Numerical simulation of intermediate-temperature direct-internal-reforming planar solid oxide fuel cell

A numerical model for an anode-supported intermediate-temperature direct-internal-reforming planar solid oxide fuel cell (SOFC) was developed. In this model, the volume-averaging method is applied to the flow passages in the SOFC by assuming that a porous material is inserted in the passages as a current collector. This treatment reduces the computational time and cost by avoiding a full three-dimensional simulation while maintaining the ability to solve the flow and pressure fields in the streamwise and spanwise directions. In this model, quasi-three-dimensional multicomponent gas flow fields, the temperature field, and the electric potential/current fields were simultaneously solved. The steam-reforming reaction using methane, the water-gas shift reaction, and the electrochemical reactions of hydrogen and carbon monoxide were taken into account. It was found that the endothermic steam-reforming reaction led to a reduction in the local temperature near the inlet and limited the electrochemical reaction rates therein. Computational results indicated that the local temperature and current density distributions can be controlled by tuning the pre-reforming rate. It was also found that a small amount of heat loss from the sidewall can cause significant nonuniformity in the flow and thermal fields in the spanwise direction.

[1]  J. Giddings,et al.  NEW METHOD FOR PREDICTION OF BINARY GAS-PHASE DIFFUSION COEFFICIENTS , 1966 .

[2]  Analysis of chemical reacting heat transfer in SOFCs , 2008 .

[3]  H. Iwai,et al.  Comprehensive Numerical Modeling and Analysis of a Cell-Based Indirect Internal Reforming Tubular SOFC , 2006 .

[4]  Jacob Bear,et al.  Fundamentals of transport phenomena in porous media , 1984 .

[5]  C. Wilke,et al.  Viscosity Behavior of Gases , 1951 .

[6]  Bengt Sundén,et al.  Transport phenomena in fuel cells , 2005, Hydrogen, Batteries and Fuel Cells.

[7]  Gerd Maurer,et al.  Chemical Equilibrium and Liquid−Liquid Equilibrium in Aqueous Solutions of Formaldehyde and 1-Butanol , 2003 .

[8]  R. Mahajan,et al.  The Effective Thermal Conductivity of High Porosity Fibrous Metal Foams , 1999 .

[9]  Fausto Arpino,et al.  Numerical simulation of mass and energy transport phenomena in solid oxide fuel cells , 2009 .

[10]  R. Mahajan,et al.  Forced Convection in High Porosity Metal Foams , 2000 .

[11]  N. Bessette,et al.  A Mathematical Model of a Solid Oxide Fuel Cell , 1995 .

[12]  Hiroshi Iwai,et al.  Electrochemical and Thermo-Fluid Modeling of a Tubular Solid Oxide Fuel Cell with Accompanying Indirect Internal Fuel Reforming , 2005 .

[13]  E. Achenbach Three-dimensional and time-dependent simulation of a planar solid oxide fuel cell stack , 1994 .

[14]  Y. Jaluria,et al.  An Introduction to Heat Transfer , 1950 .

[15]  R. Mahajan,et al.  Thermophysical properties of high porosity metal foams , 2002 .

[16]  S. Chan,et al.  A complete polarization model of a solid oxide fuel cell and its sensitivity to the change of cell component thickness , 2001 .

[17]  Tohru Kato,et al.  Numerical analysis of output characteristics of tubular SOFC with internal reformer , 2001 .

[18]  Stephen Whitaker,et al.  Heat and Mass Transfer in Porous Media , 1984 .

[19]  Don W. Green,et al.  Perry's Chemical Engineers' Handbook , 2007 .

[20]  Emmanuel Kakaras,et al.  Comparison between two methane reforming models applied to a quasi-two-dimensional planar solid oxide fuel cell model , 2009 .

[21]  B. Haberman,et al.  Three-dimensional simulation of chemically reacting gas flows in the porous support structure of an integrated-planar solid oxide fuel cell , 2004 .

[22]  B. A. Haberman,et al.  A Detailed Three-Dimensional Simulation of an IP-SOFC Stack , 2008 .

[23]  C. Adjiman,et al.  Anode-supported intermediate temperature direct internal reforming solid oxide fuel cell. I: model-based steady-state performance , 2004 .

[24]  Abel Hernandez-Guerrero,et al.  Current density and polarization curves for radial flow field patterns applied to PEMFCs (Proton Exchange Membrane Fuel Cells) , 2010 .

[25]  E. Riensche,et al.  Methane/steam reforming kinetics for solid oxide fuel cells , 1994 .

[26]  M. Fowler,et al.  Experimental and modeling study of solid oxide fuel cell operating with syngas fuel , 2006 .

[27]  Alexander L. Lindsay,et al.  Thermal Conductivity of Gas Mixtures , 1950 .

[28]  Adriano Sciacovelli,et al.  Entropy generation analysis in a monolithic-type solid oxide fuel cell (SOFC) , 2009 .