Experimental determination and fractal modeling of the effective thermal conductivity of autoclave aerated concrete (AAC) impregnated with paraffin for improved thermal storage performance

Abstract Autoclave aerated concrete (AAC) was incorporated with paraffin to form novel composite building materials with improved thermal storage capacity. The composite samples were prepared by impregnating RT28 paraffin into three types of AAC with different porosities. The effective thermal conductivity of the paraffin/AAC composites was measured at both 20 °C and 35 °C, while the paraffin was in solid and liquid phases, respectively. A fractal model was developed to predict the effective thermal conductivity of the composites. Both the experimental results and model predictions showed that the thermal conductivity increases with raising the paraffin content, leading to deterioration of the thermal insulation performance of pristine AAC. The volumetric heat capacity of the composites was also measured to derive the thermal effusivity, which serves as a measure for thermal storage performance of building materials. To reach a compromise among the various considerations, it was suggested that an intermediate paraffin content, about two thirds of the saturated level, is appropriate for all samples because it is unnecessary to fully impregnate the AAC samples with paraffin at the cost of reducing the insulation performance and increasing the risk of paraffin leakage upon melting.

[1]  D. Feldman,et al.  The stability of phase change materials in concrete , 1992 .

[2]  D. Li,et al.  Influence of optical parameters on thermal and optical performance of multi-layer glazed roof filled with PCM , 2018 .

[3]  M. Hadjieva,et al.  Composite salt-hydrate concrete system for building energy storage , 2000 .

[4]  Alex Ricklefs,et al.  Thermal Conductivity of Cementitious Composites Containing Microencapsulated Phase Change Materials , 2017 .

[5]  K. Ramamurthy,et al.  STRUCTURE AND PROPERTIES OF AERATED CONCRETE: A REVIEW , 2000 .

[6]  A. Elhassnaoui,et al.  A simple method for determining the thermal effusivity of defects , 2014 .

[7]  Maciej Jaworski,et al.  Thermal conductivity of gypsum with incorporated phase change material ( PCM ) for building applications , 2011 .

[8]  Liwu Fan,et al.  Experimental determination and fractal modeling of the effective thermal conductivity of autoclaved aerated concrete: Effects of moisture content , 2016 .

[9]  Boming Yu,et al.  A generalized model for the effective thermal conductivity of porous media based on self-similarity , 2004 .

[10]  H. Brouwers,et al.  The behavior of self-compacting concrete containing micro-encapsulated Phase Change Materials , 2009 .

[11]  Zeyu Lu,et al.  Preparation and characterization of expanded perlite/paraffin composite as form-stable phase change material , 2014 .

[12]  W. Yanjun,et al.  Fabrication and characterization of fatty acid/wood-flour composites as novel form-stable phase change materials for thermal energy storage , 2018, Energy and Buildings.

[13]  Mario A. Medina,et al.  Thermal performance of phase change materials (PCM)-enhanced cellulose insulation in passive solar residential building walls , 2018 .

[14]  D. Feldman,et al.  Latent heat storage in concrete , 1989 .

[15]  Maciej Jaworski,et al.  Thermal conductivity of gypsum containig phase change material (PCM) for builiding applications , 2011 .

[16]  D. Feldman,et al.  Control aspects of latent heat storage and recovery in concrete , 2000 .

[17]  Tanushree B. Gupta,et al.  Applications of phase change material in sustainable built environment: A review , 2018 .

[18]  Dale P. Bentz,et al.  Transient plane source measurements of the thermal properties of hydrating cement pastes , 2007 .

[19]  Mario A. Medina,et al.  Evaluation of the thermal performance of frame walls enhanced with paraffin and hydrated salt phase change materials using a dynamic wall simulator , 2010 .

[20]  Ulf Wickström,et al.  Using the TPS method for determining the thermal properties of concrete and wood at elevated temperature , 2006 .

[21]  Dong Li,et al.  Influence of glazed roof containing phase change material on indoor thermal environment and energy consumption , 2018, Applied Energy.

[22]  Dorel Feldman,et al.  Latent heat storage in building materials , 1993 .

[23]  Yi Li,et al.  A fractal model for the coupled heat and mass transfer in porous fibrous media , 2011 .

[24]  A. Sari,et al.  Diatomite/CNTs/PEG composite PCMs with shape-stabilized and improved thermal conductivity: Preparation and thermal energy storage properties , 2018 .

[25]  Juan Shi,et al.  Experimental and numerical study on effective thermal conductivity of novel form-stable basalt fiber composite concrete with PCMs for thermal storage , 2014 .

[26]  Yanfeng Liu,et al.  Effect of moisture migration and phase change on effective thermal conductivity of porous building materials , 2018, International Journal of Heat and Mass Transfer.

[27]  M. Hawlader,et al.  Encapsulated phase change materials for thermal energy storage: Experiments and simulation , 2002 .

[29]  Akira Nagashima,et al.  Viscosity and thermal conductivity of dry air in the gaseous phase , 1985 .

[30]  Zongjin Li,et al.  Paraffin/diatomite composite phase change material incorporated cement-based composite for thermal energy storage , 2013 .

[31]  Zhengguo Zhang,et al.  A novel montmorillonite-based composite phase change material and its applications in thermal storage building materials , 2006 .

[32]  Pingfang Hu,et al.  Energy saving potential of a novel phase change material wallboard in typical climate regions of China , 2016 .

[33]  Lim Chin Haw,et al.  The effect of building envelope on the thermal comfort and energy saving for high-rise buildings in hot–humid climate , 2016 .

[34]  S. Asadi,et al.  Single and combined phase change materials: Their effect on seasonal transition period , 2018, Energy and Buildings.

[35]  D. Feldman,et al.  Absorption of phase change materials in concrete , 1992 .

[36]  Boming Yu,et al.  A self-similarity model for effective thermal conductivity of porous media , 2003 .

[37]  D. Buddhi,et al.  Thermal performance assessment of encapsulated PCM based thermal management system to reduce peak energy demand in buildings , 2016 .

[38]  Robert F. Boehm,et al.  Passive building energy savings: A review of building envelope components , 2011 .

[39]  Zitao Yu,et al.  The prediction of effective thermal conductivities perpendicular to the fibres of wood using a fractal model and an improved transient measurement technique , 2006 .

[40]  Liwu Fan,et al.  Effects of sample length on the transient measurement results of water vapor diffusion coefficient of porous building materials: A case study of autoclave aerated concrete (AAC) with various porosities , 2019, International Journal of Heat and Mass Transfer.

[41]  Aaron R. Sakulich,et al.  Application of phase change materials in gypsum boards to meet building energy conservation goals , 2017 .