Metallic Glass Hemispherical Shell Resonators

By utilizing bulk metallic glasses' (BMGs) unique combination of amorphous structure, material properties, and fabrication opportunities, ultrasmooth and symmetric 3-D metallic glass resonators that are complimentary metal oxide semiconductor (CMOS) post-processing compatible are fabricated. Surface roughness to size ratio fabrication precision in the order of 100 parts per billion is demonstrated with a 3-mm diameter Pt57.5Cu14.7Ni5.3P22.5 BMG hemispherical shell with a thickness variation <;100 nm and a surface roughness of <;1 nm Ra. The resonator exhibits a resonant frequency of 13.9440 kHz ± 0.1 Hz with 0.035% frequency mismatch between degenerate N = 2 wineglass modes with a quality factor of 6200. This performance was obtained in the asmolded state without any device tuning or trimming. Another resonator with N = 2 resonant modes at 9.393 and 9.401 kHz, and quality factors of 7800 and 6500 was mounted into an integrated electrode system. Electrical readout by capacitive sensing in both time and frequency domains showed a resonance shift to 9.461 and 9.483 kHz, respectively. The quality factor was reduced to 5400 and 5300, respectively. This investigation demonstrates that BMG resonators may serve as a basis for robust microelectromechanical systems resonator devices with increased performance and low-cost fabrication techniques that exploits the atomic structure, unique softening behavior, strength, formability, and toughness of metallic glasses.

[1]  Farrokh Ayazi,et al.  Micromachined inertial sensors , 1998, Proc. IEEE.

[2]  Atomic layer deposited alumina for micromachined resonators , 2008, 2008 IEEE 21st International Conference on Micro Electro Mechanical Systems.

[3]  Akihisa Inoue,et al.  Relationship between thermal expansion coefficient and glass transition temperature in metallic glasses , 2008 .

[4]  Jan Schroers,et al.  On the formability of bulk metallic glass in its supercooled liquid state , 2008 .

[5]  J. Schroers,et al.  Hot rolling of bulk metallic glass in its supercooled liquid region , 2008 .

[6]  J. Schroers The superplastic forming of bulk metallic glasses , 2005 .

[7]  J. Schroers,et al.  Precious bulk metallic glasses for jewelry applications , 2007 .

[8]  J. Schroers,et al.  Write and erase mechanisms for bulk metallic glass , 2008 .

[9]  Andrei M. Shkel,et al.  High temperature micro-glassblowing process demonstrated on fused quartz and ULE TSG , 2013 .

[10]  H. Chen The influence of structural relaxation on the density and Young’s modulus of metallic glasses , 1978 .

[11]  J. Schroers,et al.  Three-Dimensional Shell Fabrication Using Blow Molding of Bulk Metallic Glass , 2011, Journal of Microelectromechanical Systems.

[12]  T. L. Wright,et al.  Room-temperature chemical vapor deposition and mass detection on a heated atomic force microscope cantilever , 2006 .

[13]  W. Johnson,et al.  Shear bands and cracking of metallic glass plates in bending , 2003 .

[14]  Andrei M. Shkel,et al.  Ultra-high Q silicon gyroscopes with interchangeable rate and whole angle modes of operation , 2010, 2010 IEEE Sensors.

[15]  Jan Schroers,et al.  Ductile bulk metallic glass. , 2004, Physical review letters.

[16]  G. Fedder,et al.  A Low-Noise Low-Offset Capacitive Sensing Amplifier for a 50-g = Hz Monolithic CMOS MEMS Accelerometer , 2004 .

[17]  M. Roukes,et al.  Ultra-sensitive NEMS-based cantilevers for sensing, scanned probe and very high-frequency applications. , 2007, Nature nanotechnology.

[18]  M. Roukes,et al.  Thermoelastic damping in micro- and nanomechanical systems , 1999, cond-mat/9909271.

[19]  J. Schroers,et al.  Thermodynamics, kinetics, and crystallization of Pt57.3Cu14.6Ni5.3P22.8 bulk metallic glass , 2007 .

