论文信息 - Tryptophan anion complexes of β-cyclodextrin (cyclomaltaheptaose), an aminopropylamino-β-cyclodextrin and its enantioselective nickel(II) complex

Tryptophan anion complexes of β-cyclodextrin (cyclomaltaheptaose), an aminopropylamino-β-cyclodextrin and its enantioselective nickel(II) complex

6I-(3-Aminopropylamino)-6I-deoxy-cyclomaltaheptaose (βCDpn) exhibits enhanced complexation of tryptophan anion, by comparison with βCD, while the nickel(II) complex of βCDpn complexes tryptophan anion even more strongly and exhibits a tenfold enantioselectivity in favour of the (S)-tryptophan anion.

[1] Susan E. Brown,et al. Chiral molecular recognition: a 19F nuclear magnetic resonance study of the diastereoisomer inclusion complexes formed between fluorinated amino acid derivatives and α-cyclodextrin in aqueous solution , 1991 .

[2] R. Marchelli,et al. 6‐Deoxy‐6‐N‐histamino‐β‐cyclodextrin Copper(II) Complex, a New Enantioselective Receptor for Aromatic Amino Acids , 1991 .

[3] G. Vecchio,et al. The copper(II) complex with the imidazole-bound histamine derivative of β-cyclodextrin as a powerful chiral discriminating agent , 1992 .

[4] Susan E. Brown,et al. Substituent effects and chiral discrimination in the complexation of benzoic, 4-methylbenzoic and (RS)-2-phenylpropanoic acids and their conjugate bases by β-cyclodextrin and 6A-amino-6A-deoxy-β-cyclodextrin in aqueous solution: potentiometric titration and 1H nuclear magnetic resonance spectroscopi , 1993 .

[5] I. Tabushi. Reductive dioxygen activation by use of artificial P-450 systems , 1988 .

[6] S. Lincoln,et al. Inclusion Complexes of the Cyclomalto-Oligosaccharides (Cyclodextrins) , 1988 .

[7] K. Lipkowitz,et al. Enantioselective binding of tryptophan by .alpha.-cyclodextrin , 1992 .