Evaluation of hydrolysis-esterification biodiesel production from wet microalgae.

Wet microalgae hydrolysis-esterification route has the advantage to avoid the energy-intensive units (e.g. drying and lipid extraction) in the biodiesel production process. In this study, techno-economic evaluation of hydrolysis-esterification biodiesel production process was carried out and compared with conventional (usually including drying, lipid extraction, esterification and transesterification) biodiesel production process. Energy and material balance of the conventional and hydrolysis-esterification processes was evaluated by Aspen Plus. The simulation results indicated that drying (2.36MJ/L biodiesel) and triolein transesterification (1.89MJ/L biodiesel) are the dominant energy-intensive stages in the conventional route (5.42MJ/L biodiesel). By contrast, the total energy consumption of hydrolysis-esterification route can be reduced to 1.81MJ/L biodiesel, and approximately 3.61MJ can be saved to produce per liter biodiesel.

[1]  M. Dubé,et al.  Biodiesel production from waste cooking oil: 1. Process design and technological assessment. , 2003, Bioresource technology.

[2]  Wen Tong Chong,et al.  A review on potential enzymatic reaction for biofuel production from algae , 2014 .

[3]  Shiro Saka,et al.  Two-step preparation for catalyst-free biodiesel fuel production , 2004, Applied biochemistry and biotechnology.

[4]  Viatcheslav Kafarov,et al.  Evaluation of alternatives for microalgae oil extraction based on exergy analysis , 2013 .

[5]  S. B. Adejuyigbe,et al.  Performance enhancement of vapor recompression heat pump , 2014 .

[6]  Ronald C Sims,et al.  Biodiesel from mixed culture algae via a wet lipid extraction procedure. , 2012, Bioresource technology.

[7]  Gerrit Brem,et al.  Assessment of a dry and a wet route for the production of biofuels from microalgae: energy balance analysis. , 2011, Bioresource technology.

[8]  Yutaka Kitamura,et al.  Simultaneous hydrolysis-esterification of wet microalgal lipid using acid. , 2013, Bioresource technology.

[9]  Y. Chisti Biodiesel from microalgae. , 2007, Biotechnology advances.

[10]  Hsien Hui Khoo,et al.  Bioenergy co-products derived from microalgae biomass via thermochemical conversion--life cycle energy balances and CO2 emissions. , 2013, Bioresource technology.

[11]  Tatsuo Miyazaki,et al.  Hydrolysis for direct esterification of lipids from wet microalgae. , 2013, Bioresource technology.

[12]  F. Bux,et al.  Biodiesel from microalgae: A critical evaluation from laboratory to large scale production , 2013 .

[13]  Qingling Liu,et al.  Biodiesel production process from microalgae oil by waste heat recovery and process integration. , 2015, Bioresource technology.

[14]  S. Deng,et al.  Intensification of microalgae drying and oil extraction process by vapor recompression and heat integration. , 2016, Bioresource technology.

[15]  Dadan Kusdiana,et al.  Effects of water on biodiesel fuel production by supercritical methanol treatment. , 2004, Bioresource technology.

[16]  Yasuki Kansha,et al.  Self-Heat Recuperation Technology for Energy Saving in Chemical Processes , 2009 .

[17]  Naoko Ellis,et al.  Process simulation and economic analysis of biodiesel production processes using fresh and waste vegetable oil and supercritical methanol , 2011 .

[18]  Rupam Kataki,et al.  Microalgae Chlorella as a potential bio-energy feedstock , 2011 .

[19]  Arnaud Hélias,et al.  Life-cycle assessment of biodiesel production from microalgae. , 2009, Environmental science & technology.

[20]  G. Luo,et al.  Macroalgae for biofuels production: progress and perspectives. , 2015 .

[21]  M. Dassisti,et al.  Technologies and developments of third generation biofuel production , 2015 .

[22]  P. Li,et al.  Simple extraction method of green crude from natural blue-green microalgae by dimethyl ether , 2011 .

[23]  Yuqing Su,et al.  An overview of biofuels policies and industrialization in the major biofuel producing countries , 2015 .

[24]  M. Bilal Khan,et al.  Progress in energy from microalgae: A review , 2013 .

[25]  E. Becker Micro-algae as a source of protein. , 2007, Biotechnology advances.