Abstract In Monte Carlo simulations of water radiolysis, the diffusion of reactants can be approximated by “jumping” all species randomly, to represent the passage of a short period of time, and then checking their separations. If, at the end of a jump, two reactant species are within a distance equal to the reaction radius for the pair, they are allowed to react in the model. In principle, the possibility exists that two reactants could “jump through” one another and end up with a separation larger than the reaction radius with no reaction being scored. Ignoring this possibility would thus reduce the rate of reaction below that intended by such a model. By making the jump times and jump distances shorter, any error introduced by `jump through' is made smaller. This paper reports numerical results of a systematic study of `jump through' in Monte Carlo simulations of water radiolysis. With a nominal jump time of 3 ps, it is found that more than 40% of the reactions of the hydrated electron with itself and of the H atom with itself occur when reactions during `jump through' are allowed. For all other reactions, for which the effect is smaller, the contributions of `jump through' lie in the range l%–16% of the total. Corrections to computed rate constants for two reactions are evaluated for jump times between 0.1 and 30 ps. It is concluded that jump-through corrections are desirable in such models for jump times that exceed about 1 ps or even less. In a separate study, we find that giving all species of a given type the same size jump in a random direction yields results that are indistinguishable from those when the jump sizes are selected from a Gaussian distribution. In this comparison, the constant jump size is taken to be the root-mean-square jump size from the Gaussian distribution.
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