Analysis of the characteristics of thick-film NTC thermistor devices manufactured by screen-printing and firing technique and by room temperature aerosol deposition method (ADM)

The study compares thick-film NTC thermistor devices, produced by the screen-printing (and firing) technique and by the Aerosol Deposition Method (ADM) at room temperature. The devices are compared with respect to film quality (optical, mechanical) and to the negative temperature coefficient of resistance (NTCR) parameters ρ25 and B. While the screen-printed films are porous, the Aerosol Deposited (AD) films are characterized by high tightness, mechanical stability, and a production at room temperature. The electrical analysis shows that the AD films reach the ρ25- and B-values of bulk NTCRs from literature after a moderate tempering step below 400∘C in air. The screen-printed films show B-values that are comparable to the values of bulk NTCRs from literature and ρ25-values that are significantly higher.

[1]  J. Akedo Room Temperature Impact Consolidation (RTIC) of Fine Ceramic Powder by Aerosol Deposition Method and Applications to Microdevices , 2008 .

[2]  Andreas Roosen,et al.  Screen printing of co-precipitated NiMn2O4+δ for production of NTCR thermistors , 2003 .

[3]  Rainer Schmidt,et al.  Production of NTCR thermistor devices based on NiMn2O4+δ , 2004 .

[4]  A. Rousset,et al.  Electrical conductivity of copper and nickel manganites in relation with the simultaneous presence of Mn3+ and Mn4+ ions on octahedral sites of the spinel structure , 1992 .

[5]  Ralf Moos,et al.  Aerosol deposition of (Cu,Ti) substituted bismuth vanadate films , 2014 .

[6]  Mehmet Parlak,et al.  Effect of heat treatment on nickel manganite thin film thermistors deposited by electron beam evaporation , 1999 .

[7]  Bin Sun,et al.  Preparation and characterization of NiMn2O4 negative temperature coefficient ceramics by solid-state coordination reaction , 2014, Journal of Materials Science: Materials in Electronics.

[8]  Rainer Schmidt,et al.  Electrical properties of screen-printed NiMn2O4+δ , 2005 .

[9]  Ralf Moos,et al.  Tuning of the electrical conductivity of Sr(Ti,Fe)O3 oxygen sensing films by aerosol co-deposition with Al2O3 , 2016 .

[10]  K. R. Dayas,et al.  Tape casting of nickel manganite NTC ceramics for chip thermistors , 2008 .

[11]  K. Park,et al.  Electrical properties of Ni–Mn–Co–(Fe) oxide thick-film NTC thermistors prepared by screen printing , 2003 .

[12]  A. Rousset,et al.  Electrical properties and cationic distribution in cubic nickel manganite spinels NixMn3−xO4, 0.57 , 1991 .

[13]  Vijaya Puri,et al.  Composition dependent resistivity of thick film Ni(1−x)CoxMn2O4: (0 ≤ x ≤ 1) NTC thermistors , 2006 .

[14]  C. Leroux,et al.  Cation Distribution, Short-Range Order and Small Polaron Hopping Conduction in Nickel Manganites, from a Neutron Diffraction Study , 1999 .

[15]  Aloysius J.A. Winnubst,et al.  Preparation of Ultra-Fine Nickel Manganite Powders and Ceramics by a Solid-State Coordination Reaction , 2006 .

[16]  A. Rousset,et al.  Mechanical properties of nickel manganites-based ceramics used as negative temperature coefficient thermistors (NTC) , 2004 .

[17]  R. Arnott,et al.  Preparation, semiconduction and low-temperature magnetization of the system Ni1−xMn12+xO4 , 1962 .

[18]  Woon-Ha Yoon,et al.  Highly Dense and Nanograined NiMn2O4 Negative Temperature coefficient Thermistor Thick Films Fabricated by Aerosol‐Deposition , 2009 .

[19]  B. Gillot,et al.  Ionic configuration and cation distribution in cubic nickel manganite spinels NixMn3−xO4 (0.57 , 1992 .

[20]  M. Hrovat,et al.  The development of the microstructural and electrical characteristics of NTC thick-film thermistors during firing , 2006 .

[21]  Adalbert Feltz,et al.  Conductivity data and preparation routes for NiMn2O4 thermistor ceramics , 1992 .

[22]  Ian M. Reaney,et al.  Decomposition of NiMn2O4 spinel : an NTC thermistor material , 2001 .

[23]  Abel Rousset,et al.  Thin films of nickel manganese oxide for NTC thermistor applications , 1993 .

[24]  Pantelija M. Nikolic,et al.  Intrinsic resistivity of sintered Nickel Manganite vs. powder activation time and density , 2008, Science of Sintering.