[20]  G.K. Fedder,et al.  A low-noise low-offset capacitive sensing amplifier for a 50-/spl mu/g//spl radic/Hz monolithic CMOS MEMS accelerometer , 2004, IEEE Journal of Solid-State Circuits.

[21]  M. Roukes,et al.  Zeptogram-scale nanomechanical mass sensing. , 2005, Nano letters.

[22]  A. Desai,et al.  Thermoplastic Forming of Bulk Metallic Glass— A Technology for MEMS and Microstructure Fabrication , 2007, Journal of Microelectromechanical Systems.

[23]  J. Schroers,et al.  In situ measurements of surface tension-driven shape recovery in a metallic glass , 2009 .

[24]  Farrokh Ayazi,et al.  High-Frequency AlN-on-Silicon Resonant Square Gyroscopes , 2013, Journal of Microelectromechanical Systems.

[25]  J. Schroers Processing of Bulk Metallic Glass , 2010, Advanced materials.

[26]  M. R. Hilton,et al.  Composition, morphology and mechanical properties of plasma-assisted chemically vapor-deposited TiN films on M2 tool steel , 1986 .

[27]  F. Ayazi,et al.  3-D micromachined hemispherical shell resonators with integrated capacitive transducers , 2012, 2012 IEEE 25th International Conference on Micro Electro Mechanical Systems (MEMS).

[28]  A. L. Greer,et al.  Metallic glasses…on the threshold , 2009 .

[29]  Ji-Hwan Kim,et al.  Thermoelastic Damping of Inextensional Hemispherical Shell , 2009 .

[30]  Jan Schroers,et al.  Bulk Metallic Glass: The Smaller the Better , 2011 .

[31]  Reza Ghodssi,et al.  MEMS materials and processes handbook , 2011 .

[32]  G. Palasantzas Quality factor due to roughness scattering of shear horizontal surface acoustic waves in nanoresonators , 2008, 0808.0401.

[33]  Vijay K. Varadan Nanotechnology: MEMS and NEMS and their applications to smart systems and devices , 2003, Other Conferences.

[34]  Khalil Najafi,et al.  3-Dimensional Blow Torch-Molding of Fused Silica Microstructures , 2013, Journal of Microelectromechanical Systems.

[35]  S. A. Zotov,et al.  Three-Dimensional Spherical Shell Resonator Gyroscope Fabricated Using Wafer-Scale Glassblowing , 2012, Journal of Microelectromechanical Systems.

[36]  S. A. Zotov,et al.  Low-Dissipation Silicon Tuning Fork Gyroscopes for Rate and Whole Angle Measurements , 2011, IEEE Sensors Journal.

[37]  W. W. Stripling,et al.  Hemispherical resonator gyro: Principle, design, and performance , 1992 .

[38]  A. J. Barnes,et al.  Thermoplastic blow molding of metals , 2011 .

[39]  Dieter Krause,et al.  Low thermal expansion glass ceramics , 1995 .

[40]  P. Yan,et al.  Tensile ductility and necking of metallic glass. , 2007, Nature materials.

[41]  S. Bhave,et al.  Z-axis optomechanical accelerometer , 2012, 2012 IEEE 25th International Conference on Micro Electro Mechanical Systems (MEMS).

[42]  Surface tension-driven shape-recovery of micro/nanometer-scale surface features in a Pt57.5Ni5.3Cu14.7P22.5 metallic glass in the supercooled liquid region: A numerical modeling capability , 2010 .

[43]  D. Horsley,et al.  Hemispherical wineglass resonators fabricated from the microcrystalline diamond , 2013 .

[44]  Jan Schroers,et al.  Atomically smooth surfaces through thermoplastic forming of metallic glass , 2010 .

[45]  A L Greer Metallic glasses. , 1995, Science.

[46]  R. Ehrbar,et al.  Tunable Tensile Ductility in Metallic Glasses , 2013, Scientific Reports.