrate using a SiC mold , 1998 .

[2]  Ulf Engel,et al.  Microforming—from basic research to its realization , 2002 .

[3]  Harald Giessen,et al.  Large-area two-dimensional photonic crystals of metallic nanocylinders based on colloidal gold nanoparticles , 2007 .

[4]  Tae-Il Kim,et al.  Gold nanocones fabricated by nanotransfer printing and their application for field emission , 2008, Nanotechnology.

[5]  F M Wang,et al.  Metamaterial of rod pairs standing on gold plate and its negative refraction property in the far-infrared frequency regime. , 2007, Physical review. E, Statistical, nonlinear, and soft matter physics.

[6]  Lucio Claudio Andreani,et al.  Photonic bands in patterned silicon-on-insulator waveguides , 2002 .

[7]  W. Barnes,et al.  Surface plasmon subwavelength optics , 2003, Nature.

[8]  Jeffrey N. Anker,et al.  Biosensing with plasmonic nanosensors. , 2008, Nature materials.

[9]  V. Kravets,et al.  Extremely narrow plasmon resonances based on diffraction coupling of localized plasmons in arrays of metallic nanoparticles. , 2008, Physical review letters.

[10]  J. F. Löffler,et al.  Metal direct nanoimprinting for photonics , 2008 .

[11]  David R. Smith,et al.  Metamaterials and Negative Refractive Index , 2004, Science.

[12]  W. Barnes,et al.  Collective resonances in gold nanoparticle arrays. , 2008, Physical review letters.

[13]  J. Schroers,et al.  Nanomoulding with amorphous metals , 2009, Nature.

[14]  R. Spolenak,et al.  Deformation behavior of silver submicrometer-pillars prepared by nanoimprinting , 2009 .

[15]  A. Moroz,et al.  Towards two-dimensional complete photonic bandgap structures below infrared wavelengths , 2000 .

[16]  E. Palik Handbook of Optical Constants of Solids , 1997 .

[17]  Yoshihiko Hirai,et al.  Fine gold grating fabrication on glass plate by imprint lithography , 2003, SPIE Optics + Photonics.

[18]  Miroslav Plančak,et al.  Coining process as a means of controlling surface microgeometry , 1998 .